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Journal of Applied Electrochemistry | 2014

Micro/nano-structured SnS2 negative electrodes using chitosan derivatives as water-soluble binders for Li-ion batteries

Haoxiang Zhong; Peng Zhou; Lu Yue; Daoping Tang; Lingzhi Zhang

Micro/nano-structured SnS2 was prepared by a hydrothermal method using biomolecular l-cysteine and SnCl4·5H2O as sulfur source and tin source, respectively. The electrochemical performances of SnS2 electrodes were investigated using water-soluble binders of carboxymethyl chitosan (C-chitosan) and chitosan lactate, and compared with the conventional water-soluble sodium carboxymethyl cellulose (CMC) and non-aqueous polyvinylidene difluoride (PVDF). SnS2 electrode using the water-soluble binders (C-chitosan, chitosan lactate, and CMC) showed higher initial coulombic efficiency, larger reversible capacity, and better rate capabilities than that of PVDF. In addition, SnS2 electrode using C-chitosan binder exhibited somewhat worse cycling stability, but better rate capability at a high rate of 5C than CMC.


RSC Advances | 2016

Facile synthesis of nanostructured Li4Ti5O12/PEDOT:PSS composite as anode material for lithium-ion batteries

Yan Liu; Daoping Tang; Haoxiang Zhong; Qianyu Zhang; Jianwen Yang; Lingzhi Zhang

A poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) coated Li4Ti5O12 (LTO/PP) composite is synthesized by a facile and convenient approach, which involves dispersing LTO in an aqueous solution of PEDOT:PSS, followed by rotary evaporation accompanied by an ultrasonic procedure. After the coating process, LTO is covered by a homogeneous PEDOT:PSS layer, which effectively improves the electrical conductivity and processing capability of LTO to form a more homogeneous electrode sheet, and thus impart more favorable electrochemical kinetics as compared with the pristine LTO electrode. The LTO/PP electrode exhibits better reversible capacity and rate capability compared with the LTO electrode, delivering a reversible capacity of 177.2 mA h g−1 at 0.1C and reaching a capacity of 169.1 mA h g−1 with a capacity retention of 97.8% after 100 cycles at 0.5C. At the rate of 10C, the LTO/PP electrode delivers a capacity as high as 161.1 mA h g−1 (91.0% of the value achieved at 0.1C), as compared to 144.5 mA h g−1 for the pristine LTO electrode.


Journal of Power Sources | 2014

Carboxymethyl chitosan: A new water soluble binder for Si anode of Li-ion batteries

Lu Yue; Lingzhi Zhang; Haoxiang Zhong


Electrochimica Acta | 2012

Enhanced reversible lithium storage in a nano-Si/MWCNT free-standing paper electrode prepared by a simple filtration and post sintering process

Lu Yue; Haoxiang Zhong; Lingzhi Zhang


Electrochimica Acta | 2014

Investigation on Carboxymethyl Chitosan as New Water Soluble Binder for LiFePO4 Cathode in Li-Ion Batteries

Minghao Sun; Haoxiang Zhong; Shuren Jiao; Hanqi Shao; Lingzhi Zhang


Electrochimica Acta | 2015

Cyanoethylated Carboxymethyl Chitosan as Water Soluble Binder with Enhanced Adhesion Capability and electrochemical performances for LiFePO4 Cathode

Jiarong He; J.Q. Wang; Haoxiang Zhong; Jianning Ding; Lingzhi Zhang


ChemElectroChem | 2014

Water-Soluble Conductive Composite Binder Containing PEDOT:PSS as Conduction Promoting Agent for Si Anode of Lithium-Ion Batteries

Dan Shao; Haoxiang Zhong; Lingzhi Zhang


Journal of Solid State Electrochemistry | 2013

Porous Si coated with S-doped carbon as anode material for lithium ion batteries

Lu Yue; Haoxiang Zhong; Daoping Tang; Lingzhi Zhang


Journal of Power Sources | 2016

Carboxymethyl chitosan/conducting polymer as water-soluble composite binder for LiFePO4 cathode in lithium ion batteries

Haoxiang Zhong; Aiqin He; Jidian Lu; Minghao Sun; Jiarong He; Lingzhi Zhang


Journal of Solid State Electrochemistry | 2016

The polyacrylic latex: an efficient water-soluble binder for LiNi1/3Co1/3Mn1/3O2 cathode in li-ion batteries

Haoxiang Zhong; Minghao Sun; Yong Li; Jiarong He; Jianwen Yang; Lingzhi Zhang

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