H. Balsiger

The Cluster Ion Spectrometry (CIS) Experiment

The Cluster Ion Spectrometry (CIS) experiment is a comprehensive ionic plasma spectrometry package on-board the four Cluster spacecraft capable of obtaining full three-dimensional ion distributions with good time resolution (one spacecraft spin) with mass per charge composition determination. The requirements to cover the scientific objectives cannot be met with a single instrument. The CIS package therefore consists of two different instruments, a Hot Ion Analyser (HIA) and a time-of-flight ion COmposition and DIstribution Function analyser (CODIF), plus a sophisticated dual-processor-based instrument-control and Data-Processing System (DPS), which permits extensive on-board data-processing. Both analysers use symmetric optics resulting in continuous, uniform, and well-characterised phase space coverage. CODIF measures the distributions of the major ions (H+, He+, He++, and O+) with energies from ~0 to 40 keV/e with medium (22.5°) angular resolution and two different sensitivities. HIA does not offer mass resolution but, also having two different sensitivities, increases the dynamic range, and has an angular resolution capability (5.6° × 5.6°) adequate for ion-beam and solar-wind measurements.

67P/Churyumov-Gerasimenko, a Jupiter family comet with a high D/H ratio

The provenance of water and organic compounds on Earth and other terrestrial planets has been discussed for a long time without reaching a consensus. One of the best means to distinguish between different scenarios is by determining the deuterium-to-hydrogen (D/H) ratios in the reservoirs for comets and Earth’s oceans. Here, we report the direct in situ measurement of the D/H ratio in the Jupiter family comet 67P/Churyumov-Gerasimenko by the ROSINA mass spectrometer aboard the European Space Agency’s Rosetta spacecraft, which is found to be (5.3 ± 0.7) × 10−4—that is, approximately three times the terrestrial value. Previous cometary measurements and our new finding suggest a wide range of D/H ratios in the water within Jupiter family objects and preclude the idea that this reservoir is solely composed of Earth ocean–like water.

Time variability and heterogeneity in the coma of 67P/Churyumov-Gerasimenko

Comets contain the best-preserved material from the beginning of our planetary system. Their nuclei and comae composition reveal clues about physical and chemical conditions during the early solar system when comets formed. ROSINA (Rosetta Orbiter Spectrometer for Ion and Neutral Analysis) onboard the Rosetta spacecraft has measured the coma composition of comet 67P/Churyumov-Gerasimenko with well-sampled time resolution per rotation. Measurements were made over many comet rotation periods and a wide range of latitudes. These measurements show large fluctuations in composition in a heterogeneous coma that has diurnal and possibly seasonal variations in the major outgassing species: water, carbon monoxide, and carbon dioxide. These results indicate a complex coma-nucleus relationship where seasonal variations may be driven by temperature differences just below the comet surface.

The Toroidal Imaging Mass-Angle Spectrograph (TIMAS) for the POLAR Mission

The science objectives of the Toroidal Imaging Mass-Angle Spectrograph (TIMAS) are to investigate the transfer of solar wind energy and momentum to the magnetosphere, the interaction between the magnetosphere and the ionosphere, the transport processes that distribute plasma and energy throughout the magnetosphere, and the interactions that occur as plasma of different origins and histories mix and interact. In order to meet these objectives the TIMAS instrument measures virtually the full three-dimensional velocity distribution functions of all major magnetospheric ion species with one-half spin period time resolution. The TIMAS is a first-order double focusing (angle and energy), imaging spectrograph that simultaneously measures all mass per charge components from 1 AMU e−1 to greater than 32 AMU e−1 over a nearly 360° by 10° instantaneous field-of-view. Mass per charge is dispersed radially on an annular microchannel plate detector and the azimuthal position on the detector is a map of the instantaneous 360° field of view. With the rotation of the spacecraft, the TIMAS sweeps out very nearly a 4π solid angle image in a half spin period. The energy per charge range from 15 eV e−1 to 32 keV e−1 is covered in 28 non-contiguous steps spaced approximately logarithmically with adjacent steps separated by about 30%. Each energy step is sampled for approximately 20 ms;14 step (odd or even) energy sweeps are completed 16 times per spin. In order to handle the large volume of data within the telemetry limitations the distributions are compressed to varying degrees in angle and energy, log-count compressed and then further compressed by a lossless technique. This data processing task is supported by two SA3300 microprocessors. The voltages (up to 5 kV) for the tandem toroidal electrostatic analyzers and preacceleration sections are supplied from fixed high voltage supplies using optically controlled series-shunt regulators.

D/H and 18O/16O ratio in the hydronium ion and in neutral water from in situ ion measurements in comet Halley

The D/H ratio and the 18O/16O ratio in hydronium ions in the gas coma of comet Halley have been determined from ion data obtained by the high intensity sensor (HIS) of the ion mass spectrometer (IMS) on board the spacecraft Giotto in 1986. The HIS instrument measured reliable data for the water group ions over a large distance range from the nucleus. We could therefore minimize the statistical errors. This large range also allowed us to study the systematic influence of formaldehyde on the D/H ratio in the hydronium ion and to deduce from the hydronium ion a D/H ratio for the water molecule. The measured 18O/16O ratio of (1.93±0.12) × 10−3 is compatible with the telluric value of 2.06 × 10−3. The D/H ratio for the hydronium ion measured is D/H = 3.08−0.53+0.38 × 10−4. We show that since the water chemistry is not significantly different for deuterated and nondeuterated water molecules and ions and since the contribution from other deuterated molecules to the deuterium abundance in the hydronium ion is small, the D/H value of the neutral water molecule is not significantly different from the value determined for the ion, although the uncertainty is somewhat larger. An upper limit for the deuterium abundance in formaldehyde in comet Halley can be derived from the D/H ratio in the hydronium ion as a function of distance from the nucleus. From our results we conclude that the D/H ratio in formaldehyde is certainly smaller than 2% and probably smaller than 0.5% and that the enrichment of the deuterium in the hydronium ion due to formaldehyde is lower than 5%. The D/H ratio in water in comet Halley is therefore significantly higher than the telluric sea water value, whereas the deuterium enrichment in formaldehyde is not as high as, for example, that observed in the Orion compact ridge.

Dynamics of Magnetospheric Ion Composition as Observed by the GEOS Mass Spectrometer

After one year of operation the GEOS-1 Ion Composition Experiment has surveyed plasma composition at all local times in the L range 3~8 and the energy per charge range from thermal to 16 keV/e. From measurements made in the keV range during eleven magnetic storms we find that the percentage of heavy (M/Q > 1) ions present in the outer magnetosphere increases by a factor of 3 to 10 during disturbances. We conclude that two independent sources (solar wind, characterized by 4He2+, and ionosphere, characterized by O+) give on the average comparable contributions to injected populations, although in a single event one or the other source may dominate. However, in magnetically quiet periods protons are the dominant species with a few percent of heavy ions. With the help of special satellite manoeuvres magnetic field aligned fluxes of ≈0.05–3 keV/e H+, He+, O+ with traces of O2+ have been observed which may be related to ion beams found previously at lower altitudes in the auroral zone. At still lower energies (~1 eV/e) the thermal plasma population is found to be made up of six ion species, three of which, D+, He2+ and O2+, were unknown in the magnetosphere prior to the GEOS-1 measurements. We present here a study of the evolution of doubly charged ions and their parent populations over four consecutive days. Various production mechanisms for doubly charged ions are discussed. We argue that ionization of singly charged ions by UV and energetic electrons and protons is the dominant process for plasmasphere production. Furthermore, the observed high concentrations of O2+ at high altitudes are a result of production in the upper ionosphere and plasmasphere combined with upward transport by thermal diffusion.

Inventory of the volatiles on comet 67P/Churyumov-Gerasimenko from Rosetta/ROSINA

The ESA Rosetta spacecraft (S/C) is tracking comet 67P/Churyumov-Gerasimenko in close vicinity. This prolonged en- counter enables studying the evolution of the volatile coma composition. Aims. Our work aims at comparing the diversity of the coma of 67P/Churyumov-Gerasimenko at large heliocentric distance to study the evolution of the comet during its passage around the Sun and at trying to classify it relative to other comets. Methods. We used the Double Focussing Mass Spectrometer (DFMS) of the ROSINA experiment on ESA’s Rosetta mission to determine relative abundances of major and minor volatile species. This study is restricted to species that have previously been detected elsewhere. Results. We detect almost all species currently known to be present in cometary coma with ROSINA DFMS. As DFMS measured the composition locally, we cannot derive a global abundance, but we compare measurements from the summer and the winter hemisphere with known abundances from other comets. Differences between relative abundances between summer and winter hemispheres are large, which points to a possible evolution of the cometary surface. This comet appears to be very rich in CO2 and ethane. Heavy oxygenated compounds such as ethylene glycol are underabundant at 3 AU, probably due to their high sublimation temperatures, but nevertheless, their presence proves that Kuiper belt comets also contain complex organic molecules.

Plasma Composition Experiment on ISEE-A

The plasma composition experiment on ISEE-A consists of a pair of high-sensitivity (~1 cm2 · sr · eV) high-resolution (M/¿M ¿ 10 at focus) energetic ion mass spectrometers. They cover the entire mass range from 1 AMU to > 150 AMU in 64 channels at each of 32 energy channels covering the energy per charge range from 0 to approximately 17 keV/e. The objectives of the experiment are to study the ion composition of the ring current, the plasma sheet, the plasmasphere, the magnetosheath, and the solar wind in order to establish the origin of the plasmas in the various regimes of the magnetosphere and to identify mass and charge dependent acceleration, transport, and loss processes.

Molecular nitrogen in comet 67P/Churyumov-Gerasimenko indicates a low formation temperature

Making comets in the cold The speciation of nitrogen compounds in comets can tell us about their history. Comets are some of the most ancient bodies in the solar system and should contain the nitrogen compounds that were abundant when they formed. Using the ROSINA mass spectrometer aboard the Rosetta spacecraft orbiting comet 67P/Churyumov-Gerasimenko, Rubin et al. found molecular nitrogen at levels that are depleted compared to those in the primordial solar system. Depletion of such a magnitude suggests that the comet formed either from the low-temperature agglomeration of pristine amorphous water ice grains or from clathrates. Science, this issue p. 232 Direct measurements of N2 by instruments aboard the Rosetta spacecraft provide clues about the comet’s long history. Molecular nitrogen (N2) is thought to have been the most abundant form of nitrogen in the protosolar nebula. It is the main N-bearing molecule in the atmospheres of Pluto and Triton and probably the main nitrogen reservoir from which the giant planets formed. Yet in comets, often considered the most primitive bodies in the solar system, N2 has not been detected. Here we report the direct in situ measurement of N2 in the Jupiter family comet 67P/Churyumov-Gerasimenko, made by the Rosetta Orbiter Spectrometer for Ion and Neutral Analysis mass spectrometer aboard the Rosetta spacecraft. A N2/CO ratio of (5.70±0.66)×10−3 (2σ standard deviation of the sampled mean) corresponds to depletion by a factor of ~25.4 ± 8.9 as compared to the protosolar value. This depletion suggests that cometary grains formed at low-temperature conditions below ~30 kelvin.

Abundant molecular oxygen in the coma of comet 67P/Churyumov-Gerasimenko

The composition of the neutral gas comas of most comets is dominated by H2O, CO and CO2, typically comprising as much as 95 per cent of the total gas density. In addition, cometary comas have been found to contain a rich array of other molecules, including sulfuric compounds and complex hydrocarbons. Molecular oxygen (O2), however, despite its detection on other icy bodies such as the moons of Jupiter and Saturn, has remained undetected in cometary comas. Here we report in situ measurement of O2 in the coma of comet 67P/Churyumov–Gerasimenko, with local abundances ranging from one per cent to ten per cent relative to H2O and with a mean value of 3.80 ± 0.85 per cent. Our observations indicate that the O2/H2O ratio is isotropic in the coma and does not change systematically with heliocentric distance. This suggests that primordial O2 was incorporated into the nucleus during the comet’s formation, which is unexpected given the low upper limits from remote sensing observations. Current Solar System formation models do not predict conditions that would allow this to occur.