Govindhasamy Murugadoss

Double functions of porous TiO2 electrodes on CH3NH3PbI3 perovskite solar cells: Enhancement of perovskite crystal transformation and prohibition of short circuiting

In order to analyze the crystal transformation from hexagonal PbI2 to CH3NH3PbI3 by the sequential (two-step) deposition process, perovskite CH3NH3PbI3 layers were deposited on flat and/or porous TiO2 layers. Although the narrower pores using small nanoparticles prohibited the effective transformation, the porous-TiO2 matrix was able to help the crystal transformation of PbI2 to CH3NH3PbI3 by sequential two-step deposition. The resulting PbI2 crystals in porous TiO2 electrodes did not deteriorate the photovoltaic effects. Moreover, it is confirmed that the porous TiO2 electrode had served the function of prohibiting short circuits between working and counter electrodes in perovskite solar cells.

Light stability tests of methylammonium and formamidinium Pb-halide perovskites for solar cell applications

We have prepared perovskite [CH3NH3PbI3 (MALI), CH3NH3PbBr3 (MALB), NH2CH=NH2PbI3 (FALI), and NH2CH=NH2PbBr3 (FALB)] thin films by a one-step process on glass/TiO2 and glass/Al2O3 substrates and studied the stability of the perovskite under UV/visible light radiation up to 24 h at 1.5AM in air. After irradiation, the films were characterized by UV–vis absorption and X-ray diffraction measurements. In addition, photovoltaic performance characteristics in air were studied using different perovskites before (0 h) and after 24 h irradiation. The results revealed that Al2O3 protected the perovskite crystal from degradation. However, the perovskites were unstable except for NH2CH=NH2PbI3 under the same conditions using a TiO2 scaffold layer.