Hang Qu

Nanotechnology in Textiles

Increasing customer demand for durable and functional apparel manufactured in a sustainable manner has created an opportunity for nanomaterials to be integrated into textile substrates. Nanomoieties can induce stain repellence, wrinkle-freeness, static elimination, and electrical conductivity to fibers without compromising their comfort and flexibility. Nanomaterials also offer a wider application potential to create connected garments that can sense and respond to external stimuli via electrical, color, or physiological signals. This review discusses electronic and photonic nanotechnologies that are integrated with textiles and shows their applications in displays, sensing, and drug release within the context of performance, durability, and connectivity. Risk factors including nanotoxicity, nanomaterial release during washing, and environmental impact of nanotextiles based on life cycle assessments have been evaluated. This review also provides an analysis of nanotechnology consolidation in the textiles market to evaluate global trends and patent coverage, supplemented by case studies of commercial products. Perceived limitations of nanotechnology in the textile industry and future directions are identified.

Liquid-core low-refractive-index-contrast Bragg fiber sensor

We propose and experimentally demonstrate a low-refractive-index-contrast hollow-core Bragg fiber sensor for liquid analyte refractive index detection. The sensor operates using a resonant sensing principle- when the refractive index of a liquid analyte in the fiber core changes, the resonant confinement of the fiber guided mode will also change, leading to both the spectral shifts and intensity changes in fiber transmission. As a demonstration, we characterize the Bragg fiber sensor using a set of NaCl solutions with different concentrations. Strong spectral shifts are obtained with the sensor experimental sensitivity found to be ~1400nm/RIU (refractive index unit). Besides, using theoretical modeling we show that low-refractive-index-contrast Bragg fibers are more suitable for liquid-analyte sensing applications than their high-refractive-index-contrast counterparts.

Interferometric fiber-optic bending/nano-displacement sensor using plastic dual-core fiber

We demonstrate an interferometric fiber-optic bending/nano-displacement sensor based on a plastic dual-core fiber. The light coupled into the two fiber cores is first guided along the fiber, and then reflected by the mirror coated at the fiber end. Reflected light coming out of the fiber produces interference that shifts as the fiber bends. The interference shift is interrogated using a slit and a photodetector. The resolution of our sensor is ∼3×10(-4) m(-1) for sensing the bending curvature, and ∼70 nm for sensing the displacement.

Simultaneous monitoring the real and imaginary parts of the analyte refractive index using liquid-core photonic bandgap Bragg fibers.

We demonstrate simultaneous monitoring of the real and imaginary parts of the liquid analyte refractive index by using a hollow-core Bragg fiber. We apply this two-channel fiber sensor to monitor concentrations of various commercial cooling oils. The sensor operates using spectral monitoring of the fiber bandgap center wavelength, as well as monitoring of the fiber transmission amplitude at mid-bandgap position. The sensitivity of the fiber sensor to changes in the real part of the core refractive index is found to be 1460nm/Refractive index unit (RIU). By using spectral modality and effective medium theory, we determine the concentrations of the two commercial fluids from the measured refractive indices with an accuracy of ~0.57% for both low- and high-loss oils. Moreover, using an amplitude-based detection modality allows determination of the oil concentration with accuracy of ~1.64% for low-loss oils and ~2.81% for the high-loss oils.

Time Resolved Dynamic Measurements at THz Frequencies Using a Rotary Optical Delay Line

Fabrication, characterization, and applications of a fast rotary linear optical delay line (FRLODL) for THz time-domain spectroscopy are presented. The FRLODL features two reflective surfaces with spatially separated incoming and outgoing beams. It has been manufactured using CNC machining. A linear dependence of the optical delay on the rotation angle allows a straightforward extraction of the conversion factor between the acquisition time (in ms) and the terahertz pulse time (in ps). We also discuss the accuracy of the rotary delay line detailing the possible sources of imprecision. The FRLODL has been tested using rotation speeds of up to 48 Hz, corresponding to an acquisition rate of up to 192 Hz with four blades incorporated on the same disk. At high speeds we observe a decrease of the bandwidth due to the limitations of the electronics, in particular, the transimpedance amplifier. An error analysis is performed by experimentally evaluating the signal-to-noise ratio and the dynamic range. With regard to the applications of the FRLODL, we first present observation of the evaporation of liquids, namely water, acetone and methanol. We then demonstrate monitoring of the spray painting process. Finally, detection of fast moving objects at 1 m/s and their thickness characterization are presented.

Conductive polymer yarns for electronic textiles

In this chapter, we review the recent progress in the development of conductive polymer yarns. Particularly, we classify conductive polymer yarns into two categories: bulk-conductive polymer yarns and surface-conductive polymer yarns. For bulk-conductive yarns, we review yarns based on the intrinsically conductive polymers, yarns containing metallic filaments, and yarns filled with conductive additives. For surface-conductive yarns, we mainly focus on polymer yarns coated with conductive layers using different deposition techniques. The coating materials may consist of metals, conductive polymers, carbon nanotubes, or carbon blacks. The fabrication and processing techniques of each type of conductive polymer yarn are reviewed. Moreover, we also summarize the electrical and mechanical properties of these yarns and review the corresponding advantages and limitations.

Squeezed hollow-core photonic Bragg fiber for surface sensing applications.

We demonstrate theoretically and confirm experimentally that squeezing a section of the Bragg fiber core increases overlap between the optical fields of the core-guided modes and the modes bound to the sensing layer, which, in turn, enhances surface sensitivity of the fiber sensor.

Photonic bandgap Bragg fiber sensors for bending/displacement detection

We demonstrate an amplitude-based bending/displacement sensor that uses a plastic photonic bandgap Bragg fiber with one end coated with a silver layer. The reflection intensity of the Bragg fiber is characterized in response to different displacements (or bending curvatures). We note that the Bragg reflector of the fiber acts as an efficient mode stripper for the wavelengths near the edge of the fiber bandgap, which makes the sensor extremely sensitive to bending or displacements at these wavelengths. Besides, by comparison of the Bragg fiber sensor to a sensor based on a standard multimode fiber with similar outer diameter and length, we find that the Bragg fiber sensor is more sensitive to bending due to the presence of a mode stripper in the form of a multilayer reflector. Experimental results show that the minimum detection limit of the Bragg fiber sensor can be as small as 3 μm for displacement sensing.

Piezoelectric Microstructured Fibers via Drawing of Multimaterial Preforms

We demonstrate planar laminated piezoelectric generators and piezoelectric microstructured fibers based on BaTiO3-polyvinylidene and carbon-loaded-polyethylene materials combinations. The laminated piezoelectric generators were assembled by sandwiching the electrospun BaTiO3-polyvinylidene mat between two carbon-loaded-polyethylene films. The piezoelectric microstructured fiber was fabricated via drawing of the multilayer fiber preform, and features a swissroll geometry that have ~10 alternating piezoelectric and conductive layers. Both piezoelectric generators have excellent mechanical durability, and could retain their piezoelectric performance after 3 day’s cyclic bend-release tests. Compared to the laminated generators, the piezoelectric fibers are advantageous as they could be directly woven into large-area commercial fabrics. Potential applications of the proposed piezoelectric fibers include micro-power-generation and remote sensing in wearable, automotive and aerospace industries.

Design of the Curvilinear Reflectors for Linear Rotary Optical Delay Lines

We present design principles for the linear optical delay lines based on rotating curvilinear reflectors. An optical rotary delay line with a composite rotating blade having two reflector surfaces is then fabricated using CNC machining.