Guangqing Du

Bioinspired wetting surface via laser microfabrication.

Bioinspired special wettibilities including superhydrophobicity and tunable adhesive force have drawn considerable attention because of their significant potential for fundamental research and practical applications. This review summarizes recent progress in the development of bioinspired wetting surfaces via laser microfabrication, with a focus on controllable, biomimetic, and switchable wetting surfaces, as well as their applications in biology, microfluidic, and paper-based devices, all of which demonstrate the ability of laser microfabrication in producing various multiscale structures and its adaptation in a great variety of materials. In particular, compared to other techniques, laser microfabrication can realize special modulation ranging from superhydrophilic to superhydrophobic without the assistance of fluorination, allowing much more freedom to achieve complex multiple-wettability integration. The current challenges and future research prospects of this rapidly developing field are also being discussed. These approaches open the intriguing possibility of the development of advanced interfaces equipped with the integration of more functionalities.

A simple way to achieve superhydrophobicity, controllable water adhesion, anisotropic sliding, and anisotropic wetting based on femtosecond-laser-induced line-patterned surfaces

The superhydrophobicity, controllable water adhesion, anisotropic sliding, and anisotropic wetting, which are four typical aspects of the wettability of solid surfaces, have attracted much interest in fundamental research and practical applications. However, how to use a simple and effective method to realize all those properties is still a huge challenge. Here, we present a method to realize periodic line-patterned polydimethylsiloxane (PDMS) surfaces by a femtosecond laser simply and efficiently. By adjusting the period (D) or average distance of adjacent microgrooves, the as-prepared surfaces can exhibit superhydrophobicity, controllable water adhesion, anisotropic sliding, and anisotropic wetting. We believe that these multifunctional surfaces have enormous potential applications in novel microfluidic devices, microdroplet manipulation, liquid microdroplet directional transfer, and lab-on-chips.

Rapid Fabrication of Large-Area Concave Microlens Arrays on PDMS by a Femtosecond Laser

A fast and single-step process is developed for the fabrication of low-cost, high-quality, and large-area concave microlens arrays (MLAs) by the high-speed line-scanning of femtosecond laser pulses. Each concave microlens can be generated by a single laser pulse, and over 2.78 million microlenses were fabricated on a 2 × 2 cm(2) polydimethylsiloxane (PDMS) sheet within 50 min, which greatly enhances the processing efficiency compared to the classical laser direct writing method. The mechanical pressure induced by the expansion of the laser-induced plasmas as well as a long resolidifing time is the reason for the formation of smooth concave spherical microstructures. We show that uniform microlenses with different diameters and depths can be controlled by adjusting the power of laser pulses. Their high-quality optical performance is also demonstrated in this work.

Bioinspired underwater superoleophobic surface with ultralow oil-adhesion achieved by femtosecond laser microfabrication

Femtosecond laser microfabrication has been recently utilized in interface science to modify the liquid wettability of solid surfaces. In this paper, a silicon surface with hierarchical micro/nanostructure is fabricated by a femtosecond laser. Similar to fish scales, the laser-induced surface shows superhydrophilicity in air and superoleophobicity underwater. The oil contact angles can reach up to 159.4 ± 1° and 150.3 ± 2°, respectively, for 1,2-dichloroethane and chloroform droplets in water. In addition, the surface exhibits ultralow oil-adhesion. In the oil–water–solid three-phase system, water can be trapped in the hierarchical rough structure and form a repulsive oil layer according to the extended Cassies theory. The contact area between the as-prepared surface and oil droplets is significantly reduced, resulting in superoleophobicity and ultralow oil-adhesion in water. In addition, as a potential application, the working principle diagram of preventing blockage ability of underwater superoleophobic pipes is propounded.

Bioinspired transparent underwater superoleophobic and anti-oil surfaces

Reported here is a bioinspired fabrication of transparent underwater superoleophobic and anti-oil surfaces using a femtosecond laser treatment. Rough nanoscale structures were readily created on silica glass surfaces by femtosecond laser-induced ablation. Underwater superoleophobicity and ultralow oil-adhesion were obtained by the rough nanostructures with a wide variation of processing parameters, and the as-prepared surfaces exhibited a high transparency in water. This phenomenon is attributed to the presence of the water environment because scattering and refraction are effectively weakened. As a maskless and cost-effective method, the femtosecond laser processing of transparent materials (glass) may provide a new method to create biomimetic transparent underwater surfaces, allowing for the development of novel underwater anti-oil optical devices.

Versatile route to gapless microlens arrays using laser-tunable wet-etched curved surfaces

This work reveals a cost-efficient and flexible approach to various microlens arrays on polymers, which is essential to micro-optics elements. An 800-nm femtosecond laser is employed to control the hydrofluoric (HF) acid etching process on silica glasses, and concave microstructures with smooth curved surfaces are produced by this method. Then, the micro-structured glass templates can serve as molds for replicating microlenses on polymers. In this paper, a high-ordered microlens array with over 16,000 hexagonal-shaped lenses is fabricated on poly (dimethyl siloxane) [PDMS], and its perfect light-gathering ability and imaging performance are demonstrated. The flexibility of this method is demonstrated by successful preparation of several concave molds with different patterns which are difficult to be obtained by other methods. This technique provides a new route to small-scaled, smooth and curved surfaces which is widely used in micro-optics, biochemical analysis and superhydrophobic interface.

Direct fabrication of seamless roller molds with gapless and shaped-controlled concave microlens arrays

This Letter demonstrates the direct fabrication of gapless concave microlenses on glass cylinders, which can be used as seamless roller molds for the continuous imprinting of large-area microlens arrays. The method involves femtosecond laser exposures followed by a chemical wet-etching process. A honeycomb-like concave microlens array was fabricated on a glass cylinder with a diameter of 3 mm. We demonstrated the flexibility of the method in tuning the shape and depth of the concave structures by the arrangements of the laser exposure spots and laser powers, and examined the replicating ability of the roller mold by the polymer castling method.

Bioinspired superhydrophobic surfaces with directional Adhesion

Butterfly wings have the ability to directionally control the movement of water microdroplets. However, the realization of artificial directional sliding biosurfaces has remained challenging. Inspired by butterfly wings, a new kind of directional patterned surface is developed to achieve superhydrophobicity and anisotropic adhesive properties at the one-dimensional level. The surface is composed of a hydrophobic triangle array and surrounding superhydrophobic structure. On the as-prepared surface, a droplet rolls along one direction distinctly easier than its opposite direction. The maximum anisotropy of sliding angles along two opposite directions can reach 21°. This unique ability is ascribed to the direction-dependent arrangement of the two-dimensional (2D) triangle array patterns. The directional adhesive superhydrophobic surfaces could be potentially applied in novel microfluid-controllable devices and directional easy-cleaning coatings.

Rapid fabrication of a large-area close-packed quasi-periodic microlens array on BK7 glass

Large-area close-packed microlens arrays (MLAs) are highly desirable for structured light and integrated optical applications. However, efficient realization of ultralarge area MLAs with a high fill factor is still technically challenging, especially on glass material. In this Letter we propose a high-efficiency MLA fabrication method using single-pulsed femtosecond laser wet etch and close-packed quasi-periodic concave MLAs consisting of three million units fabricated on silica glass within an hour. The fabricated MLAs are demonstrated to have extreme optical smoothness (∼8.5 nm) by an atomic force microscope. It has also been demonstrated that the profile of the quasi-periodic concave structures could be easily tuned by changing the laser scanning speed or the pulse energy. Additionally, the optical performances of the MLA diffusers were investigated by using sharp focusing, high-resolution imaging, and flat-top illumination.

A bioinspired planar superhydrophobic microboat

In nature, a frog can easily rest on a lotus leaf even though the frog’s weight is several times the weight of the lotus leaf. Inspired by the lotus leaf, we fabricated a planar superhydrophobic microboat (SMB) with a superhydrophobic upper surface on a PDMS sheet which was irradiated by a focused femtosecond laser. The SMB can not only float effortlessly over the water surface but can also hold up some heavy objects, exhibiting an excellent loading capacity. The water surface is curved near the edge of the upper surface and the SMB’s upper edge is below the water level, greatly enhancing the displacement. Experimental results and theoretical analysis demonstrate that the superhydrophobicity on the edge of the upper surface is responsible for the SMB’s large loading capacity. Here, we call it the ‘superhydrophobic edge effect’.