Guilan Zhang

Structural characterization and optical properties of nanometer-sized SnO2 capped by stearic acid

Structure and optical properties of nanometer-sized SnO2 capped by a layer of stearic acid are investigated using TEM, XRD, ESR, UV-visible absorption spectrum, photoluminescence spectra, IR absorption spectra and Z-scan techniques. It is found that such capped SnO2 samples display new optical properties, which will enlarge their applications in nonlinear optics. The relationship between structure and optical properties of the SnO2 nanoparticles is also discussed.

Optical nonlinearities of Fe2O3 nanoparticles investigated by Z-scan technique

Abstract The single beam Z-scan technique has been used to measure the third-order nonlinear refractive index, γ, the two-photon absorption coefficient, s, and the variation of refractive index per unit photoexcited carrier density σ r , and the free carrier absorption cross section σ ab for quantum-confined Fe 2 O 3 nanoparticles coated by a layer of organic molecular in toluene and bare particles in hydrosol. For coated Fe 2 O 3 nanoparticles, the ratio γ/s is enhanced by a factor of five compared to the bare sample. Their figures of merit related to linear and two-photon absorption for ultrafast all-optical devices application were determined.

Biphotonic self-diffraction in azo-doped polymer film

A new nonlinear optical phenomenon, biphotonic self-diffraction (BSD), is reported in azo dye doped in polymer matrix. The first-order and the second-order BSD signals are observed in the experiment. It is demonstrated that the dynamic behaviors of the BSD signals are dependent on the cis-trans isomerization of azo molecules by two color lights.

Optical nonlinearities and transient dynamics of 2-(2′-hydroxyphenyl)benzoxazole studied by single-beam and time-resolved two-color Z-scan techniques

Optical nonlinearities (including nonlinear absorption and nonlinear refraction) and the temporal properties of the nonlinear refraction of 2-(2′-hydroxyphenyl)benzoxazole (HBO) based on excited-state intramolecular proton transfer in its two-photon absorption (TPA) range have been investigated, for the first time to our knowledge, by single-beam and time-resolved two-color Z-scan techniques. By establishing the kinetic model of HBO that is due to the TPA, we obtained the TPA coefficient, the molecular hyperpolarizability of the ground state of the enol tautomer of HBO, and the nonlinear refraction, represented by σr, of the excited state of the keto tautomer of HBO. The theoretical results are in good agreement with the experimental ones, which shows that, on the one hand, the excited-state intramolecular proton transfer of HBO can be achieved through the excitation in its TPA range and that, on the other hand, the optical nonlinearities of HBO are closely related to the dynamics of HBO that are involved in the excited-state intramolecular proton transfer.

Research on the up-conversion luminescence of Tm3+ ion in crystal and amorphous pentaphosphate materials

Abstract Ultraviolet and dark blue upconversion luminescence of Tm3+ ion in TmP5O14 crystal as well as in amorphous Tm0.1La0.9P5O14 are reported. A compound upconversion mechanism involving both stepwise two-photon absorption of a single ion and cooperative energy transfer between two ions is observed. We also present here the methods and procedures to analyze the phenomenon and mechanism of luminescence, as well as our comments on the differences and similarities between crystalline and non-crystalline, high-concentration and low-concentration materials.

Red-band holographic storage in azo dye sensitized by noncoherent light

Biphoton holographic storage recorded with 633-nm He-Ne beams has been investigated in Methyl Yellowdoped polystyrene film sensitized by weak noncoherent light from a low-pressure Hg lamp. It is demonstrated that the holography in the sample is erasable without fading. The dynamic behavior of the hologram is dependent on the cis-trans isomerization by noncoherent light and 633-nm beams and photoinduced heat.

The infrared vibration characteristics of SnO2 nanoparticles

The infrared vibration characteristics of SnO2 nanoparticles with different sizes were studied using the infrared spectra. The Frohlich modes were observed in experiments and compared with the theoretical values. The influence of phonon localization resulting from quantum size effects on the infrared spectra of SnO2 nanoparticles is discussed.

Optical nonlinearities of hypocrellin A with the excitation of nanosecond pulses

Nonlinear absorption and nonlinear refraction in the resonant region and the two-photon absorption (TPA) region of hypocrellin A (HA) have been investigated, for the first time to our knowledge, using the Z-scan technique and intensity-dependent transmittance measurement with nanosecond pulses. At 0.53 μm the effective absorption of the triplet state of the normal form of HA is the dominant mechanism causing the reverse saturable absorption. The refractive nonlinearities of HA can be mainly attributed to the thermal effect. With the excitation at 1.06 μm the optical limiting behavior in HA may be caused by the TPA of its ground state. The ground state of HA exhibits a large real part of second-order hyperpolarizability. By establishing the kinetic model for HA, we obtained several nonlinear optical parameters, such as the cross section of TPA, the absorption cross sections of the excited state and the triplet state of the normal form of HA, and the real part of second-order hyperpolarizability of the ground state of HA. The theoretical results are in good agreement with the experimental ones, which not only shows the completeness of the kinetic model but also demonstrates the close relationship between the optical nonlinearities of HA and its dynamic processes. In addition, HA has been proved to be a potential optical limiting material.

INVESTIGATION ON NONLINEAR TRANSMISSION PROPERTY OF EXCITED STATE PROTON TRANSFER MOLECULE 2-(2′-HYDROXYPHENYL)BENZOXAZOLE

Nonlinear transmission property of excited state proton transfer molecule 2-(2′-hydroxyphenyl)benzoxazole was investigated at 355 nm and 532 nm using picosecond laser pulses. The experiment result shows that the transmissivity of 2-(2′-hydroxyphenyl)benzoxazole is nonlinear at 355 nm but it is linear at 532 nm. The nonlinear transmissivity of 2-(2′-hydroxyphenyl)benzoxazole originates from the larger nonlinearity of tautomer formed in excited state proton transfer process. Therefore 2-(2′-hydroxyphenyl)benzoxazole might be used as ultrafast optical amplitude limit material.

EFFECT OF SOLVENT ON NONLINEAR REFRACTION INDEX OF 7-HYDROXYQUINOLINE

Nonlinear refraction index n2 of 7-hydroxyquinoline in different solvents was measured using Z-scan techniques with picosecond laser pulse. The effect of solvent on the nonlinear refraction index n2 of 7-hydroxyquinoline was investigated. The origination of this effect was due to the interaction between 7-hydroxyquinoline and the solvent molecules via H-bond.