Gregoire Witz
Alstom
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Volume 6: Ceramics; Controls, Diagnostics and Instrumentation; Education; Manufacturing Materials and Metallurgy | 2014
Hans-Peter Bossmann; Thomas Duda; Joerg Krueckels; Sebastian Mihm; Roland Mücke; Gregoire Witz
The assessment of Bondcoat/Thermal barrier coating systems is an inherent part of the lifing process of gas turbine component. On the one hand, coatings are considered in the constitutive modelling — e.g. in the thermal model and for the prediction of eigenfrequencies of gas turbine blades. On the other hand, the influence of the coating system on the lifetime of the part (target cyclic life and target operation hours) needs to be assessed. This paper addresses the prediction of coating lifetime. Lifing models of Bondcoat/Thermal barrier coating systems (BC/TBC) are commonly built using isothermal furnace cyclic tests (FCT). The lifetime of the BC/TBC under such test conditions has been shown to depend on multiple coating parameters like TBC thickness, TBC porosity, BC thickness, BC roughness, and also on testing temperature. For example, the TBC life (defined as time to partial TBC spallation) is reduced with increasing temperature, with increasing TBC thickness and decreasing porosity and BC roughness. When operating in a gas turbine (GT), the TBC surface temperature and the BC temperature depend on engine operating conditions, heat transfer of combustion gas and cooling air, coating microstructure and thickness. For instance, a TBC with high porosity typically demonstrates a lower thermal conductivity than that with low porosity. For otherwise same boundary conditions, the BC temperature will decrease with increasing TBC porosity and increasing TBC thickness. The benefit of having a high coating porosity observed in FCT is further amplified by its impact on reducing the BC temperature in GT operation. To the contrary, the positive impact of a reduced TBC thickness observed in FCT is reduced by its negative impact on an increased BC temperature during GT operation. Taking these effects into account a probabilistic lifing model is proposed based on Monte Carlo simulations. Using this model the impact of the manufacturing scatter on the BC/TBC life can be assessed, and enables improved manufacturing by focusing on those parameters that are most critical for coating lifetime.Copyright
ASME Turbo Expo 2012: Turbine Technical Conference and Exposition | 2012
Markus Schaudinn; Gregoire Witz; Hans-Peter Bossmann
Models for thermal barrier coating lifetime prediction are often based on bondcoat oxidation models leading to an end of life criterion either based on bondcoat full consumption or a critical thermally grown oxide thickness. Such models can be satisfactory on turbine parts where the most common coating delamination modes are black or grey failure which are linked to the bondcoat behaviour. Such models are not reliable for combustor parts with thick thermal barrier coating systems where the most common life limiting factor is the formation of cracks appearing in the ceramic layer few tens of microns above the bondcoat interface. This behaviour is linked to the TBC layer mechanical properties and should be described by a model taking into account the evolution of the TBC mechanical properties during engine operation, the mechanical loads in the ceramic layer and a crack propagation model in the TBC. A study of the strain tolerance of TBC from combustor parts after engine operation was performed by taking samples from combustor liners at various locations having different TBC surface temperature. The strain tolerance of TBC samples was measured by four-point bending and correlated with the TBC microstructure and various engine operation parameters. It was shown that the TBC microstructure has an influence on TBC strain tolerance, and that the evolution of the TBC strain tolerance during engine operation is linked to the TBC temperature as well as the operating hours. The data have been used to develop a predictive model of the evolution of the TBC strain tolerance during engine operation. This model allows optimization of parts reconditioning interval, and provides tools for determining the residual life of coated components.
Volume 6: Ceramics; Controls, Diagnostics and Instrumentation; Education; Manufacturing Materials and Metallurgy | 2014
Gregoire Witz; Klaus F. Staerk; Carlo M. Maggi; Ulrich Krasselt; Hans-Peter Bossmann
Thermal barrier coating lifetime prediction has been commonly performed using furnace cyclic test results. This testing method causes coating failures driven by the bondcoat oxidation. This allows definition of lifetime prediction models representative of the field experience for thin thermal barrier coating systems where the difference between the bondcoat temperature and the coating surface are limited to 100–200 °C. Thick thermal barrier coating systems can experience coating surface temperatures 500 °C higher than the bondcoat temperature. In such cases sintering and phase transformations in the ceramic layers can also affect the coating lifetime. For this reason cyclic test methods like thermal gradient burner rig and laser heat-flux tests have been developed. They allow to test a coating system with surface temperatures >1400 °C while keeping bondcoat temperature <900 °C. The main issue of such tests is the often limited samples statistic, the reproducibility of the test conditions, and the coating failure mode that is not representative of the field experience. In Alstom, a burner rig test has been developed to solve these issues. It allows to test in parallel 10 samples, with a closed loop control system allowing live adjustment of the heat and cooling air input to keep an individually controlled constant thermal gradient with a homogeneous temperature distribution on the sample surface. Modeling of the test has been performed to understand the coating failure mechanism and to adapt the testing conditions such to get a failure mechanism closer to the relevant degradation mechanisms experienced in the field. Testing of coatings coming from the same production batch in various test campaign shows a low scatter in test results confirming that the burner rig test design allowed solving the test reproducibility and samples statistics issues. Examples will be shown how this burner rig test can be used for the development of lifetime prediction rules for thermal barrier coating systems.© 2014 ASME
Journal of the American Ceramic Society | 2007
Gregoire Witz; Valery Shklover; Walter Steurer; Sharath Bachegowda; Hans-Peter Bossmann
Journal of Computational and Theoretical Nanoscience | 2008
Valery Shklover; Leonid Braginsky; Gregoire Witz; Matthew Mishkirey; Christian Hafner
Journal of The European Ceramic Society | 2011
Anup K. Bhattacharya; Valery Shklover; Walter Steurer; Gregoire Witz; Hans-Peter Bossmann; Olga Fabrichnaya
Physical Review B | 2007
Leonid Braginsky; Valery Shklover; Gregoire Witz; H.-P. Bossmann
Surface & Coatings Technology | 2015
Gregoire Witz; Valery Shklover; Walter Steurer; Sharath Bachegowda; H.-P. Bossmann
Journal of Engineering for Gas Turbines and Power-transactions of The Asme | 2016
Gregoire Witz; Markus Schaudinn; Joerg Sopka; Tobias Buecklers
Archive | 2014
Gregoire Witz; Mathieu Esquerre; Michael Stuer; Daniel Renusch; Hans-Peter Bossmann