Greg D. Barber

Graphane: A two-dimensional hydrocarbon

We predict the stability of an extended two-dimensional hydrocarbon on the basis of first-principles total-energy calculations. The compound that we call graphane is a fully saturated hydrocarbon derived from a single graphene sheet with formula CH. All of the carbon atoms are in

Coupling of Titania Inverse Opals to Nanocrystalline Titania Layers in Dye-Sensitized Solar Cells†

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Enhanced conversion efficiencies for pillar array solar cells fabricated from crystalline silicon with short minority carrier diffusion lengths

hybridization forming a hexagonal network and the hydrogen atoms are bonded to carbon on both sides of the plane in an alternating manner. Graphane is predicted to be stable with a binding energy comparable to other hydrocarbons such as benzene, cyclohexane, and polyethylene. We discuss possible routes for synthesizing graphane and potential applications as a hydrogen storage material and in two-dimensional electronics.

Radial junction silicon wire array solar cells fabricated by gold-catalyzed vapor-liquid-solid growth

We report a quantitative comparison of the photoaction spectra, short circuit current densities, and power conversion efficiencies of dye-sensitized solar cells (DSSCs) that contain bilayers of nanocrystalline TiO2 (nc-TiO2) and titania inverse opal photonic crystals (PCs). Cells were fabricated with PC/nc-TiO2 and nc-TiO2/PC bilayer films on glass/tin oxide anode of the cell, as well as in a split configuration in which the nc-TiO2 and PC layers were deposited on the anode and cathode sides of the cell, respectively. Incident photon current efficiencies at single wavelengths and current-voltage curves in white light were obtained with both cathode and anode side illumination. The results obtained support a model proposed by Miguez and co-workers, in which coupling of the low refractive index PC layer to the higher index nc-TiO2 layer creates a standing wave in the nc-TiO2 layer, enhancing the response of the DSSC in the red region of the spectrum. This enhancement is very sensitive to the degree of physical contact between the two layers. A gap on the order of 200 nm thick, created by a polymer templating technique, is sufficient to decouple the two layers optically. The coupling of the nc-TiO2 and PC layers across the gap could be improved slightly by treatment with TiCl4 vapor. In the bilayer configuration, there is an enhancement in the IPCE across the visible spectrum, which is primarily caused by defect scattering in the PC layer. There is also an increase of 20-50 mV in the open circuit photovoltage of the cell. With anode side illumination, the addition of a PC layer to the nc-TiO2 layer increased the efficiency of DSSCs from 6.5 to 8.3% at a constant N719 dye loading of 155-160 nmol/cm2.

Broadband light absorption with multiple surface plasmon polariton waves excited at the interface of a metallic grating and photonic crystal.

Radial n+–p+ junction solar cells composed of densely packed pillar arrays, 25-μm-tall and 7.5 μm in diameter, fabricated from p-type silicon substrates with extremely short minority carrier diffusion lengths are investigated and compared to planar cells. To understand the two times higher AM 1.5 efficiencies of the pillar array cells, dark and light I-V characteristics as well as spectral responses are presented for the two structures. The higher pillar array cell efficiencies are due to the larger short-circuit currents from the larger photon absorption thickness and the shorter carrier collection length, with a significant additional contribution from multiple reflections in the structure.

Excitation of multiple surface-plasmon-polariton waves guided by the periodically corrugated interface of a metal and a periodic multilayered isotropic dielectric material

The fabrication of radial junction silicon (Si) solar cells using Si wire arrays grown by Au-catalyzed vapor-liquid-solid growth on patterned Si substrates was demonstrated. An important step in the fabrication process is the repeated thermal oxidation and oxide etching of the Si wire arrays. The oxidation cleaning process removes residual catalyst material from the wire tips and exposes additional Au embedded in the material. Using this cleaning process and junction formation through POCl3 thermal diffusion, rectifying p-n junctions were obtained that exhibited an efficiency of 2.3% and open circuit voltages up to 0.5 V under Air Mass 1.5G illumination.

Experimental excitation of multiple surface-plasmon-polariton waves and waveguide modes in a one-dimensional photonic crystal atop a two-dimensional metal grating

Light incident upon a periodically corrugated metal/dielectric interface can generate surface plasmon polariton (SPP) waves. This effect is used in many sensing applications. Similar metallodielectric nanostructures are used for light trapping in solar cells, but the gains are modest because SPP waves can be excited only at specific angles and with one linear polarization state of incident light. Here we report the optical absorptance of a metallic grating coupled to silicon oxide/oxynitride layers with a periodically varying refractive index, i.e., a 1D photonic crystal. These structures show a dramatic enhancement relative to those employing a homogeneous dielectric material. Multiple SPP waves can be activated, and both s- and p-polarized incident light can be efficiently trapped. Many SPP modes are weakly bound and display field enhancements that extend throughout the dielectric layers. These modes have significantly longer propagation lengths than the single SPP modes excited at the interface of a metallic grating and a uniform dielectric. These results suggest that metallic gratings coupled to photonic crystals could have utility for light trapping in photovoltaics, sensing, and other applications.

Buffer layer between a planar optical concentrator and a solar cell

The excitation of multiple surface-plasmon-polariton (SPP) waves guided by the periodically corrugated interface of a homogeneous metal and a periodic multilayered isotropic dielectric (PMLID) material was studied theoretically. The solution of the underlying canonical boundary-value problem (with a planar interface) indicates that multiple SPP waves of different polarization states, phase speeds, and attenuation rates can be guided by the periodically corrugated interface. Accordingly, the boundary-value problem was formulated using rigorous coupled-wave analysis and solved using a numerically stable algorithm. A linearly polarized plane wave was considered obliquely incident on a PMLID material of finite thickness and backed by a metallic surface-relief grating. The total reflectance, total transmittance, and the absorptance were calculated as functions of the incidence angle for different numbers of unit cells in the PMLID material of fixed period. The excitation of SPP waves was indicated by those peaks in the absorptance curves that were independent of the number of unit cells, and these peaks were also correlated with the solutions of a dispersion equation obtained from the canonical boundary-value problem.

Organophosphates as solvents for electrolytes in electrochemical devices.

The excitation of multiple SPP waves as Floquet harmonics was demonstrated in structures fabricated as one-dimensional photonic crystals (PCs) on top of two-dimensional gold gratings. Each period of the PC comprised nine layers of silicon oxynitrides of different compositions, and each PC had either two or three periods. Absorptances for obliquely incident

Experimental investigation of circular Bragg phenomenon for oblique incidence

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