Gordon Jock Churchman

FACTORS INFLUENCING THE FORMATION AND CHARACTERISTICS OF HALLOYSITES OR KAOLINITES IN GRANITIC AND TUFFACEOUS SAPROLITES IN HONG KONG

The occurrence of halloysite and/or kaolinite in clay-rich, vein-like zones in saprolites in Hong Kong has provided the opportunity to examine the conditions determining the formation of one kaolin mineral or the other and also the nature of their particles. Clay-rich zones within tuffaceous or granitic saprolites from six different hillside sites have been examined in replicate samples by optical and scanning electron microscopy, X-ray diffraction, and thermal analysis. Kaolin minerals, sometimes together with Mn oxides and Fe oxides/oxyhydroxides, have formed within discontinuities within the altered host rocks. The fabrics of kaolin infills generally indicated several generations of kaolin formation and that shear and deformation have commonly occurred within the infills. The infills were either light or dark in color. Light-colored infills often comprised pure, or nearly pure, halloysite or kaolinite. Dark Mn- and Fe-rich infills all contained kaolinite, while including some halloysite. The very halloysitic, light-colored infills occurred in saprolites in both granite and tuff as long tubular shapes in parallel bunches. The light-colored, very kaolinitic infills occurred in tuff only, in large platy or near-platy shapes within vermiform packets. In dark-colored infills, early kaolin mineral crystallization was limited by impurities from the breakdown of primary minerals leaving dissolved and re-precipitated compounds of Mn and Fe within the infill. Kaolin minerals in infill at all the sites except one are considered to have formed as a result of weathering. The exception comprises white infills in tuff that are composed of extremely small, closely packed particles, suggesting formation by hydrothermal action. Generally, the kaolin minerals have formed by neogenesis out of solution in the discontinuities. Drying, with the formation of Mn and/or Fe oxides/oxyhydroxides, had occurred several times, indicating enhanced drainage. Where drying had occurred, kaolinite had formed. Where indications of drying in infills were absent, halloysite was predominant.

Increased profile wettability in texture-contrast soils from clay delving: case studies in South Australia

Clay delving is becoming a popular practice to increase productivity of texture-contrast soils in southern Australia. The practice brings subsoil clay to the surface to be mixed with the sandy topsoil, and unlike clay spreading, it combines the addition of hydrophilic material with a ripping effect that disrupts the sharp boundary between the sandy topsoil and clayey subsoil. Our objective was to evaluate the magnitude of effects caused by delving on the spatial distribution of water through the profile for three Sodosols (Stagnic Solonetz soils) in the south-east of South Australia. We also wished to evaluate the extent to which clay delving might reduce water ponding at the A–B horizon interface. We wetted both delved and undelved texture-contrast soils with a Brilliant Blue dye solution under initially dry and wet conditions (to evaluate the effect of antecedent water content), and then took digital images of the stained profiles for quantitative comparison of the wetted areas. The stained soil profiles indicated that clay delving reduced preferential water flow (finger flow) and resulted in deeper and more uniform wetting of the A horizon, particularly under initially dry conditions. Under wet conditions (where water repellence was largely overcome), finger flow was significantly reduced regardless of delving but it still occurred to varying degrees depending on site characteristics. Delving significantly reduced ponding of water at the A–B horizon boundary and allowed greater penetration into the B horizon. At all sites, greater effects occurred directly on the delving lines and diminished with distance, implying that closer spacing of delving tines would increase uniformity of wetting throughout the profile. The effectiveness of delving on profile wetting was highly variable across the three sites, indicating that the outcome depends inter alia on the intrinsic soil characteristics and the delving equipment used in the field.

Three-component mixed-layer illite/smectite/kaolinite (I/S/K) minerals in hydromorphic soils, south China

Abstract To understand clay mineral transformations in hydromorphic conditions in the red earth sediments in Xuancheng, south China, clay mineralogy was investigated using X‑ray diffraction (XRD) and highresolution transmission electron microscopy (HRTEM). The XRD results indicated that clay minerals in the hydromorphic soils were illite, kaolinite, smectite, vermiculite, and mixed-layer illite/smectite and illite/smectite/kaolinite. Changes of the kaolinitic reflections under the various conditions suggested that the kaolinitic phase is a mixed-layer structure having kaolinite layers randomly interstratified with illite and smectite layers. HRTEM observation showed that 10 Å illite layers interstratified with both 15 Å smectite layers and 7 Å kaolinite layers in clay particles, confirming the occurrence of illite/smectite/kaolinite (I/S/K) three-component mixed-layer clays. The lattice fringes of the I/S/K clays appeared corrugated and vanishing, and also exhibited variable thickness along a lattice fringe, which were consistent with changes from illite to smectite, from smectite to kaolinite, and from illite to kaolinite, respectively. Hydromorphic conditions in the Xuancheng soils led simultaneously to the direct transformation of illite to kaolinite and the transformation of illite to smectite to kaolinite in the pedogenic processes, and the formation of I/S/K three-component mixed-layer clays as intermediate products of these processes.

Pedogenic alteration of illite in subtropical China

Abstract Pedogenic alteration of illite from red earth sediments in Jiujiang in subtropical China was investigated using X–ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM). Illite, hydroxy-interlayered vermiculite (HIV), kaolinite and mixed-layer illite-HIV (I-HIV) are present in the soils. The characteristic reflections of the clay phases were 14 Å, 10-14 Å, 10 Å, and 7 Å, respectively. After Mg-glycerol saturations, the 14 Å peak of the samples did not expand, and after heating at 350 °C and 550 °C it shifted to 13.8 Å and 12 Å respectively, with no residual 14 Å reflection, suggesting the occurrence of hydroxy-interlayered vermiculite. The randomly interstratified I-HIV clays were characterized by a broad peak at 10-14 Å, which did not change its position after Mg-glycerol saturation, but collapsed to 10 Å after heating at 350ºC and 550°C. HRTEM analysis showed different lattice fringes of 12 Å, 10 Å and 7 Å. Mixed-layer I-HIV, HIV-K and illite-kaolinite (I-K) were observed in the HRTEM images which represented the intermediate phases during illite alteration. The merging of two 10 Å illite layers into a 12 Å HIV layer, lateral transformation of one HIV layer into one kaolinite layer and alteration of one illite layer into two kaolinite layers illustrated the mechanisms of illite-to-HIV, HIV-to-kaolinite and illite-tokaolinite transformation, respectively. The proposed pedogenic alteration of illite and the weathering sequence of the clay minerals in Jiujiang is illite → I-HIV → HIV→ HIV-K → kaolinite. In addition, illite may transform directly to kaolinite.

Comparison of the Effects of Latex and) Poly (DADMAC) on Structural Stability and' Strength of Soil Aggregates

Two types of high molecular weight polymers having contrasting charge properties and molecular shapes [latex and poly(DADMAC)] were applied at different rates to three Alfisols and a Mollisol to examine the effects of these polymers on soil strength and structural stability, and to identify some of the mechanisms by which these polymers act to stabilize soils. Wet aggregate stability, mechanically dispersible clay, and soil friability tests were used to assess treatment effects, which were found to be greatest in soils having a poor structural condition. Each polymer acted differently. Latex, which acted like a coat of paint (because of its inability to penetrate beyond the surface of aggregates), dramatically increased the proportion of water stable aggregates >2 mm in all soils examined, and this was achieved without the traditional (expensive) use of aromatic oils and stabilizers. The latex coating produced a conglomeration of smaller soil aggregates, but did not extensively alter either the dispersibility of the aggregates in the face of mechanical action, or their strength and friability. Results indicate latex may be best suited to minimum tillage cropping systems. Poly(DADMAC), by contrast, was capable of entering most pores accessible to water. This enabled it to minimize clay dispersion, increase soil friability, and to modestly increase the size of water stable aggregates. In many ways, poly(DADMAC) would appear to be an ideal soil conditioner, although the economic suitability of this polymer and its effects on erosion control and plant growth have yet to be assessed.

Clay mineralogy and its palaeoclimatic significance in the Luochuan loess-palaeosols over ~1.3 Ma, Shaanxi, northwestern China

To understand climate changes recorded in the Luochuan loess-palaeosols, Shaanxi province, northwestern China, clay mineralogy was studied using X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), and scanning electron microscopy (SEM) methods. XRD results show that clay mineral compositions in the Luochuan loess-palaeosols are dominantly illite, with minor chlorite, kaolinite, smectite, and illite-smectite mixed-layer clays (I/S). Illite is the most abundant species in the sediments, with a content of 61%–83%. The content of chlorite ranges from 5%–22%, and the content of kaolinite ranges from 5%–19%. Smectite (or I/S) occurs discontinuously along the loess profile, with a content of 0–8%. The Kübler index of illite (IC) ranges from 0.255°–0.491°, and the illite chemical index (ICI) ranges from 0.294–0.394. The CIA values of the loesspalaeosols are 61.9–69.02, and the R3+/(R3+ + R2+ + M+) values are 0.508–0.589. HRTEM observations show that transformation of illite to illite-smectite has occurred in both the loess and palaeosol, suggesting that the Luochuan loess-palaeosols have experienced a certain degree of chemical weathering. The Luochuan loess-palaeosols have the same clay mineral assemblage along the profile. However, the relative contents of clay mineral species, CIA, ICI, and IC values fluctuate frequently along the profile, and all these parameters display a similar trend. Moreover, climate changes suggested by the clay index are consistent with variations in the deep-sea δ18O records and the magnetic susceptibility value, and thus, climate changes in the Luochuan region have been controlled by global climate change.

Fe-oxide mineralogy of the Jiujiang red earth sediments and implications for Quaternary climate change, southern China

Diffuse reflectance spectrophotometry (DRS) is a new, fast, and reliable method to characterize Fe-oxides in soils. The Fe-oxide mineralogy of the Jiujiang red earth sediments was investigated using DRS to investigate the climate evolution of southern China since the mid-Pleistocene. The DRS results show that hematite/(hematite + goethite) ratios [Hm/(Hm + Gt)] exhibit an upward decreasing trend within the Jiujiang section, suggesting a gradual climate change from warm and humid in the middle Pleistocene to cooler and drier in the late Pleistocene. Upsection trends toward higher (orthoclase + plagioclase)/quartz ratios [(Or + Pl)/Q] and magnetic susceptibility values (χlf) support this inference, which accords with global climate trends at that time. However, higher-frequency climatic subcycles observed in loess sections of northern China are not evident in the Jiujiang records, indicating a relatively lower climate sensitivity of the red earth sediments in southern China.

Clay Minerals—Organic Matter Interactions in Relation to Carbon Stabilization in Soils

Abstract Stabilization of C in soil is important for minimizing greenhouse gas emission into the atmosphere and for improving the soil fertility. The physical, chemical, and biological properties of soil greatly influence the C protection capacity. Both the physical and chemical properties of soils are directly or indirectly governed by clay minerals, which are the most reactive soil particles. Apart from the amount of clays, clay types are also very important in protecting soil C. Clay minerals provide both permanent and variable surface charges and different specific surface areas that are crucial to determine the C protection capacity of soils. They form organo–mineral complexes, promote aggregate establishment, and protect soil organic matter against microbial decomposition. This chapter aims to provide an overview of the role of various clay minerals in protecting organic C in soils and highlights the mechanisms of C sequestration by clay minerals.

Seen as different, soil clays become more important to soils and also beyond soils

ABSTRACT Using data from the literature, we pose the question of the extent to which a knowledge of soils is contributed by that of its clay fraction. In the past, soil characteristics have not related well to mineralogical analyses but we have redefined clays and also used a computer programme to more closely analyse X-ray diffraction (XRD) profiles. It was found that cation exchange capacities and specific surface areas of soil kaolinites almost always exceed those of standard kaolinites. The surfaces of soil clays are often coated by organic matter, which reduces their capacity to adsorb dissolved organic carbon (DOC). Oxidised iron is closely associated with phyllosilicate clays and enhances their capacity to adsorb DOC. Computer-aided decomposition of XRD traces show that phyllosilicates may contain several phases and react dynamically with potassium-containing solutions. Clays should be regarded as natural products with as yet undiscovered applications, including for cancer treatment.

Correction to: Influence of physico-chemical properties of soil clay fractions on the retention of dissolved organic carbon

Unfortunately, in the original publication of the article, Prof. Yong Sik Ok’s affiliation was incorrectly published. The author’s affiliation is as follows.