H. Romero-Paredes

Radiative heat transfer analysis of a directly irradiated cavity-type solar thermochemical reactor by Monte-Carlo ray tracing

Radiative heat transfer in a 1u2009kW cavity-type solar reactor devoted to the thermal reduction of compressed ZnO and SnO2 powders is analyzed by a Monte Carlo ray tracing simulation. The developed model takes into account the radiative properties of the reactant particles and of the ceramic cavity walls, as well as the angular intensity distribution of the incoming concentrated solar irradiation. The model also includes the conduction heat losses through the lateral walls and the energy consumed by the endothermic chemical reaction. It is used to predict the temperature and the absorbed flux density profiles on the inner cavity walls for different main features of the reactor, concerning the dimensions of the cavity and the type of reactant. Results show that the absorbed flux density profile and the theoretical thermochemical efficiency change with the cavity aspect ratio and with the oxide reactant. The cavity with an aspect ratio of 3 and a SnO2 pellet undergoing dissociation presents the highest thermoc...

Monte Carlo Heat Transfer Modeling of a Particle-Cloud Solar Reactor for SnO2 Thermal Reduction

A directly irradiated cavity solar reactor devoted to the thermal reduction of SnO 2 particle-cloud is studied numerically by using the Monte Carlo method. The steady-state model solves the radiation and convection heat transfers in the semitransparent particle suspension and the chemical reaction. It was used to predict the temperature distribution and the reaction extent inside the cavity, as well as the theoretical thermochemical efficiency for different operational conditions. The simulations assume that the reactor contains a nonuniform size suspension of radiatively participating reacting SnO 2 particles. The model takes into account the radiative characteristics of the particles, as well as the directional characteristics of the power distribution of the incoming concentrated solar energy. The particle concentration, the particle size, and the length of the reactor are varied. Results show that the particle temperature and the yield of the endothermic reaction are higher when the reactor is fed with a cloud of particles with average diameter of 20 μm. The maximal thermochemical efficiency reached is 10%, which corresponds to an optimal optical thickness of around 2.

Heat and Mass Transfer during Hydrogen Generation in an Array of Fuel Bars of a BWR Using a Periodic Unit Cell

This paper presents, the numerical analysis of heat and mass transfer during hydrogen generation in an array of fuel cylinder bars, each coated with a cladding and a steam current flowing outside the cylinders. The analysis considers the fuel element without mitigation effects. The system consists of a representative periodic unit cell where the initial and boundary-value problems for heat and mass transfer were solved. In this unit cell, we considered that a fuel element is coated by a cladding with steam surrounding it as a coolant. The numerical simulations allow describing the evolution of the temperature and concentration profiles inside the nuclear reactor and could be used as a basis for hybrid upscaling simulations.

Exergy and Energy Efficiencies in High Temperature Gas Reactors (PBMR)

The aims of this work are to determine the maximum efficiency in the generation and conversion of energy to electricity, and to obtain the exergy efficiency in a pebblebBed modular reactor. The dynamics of the process of energy generation in the nuclear fuel is represented by a point reactor kinetics model, and the process of transport of this energy toward the coolant fluid was based on the conservation laws of mass, energy, and momentum. The conversion to mechanical energy in the turbo-generators, as well as the operation of the heat exchangers, was also made on the simplified models based on physical laws. The results obtained of the energy and exergy balances were applied in order to calculate the maximum efficiency considering a change in the original design and the utilization of the energy lost in the cooling process, respectively.

Modeling of the steam hydrolysis in a two-step process for hydrogen production by solar concentrated energy

In this paper the simulation of the steam hydrolysis for hydrogen production through the decomposition of cerium oxide is presented. The thermochemical cycle for hydrogen production consists of the endothermic reduction of CeO2 to lower-valence cerium oxide, at high temperature, where concentrated solar energy is used as a source of heat; and of the subsequent steam hydrolysis of the resulting cerium oxide to produce hydrogen. The modeling of endothermic reduction step was presented at the Solar Paces 2015. This work shows the modeling of the exothermic step; the hydrolysis of the cerium oxide (III) to form H2 and the corresponding initial cerium oxide made at lower temperature inside the solar reactor. For this model, three sections of the pipe where the reaction occurs were considered; the steam water inlet, the porous medium and the hydrogen outlet produced. The mathematical model describes the fluid mechanics; mass and energy transfer occurring therein inside the tungsten pipe. Thermochemical process ...

Modeling of a CeO2 thermochemistry reduction process for hydrogen production by solar concentrated energy

In this paper the simulation of the thermal reduction for hydrogen production through the decomposition of cerium oxide is presented. The thermochemical cycle for hydrogen production consists of the endothermic reduction of CeO2 at high temperature, where concentrated solar energy is used as a source of heat; and of the subsequent steam hydrolysis of the resulting cerium oxide to produce hydrogen. For the thermochemical process, a solar reactor prototype is proposed; consisting of a cubic receptacle made of graphite fiber thermally insulated. Inside the reactor a pyramidal arrangement with nine tungsten pipes is housed. The pyramidal arrangement is made respect to the focal point where the reflected energy is concentrated. The solar energy is concentrated through the solar furnace of high radiative flux. The endothermic step is the reduction of the cerium oxide to lower-valence cerium oxide, at very high temperature. The exothermic step is the hydrolysis of the cerium oxide (III) to form H2 and the corres...