Hakan Hoşgörmez

Isotopic and molecular composition of coal-bed gas in the Amasra region (Zonguldak basin—western Black Sea)

Previous studies on the coal-bed methane potential of the Zonguldak basin have indicated that the gases are thermogenic and sourced by the coal-bearing Carboniferous units. In this earlier work, the origin of coal-bed gas was only defined according to the molecular composition of gases and to organic geochemical properties of the respective source rocks, since data on isotopic composition of gases were not available. Furthermore, in the western Black Sea region there also exist other source rocks, which may have contributed to the coal-bed gas accumulations. The aim of this study is to determine the origin of coal-bed gas and to try a gas-source rock correlation. For this purpose, the molecular and isotopic compositions of 13 headspace gases from coals and adjacent sediments of two wells in the Amasra region have been analyzed. Total organic carbon (TOC) measurements and Rock-Eval pyrolysis were performed in order to characterize the respective source rocks. Coals and sediments are bearing humic type organic matter, which have hydrogen indices (HI) of up to 300 mgHC/gTOC, indicating a certain content of liptinitic material. The stable carbon isotope ratios (δ 13 C) of the kerogen vary from -23.1 to -27.7%o. Air-free calculated gases contain hydrocarbons up to C 5 , carbon dioxide ( 98%). The stable carbon isotope ratios of methane, ethane and propane are defined as δ 13 C 1 : -51.1 to -48.3‰, δ 13 C 2 : -37.9 to -25.3‰, δ 13 C 3 : -26.0 to -19.2 ‰, respectively. The δD 1 values of methane range from -190 to -178‰. According to its isotopic composition, methane is a mixture, partly generated bacterially, partly thermogenic. Molecular and isotopic composition of the gases and organic geochemical properties of possible source rocks indicate that the thermogenic gas generation took place in coals and organic rich shales of the Westphalian-A Kozlu formation. The bacterial input can be related to a primary bacterial methane generation during Carboniferous and/or to a recent secondary bacterial methane generation. However, some peculiarities of respective isotope values of headspace gases can also be related to the desorption process, which took place by sampling.

Microbial Community Structure in a Serpentine-Hosted Abiotic Gas Seepage at the Chimaera Ophiolite, Turkey

ABSTRACT The surface waters at the ultramafic ophiolitic outcrop in Chimaera, Turkey, are characterized by high pH values and high metal levels due to the percolation of fluids through areas of active serpentinization. We describe the influence of the liquid chemistry, mineralogy, and H2 and CH4 levels on the bacterial community structure in a semidry, exposed, ultramafic environment. The bacterial and archaeal community structures were monitored using Illumina sequencing targeting the 16S rRNA gene. At all sampling points, four phyla, Proteobacteria, Actinobacteria, Chloroflexi, and Acidobacteria, accounted for the majority of taxa. Members of the Chloroflexi phylum dominated low-diversity sites, whereas Proteobacteria dominated high-diversity sites. Methane, nitrogen, iron, and hydrogen oxidizers were detected as well as archaea and metal-resistant bacteria. IMPORTANCE Our study is a comprehensive microbial investigation of the Chimaera ophiolite. DNA has been extracted from 16 sites in the area and has been studied from microbial and geochemical points of view. We describe a microbial community structure that is dependent on terrestrial, serpentinization-driven abiotic H2, which is poorly studied due to the rarity of these environments on Earth.

A new Carboniferous coal/shale driven gas play in the Western Black Sea Region (Turkey)

The sedimentary sequence in the Western Black Sea region of Turkey both onshore and offshore offers many possibilities for different hydrocarbon plays. This study presents a new play, which considers Carboniferous coals and shales as source beds, Cretaceous sandstones as reservoirs and Cretaceous shales and marls as seal rocks. The evaluation of this play is performed using the petroleum system approach. Results suggest that the coals and shales have a good to very good source rock potential for gas, that the Cretaceous synrift sandstones are good reservoirs. On the other hand, the sealing efficiency of respective Cretaceous units is assumed to be sufficient based on their lithological (shales and carbonaceous marls) characteristics. Stratigraphic traps, which formed by transgression and by onlap on paleohighs, were sealed and potentially available at 97 million years (ma) before present. Structural traps related to Early Cretaceous extension were also sealed around 97 ma. On the contrary, traps formed by folding and thrusting during the Alpine orogeny only formed during the last 50 ma. The timing of gas generation and migration was determined by one and two-dimensional basin modeling in one well and along a cross-section. The modeling results indicated that during the period between 90 and 42 ma, large volumes of gas were generated from the Carboniferous source rocks. Comparison with the age of stratigraphic and structural traps showed that stratigraphic and normal fault traps were potentially available for the entire volume of generated gas and that the other structural traps associated with Alpine orogeny were available only for gas generated and/or re-migrated during the last 50 ma. The evaluation of this new play results in the conclusion, that the Western Black Sea region is worthy of further exploration for conventional accumulations of thermogenic gas.