Hailong Ye

A Review and Comparative Study of Existing Shrinkage Prediction Models for Portland and Non-Portland Cementitious Materials

This paper reviews shrinkage prediction models for cementitious materials and presents analysis of selected published data utilizing the aforementioned models. The main objective of this review is to revisit and reexamine the primary shrinkage mechanisms, that is, capillary pressure theory, Gibbs-Bangham shrinkage, and withdrawal of disjoining pressure in Portland and non-Portland cement. In particular, the theoretical basis for current shrinkage models is elaborated on and its soundness and applicability to explain the published experimental data are discussed. Additionally, a specific comparison was made among high water-to-cement (w/c) ratio ordinary Portland cement (OPC), low w/c OPC, and alkaline activated slag.

Effect of Drying Rate on Shrinkage of Alkali-Activated Slag Cements

The volumetric instability of alkali-activated slag (AAS) binders has raised concerns and impeded the acceptance of this Portland cement-free material. The objective of this article is to characterize the influence of drying rate on drying shrinkage behavior of AAS mortars to better understand the mechanisms responsible for its large shrinkage deformation. A series of four AAS mortar mixtures with varying activator composition, as well as a reference Portland cement mortar, was cast and dried at different relative humidities, that is, 30, 50, 70, and 85% RH. Drying took place inside nitrogen-purged environmental chambers for the purpose of eliminating the contribution of carbonation to the total volumetric change of AAS. The shrinkage and corresponding mass loss of 1.27 cm × 1.27 cm × 12.7 cm prisms were measured as a function of time. The results show that shrinkage of AAS varies largely depending on the drying rate, that is, ambient RH. Interestingly, even though the drying mass loss increases with reducing the RH, the magnitude of shrinkage is the largest for samples stored at 50 and 70% RH, depending on the mixture type. Possible causes of these irregular behaviors are discussed. It is concluded that the drying rate has a much more significant influence on AAS than on ordinary Portland cement (OPC), which implies a more complicated shrinkage mechanism for AAS samples stored at various relative humidities.