Gustavo Domínguez-Espinosa
Polytechnic University of Valencia
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Publication
Featured researches published by Gustavo Domínguez-Espinosa.
Journal of Chemical Physics | 2005
Gustavo Domínguez-Espinosa; Ricardo Díaz-Calleja; Evaristo Riande; Ligia Gargallo; Deodato Radić
The relaxation behavior of poly(2,3-dichlorobenzyl methacrylate) is studied by broadband dielectric spectroscopy in the frequency range of 10(-1)-10(9) Hz and temperature interval of 303-423 K. The isotherms representing the dielectric loss of the glassy polymer in the frequency domain present a single absorption, called beta process. At temperatures close to Tg, the dynamical alpha relaxation already overlaps with the beta process, the degree of overlapping increasing with temperature. The deconvolution of the alpha and beta relaxations is facilitated using the retardation spectra calculated from the isotherms utilizing linear programming regularization parameter techniques. The temperature dependence of the beta relaxation presents a crossover associated with a change in activation energy of the local processes. The distance between the alpha and beta peaks, expressed as log(fmax;beta/fmax;alpha) where fmax is the frequency at the peak maximum, follows Arrhenius behavior in the temperature range of 310-384 K. Above 384 K, the distance between the peaks remains nearly constant and, as a result, the a onset temperature exhibited for many polymers is not reached in this system. The fraction of relaxation carried out through the alpha process, without beta assistance, is larger than 60% in the temperature range of 310-384 K where the so-called Williams ansatz holds.
IV INTERNATIONAL CONFERENCE TIMES OF POLYMERS (TOP) AND COMPOSITES | 2008
M. J. Sanchis; Gustavo Domínguez-Espinosa; Ricardo Díaz-Calleja; Luz Alegría; Ligia Gargallo; D. Radic
With the aim to investigate the influence of slight differences in the chemical structure of a family of polymers on the response of these to electric perturbation fields, the relaxation behavior of three dimethoxy phenyl isomers of poly(benzyl methacrylate) have been studied.
Journal of Physical Chemistry C | 2007
Natalia A. Nikonorova; Evgeny Barmatov; D. A. Pebalk; Marina Barmatova; Gustavo Domínguez-Espinosa; Ricardo Díaz-Calleja; P. Pissis
Macromolecules | 2006
Gustavo Domínguez-Espinosa; Ricardo Díaz-Calleja; Evaristo Riande; Ligia Gargallo; Deodato Radić
Polymer | 2009
Amparo Navarro; M. Paz Fernández-Liencres; Tomás Peña-Ruiz; José M. Granadino-Roldán; Manuel Fernández-Gómez; Gustavo Domínguez-Espinosa; M. J. Sanchis
Macromolecules | 2006
Gustavo Domínguez-Espinosa; Ricardo Díaz-Calleja; Evaristo Riande
Polymer | 2005
Gustavo Domínguez-Espinosa; M. J. Sanchis; Ricardo Díaz-Calleja; Claudia Pagueguy; Ligia Gargallo; Deodato Radić
Journal of Chemical Physics | 2007
Abel García-Bernabé; Gustavo Domínguez-Espinosa; Ricardo Díaz-Calleja; Evaristo Riande; Rainer Haag
Polymer | 2005
Gustavo Domínguez-Espinosa; M. J. Sanchis; Ricardo Díaz-Calleja; Claudia Pagueguy; Ligia Gargallo; Deodato Radić
Journal of Non-crystalline Solids | 2007
Ricardo Díaz-Calleja; Gustavo Domínguez-Espinosa; Evaristo Riande