Guralp Ozkoc

Thermally induced shape memory behavior, enzymatic degradation and biocompatibility of PLA/TPU blends: “Effects of compatibilization”

Poly(lactic acid) (PLA)/thermoplastic polyurethane (TPU) blends were melt-mixed and compatibilized to investigate their biocompatibility, biodegradability and thermally induced shape memory properties. The blend compositions were PLA/TPU: 80/20 (20TPU) and PLA/TPU: 50/50 (50TPU). 1,4-phenylene diisocyanate (PDI) was used in order to compatibilize the components reactively. The PDI composition was 0.5, 1, 3% by weight. Biodegradability was assessed by enzymatic degradation tests. Biocompatibility was investigated through in-vitro cell-culture experiments. Shape memory tests exhibited that 20TPU blends have higher recovery ratio than that of 50TPU blends. It was observed that the shape recovery ratio was enhanced by the addition of PDI. The highest shape recovery ratio was obtained at 3%PDI in 20TPU blends. Enzymatic biodegradability tests showed that the increasing TPU content decreased the biodegradability of the blends. It was found that compatibilization slowed down the enzymatic degradation of PLA/TPU blends. In-vitro cell-culture experiments indicated that all blends were biocompatible, and no evidence of cytotoxicity was observed.

Properties of modified ethylene terpolymer/poly(lactic acid) blends based films

In order to explore an alternative method instead of plasticization for improving the toughness, flexibility and processability of PLA based packaging films, two different kinds of modified polyethylene based elastomers, such as glycidyl methacrylate or maleic anhydride functionalized ethylene-acrylate based elastomers, were melt blended with PLA. Their properties were compared with conventional PEG plasticized PLA. The chemical interaction between end groups of PLA and epoxide or maleic anhydride functional groups of elastomers was shown by FTIR. Scanning electron microscopy showed that up to 20 % PEG loading, one phase morphology was achieved, however beyond this point, a phase separation was observed for plasticized PLA. For PLA/elastomer blends, a two-phase morphology was obtained as a result of immiscible nature of PLA and elastomers. Tensile and dynamic mechanical properties indicated that elastomer based blends were better than plasticized PLA independently from elastomer type. Differential scanning calorimeter (DSC) analysis exhibited that the Tg value was remarkably lowered in the plasticized PLA; however, it did not change in the case of elastomers. In terms of oxygen permeability and biodegradability, plasticized PLA was found to be better than elastomer based blends.

Effects of Diisocyanate and Polymeric Epoxidized Chain Extenders on the Properties of Recycled Poly(Lactic Acid)

Increasing demand in the use of poly(lactic acid) (PLA) leads to a debate about using potential foodstuffs for plastic production and a moral issue when starvation problem is taken into account. One of the solutions is recycling of PLA; however, recycling results in property losses during melt processing due to low thermal stability of PLA. This study focuses on using chain extenders to offset thermal degradation of recycled PLA. The effects of a diisocyanate and a polymeric epoxidized chain extender on the properties of the recycled poly(lactic acid) were investigated. In order to mimic the recycling process, PLA was subjected to thermo-mechanical degradation using a laboratory scale compounder. Chain extender type, loading and mixing time were investigated. On-line rheology and intrinsic viscosity measurements of PLA before and after chain extension confirmed that the molecular weight increased. Dynamic mechanical analysis, rheology and tensile tests revealed that the chain extenders led to a significant increase in modulus, strength and melt-viscosity. It was found that diisocyanate had slightly higher and faster chain extension reactivity than polymeric extender. Differential scanning calorimetry results showed an increase in the crystallization temperature due to the branched and extended chain structure.

Micro and Nanofillers in Rubbers

As a most general definition, filler is a finely divided solid that is used to modify the properties of a material in which it is dispersed. From the inception of the rubber industry, fillers have a crucial role in either providing durability and performance or in reducing the price by decreasing the rubber partition in the compound. The fillers used in rubbers can be divided into two main groups such as black and non-black fillers. Besides the conventional micron size fillers, nanofillers recently have gained both academic and industrial importance. In this chapter, it is aimed to introduce the fillers used in rubbers. Their characteristics and their impact on properties of rubbers are discussed by giving examples from the recently published literature. In addition to the conventional ones, the new emerging nano-fillers and their added value to the rubbers are given in detail by highlighting some selected studies.

Effects of epoxy-POSS nanoparticles on the properties of PLA/TPU blends

In this study, the influence of epoxy functionalized polyhedral oligomeric silsesquioxanes (G-POSS) loading level on the mechanical, thermal and rheological properties of poly(lactic acid) (PLA)/thermoplastic polyurethane (TPU) blends were investigated. The blends were prepared in an Xplore Instruments MC15 twin-screw microcompounder at 200°C barrel temperature and 100 rpm screw speed. Mechanical properties were characterized by tensile and impact tests, thermal properties were determined via differential scanning calorimeter (DSC) and thermogravimetric analysis (TGA). Rheological properties were examined by oscillatory rheometer. A decreasing trend in tensile strength and thermal degradation temperature were obtained for PLA/TPU blends at high G-POSS loading levels. G-POSS loading level did not exhibit significant effect on glass transition, crystallization and melting temperatures of the blends.

Correlation between crystallization behaviour and interfacial interactions in plasticized PLA/POSS nanocomposites

In this study, the correlation between crystallization behavior and surface chemistry of polyhedral oligomeric silsesquioxanes (POSS) for plasticized poly(lactic acid) (PLA)/POSS nanocomposites was investigated. Four different kinds of POSS particles having different chemical structures were used. Poly(ethylene glycol) (PEG, 8000 g/mol) was utilized as the plasticiser. The nanocomposites were melt-compounded in an Xplore Instruments 15 cc twin screw microcompounder at 180°C barrel temperature and 100 rpm screw speed. Non-isothermal crystallization behaviour of PLA/PEG/POSS nanocomposites were evaluated from common kinetic models such as Avrami and Avrami-Ozawa and Kissinger by using the thermal data obtained from differantial scanning calorimetry (DSC). A polarized optical microscope (POM) equipped with a hot-stage was used to examine the morphology during the crystal growth. In order to investigate the interfacial interactions between POSS particles and plasticized PLA, thermodynamic work of adhesion app...