Haoxin Li

Investigation on the potential of waste cooking oil as a grinding aid in Portland cement

Although there are several methods for managing waste cooking oil (WCO), a significant result has not been achieved in China. A new method is required for safe WCO management that minimizes the environmental threat. In this context, this work was developed in which cement clinker and gypsum were interground with various WCOs, and their properties, such as grindability, water-cement ratio required to achieve a normal consistency, setting times, compressive strength, contents of calcium hydroxide and ettringite in the hardened paste, microstructure and economic and environmental considerations, were addressed in detail. The results show that, overall, WCO favorably improves cement grinding. WCO prolonged the cement setting times and resulted in longer setting times. Additionally, more remarkable effects were found in cements in which WCO contained more unsaturated fatty acid. WCOs increased the cement strength. However, this enhancement was rated with respect to the WCO contents and components. WCOs decreased the CH and AFt contents in the cement hardened paste. Even the AFt content at later ages was reduced when WCO was used. WCO also densify microstructure of the hardened cement paste. It is economically and environmentally feasible to use WCOs as grinding aids in the cement grinding process. These results contribute to the application of WCOs as grinding aids and to the safe management of WCO.

Recent Advances in Intrinsic Self-Healing Cementitious Materials

Self-healing is a natural phenomenon whereby living organisms respond to damage. Recently, considerable research efforts have been invested in self-healing cementitious materials that are capable of restoring structural integrity and mechanical properties after being damaged. Inspired by nature, a variety of creative approaches are explored here based on the intrinsic or extrinsic healing mechanism. Research on new intrinsic self-healing cementitious materials with biomimetic features is on the forefront of material science, which provides a promising way to construct resilient and sustainable concrete infrastructures. Here, the current advances in the development of the intrinsic healing cementitious materials are described, and a new definition of intrinsic self-healing discussed. The methods to assess the efficiency of different healing mechanisms are briefly summarized. The critical insights are emphasized to guide the future research on the development of new self-healing cementitious materials.

Silicon carbide waste as a source of mixture materials for cement mortar

This paper presents an investigation of the feasibility of recycling silicon carbide waste (SCW) as a source of mixture materials in the production of cement mortar. Mortars with SCW were prepared by replacing different amounts of cement with SCW, and the properties of the resulting mortars, such as the fluidity, strength and shrinkage, were studied in this work. Thermogravimetry-differential scanning calorimetry and scanning electron microscopy were employed to understand the reasons for the property changes of the mortars. The results indicate that SCW decreases the initial and 1-h fluidity of fresh mortar but improves the loss of fluidity. The mortar with SCWexhibits a lower strength at 3 d and 7 d but a higher strength at 28 d and 56 d compared to the control. The shrinkage rate of cement mortar with SCW shows an obvious decrease as the replacement ratio increases. In addition, the content of calcium hydroxide in hardened paste also shows that SCW has some impact on the hydration of the cement-SCW system. The microstructures of the hardened paste also show evidence for a later strength change of mortar containing SCW. This work provides a strategic reference for possibly applying SCW as a mixture material in the production of cement mortar.

Stochastic micromechanical predictions for the effective properties of concrete considering the interfacial transition zone effects

A stochastic micromechanical framework for predicting the concrete probabilistic behavior is proposed considering the interfacial transition zone effects in this paper. The volume fraction of the interfacial transition zone is analytically calculated based on the aggregate grading. Multilevel homogenization schemes based on the direct interaction micromechanical solutions are presented to predict the concrete effective properties considering the aggregate and interfacial transition zone effects. By modeling the volume fractions and properties of the constituents as stochastic, we extend the deterministic framework to stochastic to incorporate the inherent randomness of effective properties among different concrete specimens. With the moments of the effective properties, the probability density function is approximated using the exponential polynomial for concrete material. Numerical examples including limited experimental validations, comparisons with existing micromechanical models, commonly used probability density functions, and the direct Monte Carlo simulations indicate that the proposed models provide an accurate and computationally efficient framework in characterizing the material’s effective properties. Finally, the effects of the randomness of interfacial transition zone and aggregate on the materials’ macroscopic probabilistic behaviors are investigated based on our proposed stochastic micromechanical framework.

Migration and transformation of sulfur in the municipal sewage sludge during disposal in cement kiln

The aim of this work was to investigate the migration and transformation of sulfur in the municipal sewage sludge during disposal in cement kiln, and better understand the emission of the sulfur related pollutants in this process. In consideration of the temperature conditions in the practical operation, municipal sewage sludge was pre-dried at 105 °C, and then dried at 210, 260 and 310 °C, co-combusted with cement raw mill at 800, 900 and 1000 °C, and 1350, 1400 and 1450 °C respectively in the laboratory. X-ray photoelectron spectroscopy (XPS) was used to determine the S2p spectral lines of the municipal sewage sludge treated in the different process. Besides, The Thermal Analysis-Thermogravimetry (DTA-TG), Back Scattered Electron (BSE) and Energy Dispersive Spectrometer (EDS) were also employed to explore the mechanism of sulfur subsistence at 1450 °C. The results indicate that sulfide, thiophene, sulfone and sulfate are mainly sulfur compound in the municipal sewage sludge dried at 105 °C. Sulfoxide, a new sulfur compound, appears after it is further dried at 210 °C. The relative contents of sulfide and thiophene are continuously declined as the drying temperature increases due to their evaporation, decomposition and transformation in this process. The transformation of sulfide and thiophene makes the relative contents of sulfoxide and sulfate accordingly increased. However, the relative content of sulfone experiences an elevating-lowering process while the dry temperature elevated from 210 to 310 °C. This case is related to its evaporation and decomposition, as well as its production for the transformation of sulfide and thiophene. In the co-combustion process, sulfide, thiophene and sulfone are entirely vanished for their evaporation, decomposition and transformation. Sulfone is still contained at 800 °C, but when the temperature unceasingly rises, it is completely decomposed or evaporated and sulfate is the only sulfur compound. The microstructures left by the gas release are also observed in the mixtures sintered at 1450 °C, however sulfate still exists even at 1450 °C. The BSE and EDS results show that the melt phase is the important contribution to the appearance of sulfate at the high temperature. These results will sever as a theoretically reference for the pollution control of the sulfur related pollutants in the disposal process of the municipal sewage sludge in cement kiln.

Effect of Waste Paper Fiber on Properties of Cement-based Mortar and Relative Mechanism

The aim of this work was to investigate the effect of waste paper fiber on the properties of cement-based mortar and the relative mechanism. The cement-based mortars with various contents and mixing way of waste paper fibers were prepared and the slump flow, setting time and strength developments of all mortars were tested. Besides, Ca(OH)2 content in hardened pastes at different ages and the microstructures of all mortar at 90d were observed by scanning electron microscopy. The experimental results showed that in the process of mixing, more superplastizier was consumed to maintain the workability because of the absorption of water and superplastizer on waste paper fiber. With more waste paper fiber being added, longer setting time is available for the pastes with it because of the carbohydrate dissolving and its retarding to the cement hydration. Waste paper fiber is adverse to the early and later strength of cement-based mortar, but it increases the mortar strengths at 7 and 28 d. The strength, Ca(OH)2 content and microstructure are related to the content and mixing way of waste paper fiber. Waste paper fiber helps produce the Ca(OH)2 at 7 and 28 d, but this case is reverse at ages of 1 and 3 d. Overall, waste paper fiber leads to the appearance of more pores in the hardened paste. However, it increases the toughness of cement-based mortar.

A multiphase micromechanical model for unsaturated concrete repaired by electrochemical deposition method with the bonding effects

Most concrete structures repaired by the electrochemical deposition method are not fully saturated and the healing interfaces are not always perfect in reality. To demonstrate these issues, micromechanical models are presented for unsaturated concrete repaired by electrochemical deposition method with the healing interfacial transition zone based on our latest work. The repaired unsaturated concrete is represented as a multiphase composite made up of the water, unsaturated pores, intrinsic concrete, deposition products and the healing interfacial transition zone between the latter two components. The equivalent particle, matrix and composite for repaired unsaturated concrete are obtained by modifying the differential-scheme and the generalized self-consistent method. Modifications are utilized to rationalize the differential-scheme based estimations by taking into the water (including further hydration and viscosity effects), interfacial transition zone and the shapes of the pores into considerations. Furthermore, our predictions are compared with those of the existing models and available experimental results, thus illustrating the feasibility and capability of the proposed micromechanical framework.

A Stochastic Micromechanical Framework for Saturated Concrete Repaired by Electrochemical Deposition Method

A stochastic micromechanical framework is presented to predict the probabilistic behavior of saturated concrete repaired by the electrochemical deposition method (EDM). The repaired concrete is represented as a multiphase composite composed of the intrinsic concrete, water and deposition products. Multi-level homogenization schemes are presented to predict the properties of the repaired concrete. The equivalent inclusion is reached by homogenization of the two-phase composite composed of the deposition products and the water. The equivalent composite of the repaired concrete is attained by the homogenization of the two-phase composited made up of the equivalent inclusion and the intrinsic concrete. By modeling the volume fractions and the properties of constituents as stochastic, the deterministic framework is extended to stochastic to incorporate the inherent randomness of the effective properties among the different specimens. Through the Monte Carlo simulations, the probabilistic behaviors are obtained, such as the mean, the different order moments and the probability density functions. Numerical examples including deterministic and stochastic micromechanical validations indicate that the proposed models are capable of providing an accurate framework in characterizing the effective properties of the concrete repaired by the EDM.

Recycling red mud from the production of aluminium as a red cement-based mortar

Current management for red mud is insufficient and a new method is needed. A series of experiments have been carried out to develop a new approach for effective management of red mud. Mortars without or with 3%, 6% and 9% red mud were prepared and their fresh and hardened properties were measured to access the possibility of recycling the red mud in the production of red cement-based mortar. The mechanisms corresponding to their mechanical performance variations were explored by X-ray powder diffraction and scanning electron microscopy. The results show that the fresh mortars with red mud present an increase of viscosity as compared with the control. However, little difference is found when the content of red mud is altered. It also can be seen that red mud increases flow time and reduces the slump flow of the mortar. Meanwhile, it is found that mortar with red mud is provided with higher air content. Red mud is eligible to adjust the decorative mortar colour. Compressive strength of mortar is improved when less than 6% red mud is added. However, overall it has a slightly negative effect on tensile bond strength. It decreases the Ca(OH)2 content and densifies the microstructure of hardened paste. The heavy metal concentrations in leachates of mortars with red mud are much lower than the values required in the standard, and it will not do harm to people’s health and the environment. These results are important to recycle and effectively manage red mud via the production of red cement-based mortar.

Properties of bamboo charcoal and cement-based composite materials and their microstructure

The objective of this work was to study the properties of bamboo charcoal and cement-based composite materials and their microstructure. The pastes with various bamboo charcoals were prepared and the relative properties such as setting times and strength were tested and the microstructures and pore characteristics of pastes with various bamboos were also studied. The experimental results indicated that bamboo charcoal affects the setting times of cement paste, but the introduction of water reducer relieves this condition. Bamboo charcoal also poses an impact on the hardened paste strength. The prominent strength decrease is found when more and larger size bamboo charcoal is mixed into the cement paste. Bamboo charcoal alters the paste microstructure and increases the porosity and pore volume, but it increases the pores with the diameter of less than 50 μm. The pastes with various bamboo charcoals are given with the good functions such as adjusting humidity and adsorption.