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Featured researches published by Goushi Nishida.


Organic Letters | 2008

Practical Enantioselective Synthesis of Axially Chiral Biaryl Diphosphonates and Dicarboxylates by Cationic Rhodium(I)/Segphos-Catalyzed Double [2 + 2 + 2] Cycloaddition

Goushi Nishida; Shuichiro Ogaki; Yukinori Yusa; Tohru Yokozawa; Keiichi Noguchi; Ken Tanaka

A cationic rhodium(I)/Segphos complex catalyzes a [2 + 2 + 2] cycloaddition of internal 1,6-diynes with a phosphonate- or ester-substituted 1,3-butadiyne leading to C(2)-symmetric axially chiral biaryl diphosphonates or dicarboxylates, respectively, in high yields with outstanding ees. The use of a phosphonate- or ester-substituted 1,3-butadiyne as a cycloaddition partner and Segphos as a ligand is crucial for the success of this transformation.


Angewandte Chemie | 2007

Asymmetric assembly of aromatic rings to produce tetra-ortho-substituted axially chiral biaryl phosphorus compounds.

Goushi Nishida; Keiichi Noguchi; Masao Hirano; Ken Tanaka


Angewandte Chemie | 2004

Enantioselective Synthesis of Axially Chiral Phthalides through Cationic [RhI(H8-binap)]-Catalyzed Cross Alkyne Cyclotrimerization†

Ken Tanaka; Goushi Nishida; Azusa Wada; Keiichi Noguchi


European Journal of Organic Chemistry | 2006

Cationic rhodium(I)/modified-BINAP catalyzed [2+2+2] cycloaddition of alkynes with nitriles

Ken Tanaka; Nanami Suzuki; Goushi Nishida


Angewandte Chemie | 2008

Enantioselective Synthesis of P‐Stereogenic Alkynylphosphine Oxides by Rh‐Catalyzed [2+2+2] Cycloaddition

Goushi Nishida; Keiichi Noguchi; Masao Hirano; Ken Tanaka


Organic Letters | 2006

Enantioselective Synthesis of Tetra-ortho-Substituted Axially Chiral Biaryls through Rhodium-Catalyzed Double [2 + 2 + 2] Cycloaddition

Goushi Nishida; Nanami Suzuki; and Keiichi Noguchi; Ken Tanaka


Organic Letters | 2007

Synthesis of perfluoroalkylated benzenes and pyridines through cationic Rh(I)/modified BINAP-catalyzed chemo- and regioselective [2 + 2 + 2] cycloaddition.

Ken Tanaka; Hiromi Hara; Goushi Nishida; Masao Hirano


Organic Letters | 2005

Enantioselective Synthesis of Axially Chiral Biaryls through Rhodium-Catalyzed Complete Intermolecular Cross-Cyclotrimerization of Internal Alkynes

Ken Tanaka; Goushi Nishida; Masakazu Ogino; Masao Hirano; Keiichi Noguchi


Synlett | 2007

Enantioselective Synthesis of C2-Symmetric Dimethyl Cyclohexadiene­dicarboxylates through Cationic Rhodium(I)/Modified-BINAP-Catalyzed [2+2+2] Cycloadditions

Ken Tanaka; Goushi Nishida; Hiromi Sagae; Masao Hirano


Journal of Synthetic Organic Chemistry Japan | 2007

Development of Chemo-, Regio-, and Enantioselective [2+2+2] Cycloadditions Catalyzed by Cationic Rhodium (I) /BINAP-Type Bisphosphine Complexes

Ken Tanaka; Goushi Nishida; Takeshi Suda

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Ken Tanaka

Tokyo Institute of Technology

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Keiichi Noguchi

Tokyo University of Agriculture and Technology

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Yukinori Yusa

Tokyo Institute of Technology

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Nanami Suzuki

Tokyo University of Agriculture and Technology

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