Haiyan Ni

Characterization of Gas-Phase Organics Using Proton Transfer Reaction Time-of-Flight Mass Spectrometry: Residential Coal Combustion

Residential coal combustion is a significant contributor to particulate urban air pollution in Chinese mega cities and some regions in Europe. While the particulate emission factors and the chemical characteristics of the organic and inorganic aerosol from coal combustion have been extensively studied, the chemical composition and nonmethane organic gas (NMOG) emission factors from residential coal combustion are mostly unknown. We conducted 23 individual burns in a traditional Chinese stove used for heating and cooking using five different coals with Chinese origins, characterizing the NMOG emissions using a proton transfer reaction time-of-flight mass spectrometer. The measured emission factors range from 1.5 to 14.1 g/kgcoal for bituminous coals and are below 0.1 g/kgcoal for anthracite coals. The emission factors from the bituminous coals are mostly influenced by the time until the coal is fully ignited. The emissions from the bituminous coals are dominated by aromatic and oxygenated aromatic compounds with a significant contribution of hydrocarbons. The results of this study can help to improve urban air pollution modeling in China and Eastern Europe and can be used to constrain a coal burning factor in ambient gas phase positive matrix factorization studies.

Source apportionment of carbonaceous aerosols in Xi’an, China: insights from a full year of measurements of radiocarbon and the stable isotope 13 C

Sources of organic carbon (OC) and elemental carbon (EC) in Xi’an, China, are investigated based on 1year radiocarbon and stable carbon isotope measurements. The radiocarbon results demonstrate that EC is dominated by fossil sources throughout the year, with a mean contribution of 83± 5 % (7± 2 μgm−3). The remaining 17± 5 % (1.5± 1 μgm−3) is attributed to biomass burning, with a higher contribution in the winter (∼ 24 %) compared to the summer (∼ 14 %). Stable carbon isotopes of EC (δCEC) are enriched in winter (−23.2± 0.4 ‰) and depleted in summer (−25.9± 0.5 ‰), indicating the influence of coal combustion in winter and liquid fossil fuel combustion in summer. By combining radiocarbon and stable carbon signatures, relative contributions from coal combustion and liquid fossil fuel combustion are estimated to be 45 % (median; 29 %– 58 %, interquartile range) and 31 % (18 %–46 %) in winter, respectively, whereas in other seasons more than one half of EC is from liquid fossil combustion. In contrast with EC, the contribution of non-fossil sources to OC is much larger, with an annual average of 54± 8 % (12± 10 μgm−3). Clear seasonal variations are seen in OC concentrations both from fossil and non-fossil sources, with maxima in winter and minima in summer because of unfavorable meteorological conditions coupled with enhanced fossil and non-fossil activities in winter, mainly biomass burning and domestic coal burning. δCOC exhibited similar values to δCEC, and showed strong correlations (r2 = 0.90) in summer and autumn, indicating similar source mixtures with EC. In spring, δCOC is depleted (1.1 ‰–2.4 ‰) compared to δCEC, indicating the importance of secondary formation of OC (e.g., from volatile organic compound precursors) in addition to primary sources. Modeled mass concentrations and source contributions of primary OC are compared to the measured mass and source contributions. There is strong evidence that both secondary formation and photochemical loss processes influence the final OC concentrations.