Gregory J. Holk

Mobile Pb-isotopes in Proterozoic sedimentary basins as guides for exploration of uranium deposits

Lead isotope ratios and associated trace element concentrations (U, Th and Pb) extracted by partial-leaching with 2% nitric acid from Proterozoic sandstones and basement rocks reveal much about the fluid evolution of sedimentary basins hosting unconformity-type uranium deposits. In addition, these techniques have great potential as a guide for exploration of uranium and other types of deposits in basins of any age. Isotope ratios of Pb in Proterozoic sandstones from basins known to contain high-grade uranium deposits are radiogenic at key geological localities and settings distal to known mineralization and particularly in altered zones proximal to mineralization. Sandstones completely cemented by quartz overgrowths typically have non-radiogenic Pb isotope ratios, indicating early closure of porosity and isolation of these rocks from later fluid events. Alternatively, the unconformity served as both a source of uranium and radiogenic Pb as well as an avenue for late-stage (<250–900 Ma) fluid flow. The mafic volcanic units, which are relatively reducing lithologies and therefore have removed uranium from basinal brines, have uranium-supported radiogenic Pb isotope ratios. Comparison of 238U/206Pb and 206Pb/204Pb ratios is useful in determining the timing and nature of U and Pb migration before, during and after mineralization in these basins. This comparison can be used to delineate the presence of radiogenic Pb isotope ratios that are not internally supported by uranium and thorium in rocks, eventually providing the explorationist with geochemical vectors that point toward sites of high potential for economic uranium mineralization.

Enhancing Diversity in the Geosciences.

Abstract An innovative interdisciplinary project at California State University, Long Beach, was designed to increase the attractiveness of the geosciences (physical geography, geology, and archaeology) to underrepresented groups. The goal was to raise awareness of the geosciences by providing summer research opportunities for underrepresented high school and community college students and their faculty. A survey of a larger sample provided insight into strategies for enhancing geoscience awareness. A qualitative evaluation pointed to its success in meeting project goals. This unprecedented level of collaboration has set the groundwork for an institutional shift for inclusion of minorities in the geosciences and warrants replication.

Ethnic differences in geoscience attitudes of college students

While a gender balance remains elusive in the geosciences [de Wet et al., 2002], the underrepresentation of ethnic minorities in these fields is at least as great a concern. A number of cultural and social factors have been proposed to explain the poor ethnic minority representation in the geosciences, including limited exposure to nature, deficient academic preparation, inadequate financial resources to pursue higher education, ignorance of career opportunities in the geosciences, insufficient family support, and misconceptions of the field.

Stable Isotope Evidence for Large-Scale Infiltration of Metamorphic Fluids Generated during Shallow Subduction into the Eastern Peninsular Ranges Mylonite Zone (EPRMZ), Southern California

New δ18O and δD data confirm and amplify the conclusion by Holk et al. (1991) that, during the late Cretaceous or earliest Tertiary, there was large-scale infiltration of metamorphic water at depths of at least 15 km into the lower plate of the EPRMZ, a major crustal shear zone that transects a 15 x 15 km tonalite pluton west of Borrego Springs, California. Whole-rock δ18O values in undeformed tonalite are +11.2 ± 0.4 (n = 9) and in mylonitized tonalite are +12.3 ± 0.3 (n = 21), indicating a 1 per mil increase in 18O during open-system water-rock exchange. Quartz, feldspar, and biotite δ18O values in undeformed tonalite are +12.9 ± 0.4 (n = 8), +11.0 ± 0.6 (n = 8), and +7.7 ± 0.7 (n = 8), compared with +13.5 ± 0.2 (n = 8), +11.8 ± 0.3 (n = 9), and +9.2 ± 0.3 (n = 10) in mylonitized tonalite. The extremely uniform quartz-feldspar and quartz-biotite 18O fractionations in the mylonitized tonalite indicate equilibration at 500-600°C. Biotite and hornblende δD values from undeformed tonalite are -73 ± 3 (n = 12), compared with -52 to -68 (n = 21) in mylonitic tonalite, even though the biotite and hornblende have the same Fe/Mg (≈1.25; Anderson, 1983) in both kinds of tonalite. This implies that the EPRMZ was infiltrated by large amounts of high-D water (δD ≈ -10 to -30) at 500-600°C, probably derived at depth by dehydration of subducted oceanic crust or underplated volcanogenic sediments. Syndeformational tonalitic pegmatites have quartz and feldspar δ18O values of +13.5 ± 0.3 (n = 4) and +12.2 ± 0.3 (n = 6), and biotite and muscovite δD values of -64 ± 1 (n = 2) and -42 (n = 1), suggesting a genetic relationship between the pegmatites and these deep-seated fluids. Higher whole-rock δ18O values (+13.2 to +16.1, n = 3) and much lower δD values (-72 to -114, n = 3) occur where the EPRMZ cuts upper-plate amphibolite-facies metasediments. The shift to lower δD values in these finer grained rocks probably occurred during interactions with heated meteoric groundwaters during Pliocene detachment faulting associated with the opening of the Gulf of California.

A two-stage fluid history for the Orocopia Schist and associated rocks related to flat subduction and exhumation, southeastern California

ABSTRACT Stable isotopes combined with pre-existing 40Ar/39Ar thermochronology at the Gavilan Hills and Orocopia Mountains in southeastern California record two stages of fluid–rock interaction: (1) Stage 1 is related to prograde metamorphism as Orocopia Schist was accreted to the base of the crust during late Cretaceous–early Cenozoic Laramide flat subduction. (2) Stage 2 affected the Orocopia Schist and is related to middle Cenozoic exhumation along detachment faults. There is no local evidence that schist-derived fluids infiltrated structurally overlying continental rocks. Mineral δ18O values from Orocopia Schist in the lower plate of the Chocolate Mountains fault and Gatuna normal fault in the Gavilan Hills are in equilibrium at 490–580°C with metamorphic water (δ18O = 7–11‰). Phengite and biotite δD values from the Orocopia Schist and upper plate suggest metamorphic fluids (δD ~ –40‰). In contrast, final exhumation of the schist along the Orocopia Mountains detachment fault (OMDF) in the Orocopia Mountains was associated with alteration of prograde biotite and amphibole to chlorite (T ~ 350–400°C) and the influx of meteoric-hydrothermal fluids at 24–20 Ma. Phengites from a thin mylonite zone at the top of the Orocopia Schist and alteration chlorites have the lowest fluid δD values, suggesting that these faults were an enhanced zone of meteoric fluid (δD < –70‰) circulation. Variable δD values in Orocopia Schist from structurally lower chlorite and biotite zones indicate a lesser degree of interaction with meteoric-hydrothermal fluids. High fluid δ18O values (6–12‰) indicate low water–rock ratios for the OMDF. A steep thermal gradient developed across the OMDF at the onset of middle Cenozoic slip likely drove a more vigorous hydrothermal system within the Orocopia Mountains relative to the equivalent age Gatuna fault in the Gavilan Hills.