Han-Young Moon

Diffusion of Chloride Ions in Limestone Powder Concrete

In this study, the diffusion of chloride ions in cement concrete made with and without the limestone powder was investigated. In order to study the effect of the limestone powder, all mixtures were prepared at a fixed water-cementitious ratio (0.45). From the experimental results, the setting time of limestone powder concrete is faster than that of control concrete, and compressive strength of all specimens decreased with increasing replacement ratio of limestone powders. The diffusion properties of limestone powder concretes indicated a trend increasing with curing period. LSA10 and LSA20 concretes, the diffusion coefficient was smaller than that of control concrete. The addition of limestone powder reduces the diffusion coefficient of chloride ions, irrespective of fineness levels of limestone powder.

Experimental Study on the Sulfate Resistance of Concrete Blended Ground Granulated Blast-furnace Slag for Recycling

ABSTRACT Recently, ground granulated blast-furnace slag (GGBFS) has been increasingly used as additive for concrete. Many researchers reported that concrete using GGBFS had a better resistance under severe environments, such as marine or sulfate-rich soils, than Portland type cement concrete. The aim, therefore, of this study is to evaluate the effectiveness of concrete using GGBFS when the concrete exposed to sulfate-rich environment. The detailed items for experiments show 2 series consisted of sulfate immersion test with mortar and sulfate diffusion test with concrete. The sulfate immersion test was performed for 400 days and contained reduction of compressive strength, length change and XRD analysis. For sulfate diffusion test, sulfate ions diffusivity was calculated on the consideration of transference number by the diffusion cell test. As the results of this study, it was found that the concrete using GGBFS as additive was superior to portland type cement concrete. Consequently, the use of concrete with GGBFS for recycling may expect the durable and economical benefits.

Effect of Ground Granulated Blast Fumace Slag, Pulverized Fuel Ash, Silica Fume on Sulfuric Acid Corrosion Resistance of Cement Matrix

In this study, the effect of supplementary materials(GGBS, PFA, SF) on sulfuric acid corrosion resistance was assessed by measuring the compressive strength, corroded depth and weight change at 7, 28, 56, 91, 180 and 250 days of immersion in sulfuric acid solution with the pH of 0.5, 1.0, 2.0 and 3.0. Then, it was found that an increase in the duration of immersion and a decrease in the pH, as expected, resulted in a more severe corrosion irrespective of binders: increased corroded depth and weight change, and lowered the compressive strength. 60% GGBS mortar specimen was the most resistant to acid corrosion in terms of the corroded depth, weight change and compressive strength, due to the latent hydraulic characteristics and lower portion of calcium hydroxide. The order of resistance to acid was 60% GGBS>20% PFA>10% SF>OPC. In a microscopic examination, it was found that acid corrosion of cement matrix produced gypsum, as a result of decomposition of hydration products, which may loose the structure of cement matrix, thereby leading to a remarkable decrease of concrete properties.

Influence of Binder Type on the Chloride Threshold Level for Steel Corrosion in Concrete

The present study concerns the influence of binder type on the chloride-induced corrosion being accompanied by the chloride threshold level (CTL), chloride transport and as their results the corrosion-free lift. Two levels of cement content, PFA and GGBS concrete were employed. It was found that the most dominant factor to the CTL is the entrapped air void content at the steel-concrete interface, irrespective of the chloride binding capacity, binder type and acid neutralisation capacity of cement matrix. The CTL for lower interfacial air void contents was significantly increased up to by weight of cement, whereas a same mix produced for a higher level of voids. Because of a remarkable reduction in the diffusion fur GGBS concrete, its time to corrosion ranges from 255 to 1,250 days, while the corrosion-free life for control varies from 20 to 199 days sand for PFA concrete from 200 to 331 days.

Pore Size Distribution and Chloride Diffusivity of Concrete Containing Ground Granulated Blast Furnace Slag

In a hardened concrete, diffusion of oxygen, carbon dioxide, aggressive ions, and moisture from the environment to the concrete takes place through the pore network. It is well known that making dense cement matrix enhances the durability of concrete as well as all the characteristics including strength of concrete. In this paper,9 mix concretes with water to cementitious material ratio (40,45, and ) and replacement ratio of GGBFS (40 and of cement by weight) were studied on the micro-pore structure by mercury intrusion porosimetry and the accelerated chloride diffusion test by potential difference. From the results the average pore diameter and accelerated chloride diffusivity of concrete were ordered NPC > G4C > G6C. It is concluded that there is a good correlation between the average pore diameter and the chloride diffusivity, and the mineral admixtures has a filling effect, which increases the tortuosity of pore and makes large pores finer, on the pore structure of cement matrix due to the latent hydraulic reaction with hydrates of cement.

The Properties of Strength and Durability of Concrete Using Early-Strength Poly Carbonic Acid Admixture

This study reports the properties of high early strength & durability of concrete using PC admixture. To apply these data to construction site, we did the lab tests. The target of this study is to accomplish early strength of concrete (5.0 Mpa/18 hr), and we did the durability tests such as length change test, chloride ion penetration test, fleeting and thawing test, adiabatic test, etc. And we tested the porperties of concrete by the different factors, such as the type of admixtures, curing temperature, the amount of binder, etc. Through the test of concrete using the different type of admixture, PC type was more excellent than PNS type admixture. As a result, we made a concrete of high early strength concrete, and excellent durable concrete. According to these tests, we concluded that we can apply this type of PC admixture to the civil & construction site, and we can reduce the term of works and finally we will accomplish the economical construction.

Experimental Approach on Sulfate Attack Mechanism of Ordinary Portland Cement Matrix: Part I. Sodium Sulfate Attack

This paper introduces a study carried out to investigate sodium sulfate attack caused by various reactive products. Experiments were performed on mortar and paste specimens made with ordinary Portland cement (OPC) conforming to KS L 5201 Type I. The water-cement ratios were varied from 0.35 to 0.55. It was found from the laboratory study that the water-cement ratio may be a key to control the deterioration of OPC matrix during sodium sulfate attack. Furthermore, X-ray diffraction (XRD) confirmed that ettringite, gypsum and thaumasite were the main products formed by sodium sulfate attack. These findings were well supported by thermal analysis through differential scanning calorimetry (DSC), and confirmed the long-term understanding that deterioration mechanism by sodium sulfate attack is a complicated process. Most importantly, deterioration due to sodium sulfate attack is characterized as the drastic reduction in compressive strength as well as the expansion (especially in cement matrix with a higher water-cement ratio).

Sulfate Resistance of Cement Matrix Containing Limestone Powder

In order to improve the performance of concrete, generally, modern cements often incorporate several mineral admixtures. In this study, the experimental included the flow value, air content of mortar containing limestone powder and length change and compressive strength of mortar specimen immersed in sulfate solutions. From the experimental results, the limestone powder cement matrices improved the physical properties and sulfate resistance of cement matrices at replacement ratio of limestone powder. The replacement ratio of limestone powder was significantly deteriorated in sodium sulfate solution. Irrespective of fineness levels of limestone powder, length change and SDF of mortar specimens with only replacement was much superior to the other replacements.

Distribution of Calcium Hydroxide at the ITZ between Steel and Concrete

The present study examines the distribution of calcium hydroxide, unhydrated cement grain and porosity at the steel-concrete interface. The formation of calcium hydroxide has been confirmed by microscopic analysis using BSE images containing the ITZ between the steel and concrete. It was found that calcium hydroxide does not form a layer on the steel surface, different from the hypothesis that has been available in investigating the corrosion of steel in concrete, ranging from 5 to within the steel surface. Moreover, the high level of porosity at the ITZ was observed, accounting for , which may reduce the buffering capacity of cement hydration products against a local fall in the pH. These findings may imply that the mole of () :() in pore solution as chloride threshold level lead to wrong judgement or to a wide range of values.

In-Situ Application of High-Strength Antiwashout Underwater Concrete

Recently, the construction of underwater structures has been gradually increased, but underwater concrete got some problems of quality deterioration and water contamination around cast-in-situ of construction. In addition, massive underwater structures such as LNG tank, underwater concrete structures of large and continuous high- strength subterranean wall under water are being demanded lower heat of hydration. In this paper, the mechanical properties of high-strength antiwashout underwater concrete (HAWC) containing with two kinds of mineral admixtures respectively were investigated. On the basis of these results, the pH value and suspended solids of HAWC manufactured in the mock-up test were 10.011.0 and 51 mg/ at 30 minutes later, respectively, initial and final setting time were about 30,37 hours, and the slump flow was 53020Tm. In the placement at a speed of , there was no large difference in flowing velocity with or without reinforcing bar, and flowing slope was maintained at horizontal level. Compressive strength and elastic modulus of the cored specimen somewhat decreased as flowing distance was far; however, those of central area showed the highest value.