Hatice Dinçer
Istanbul Technical University
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Featured researches published by Hatice Dinçer.
Journal of Porphyrins and Phthalocyanines | 2004
Hatice Dinçer; Ahmet Gül; Makbule Burkut Koçak
A new route to the synthesis of 4-chloro-5-alkyl-phthalonitrile derivatives was shown by the displacement reaction of 4,5-dichloro-phthalonitrile and diethylmalonate, a CH-acidic precursor, in the presence of K2CO3. Cyclotetramerization of 1-chloro-3,4-dicyano-6-(1,1-dicarbethoxy-methyl)benzene and the metal salt without any solvent gave the corresponding metallophthalocyanines (M = Co, CuorPd). Transesterification occurred when the reaction was carried out in hexanol in the presence of DBU to obtain the metal-free derivative. Treatment of 1-chloro-3,4-dicyano-6-(1,1-dicarbethoxy-methyl)benzene with sodium ethoxide at ambient temperature and further acidification resulted in 2,9,16,23-tetra(carboxymethyl)-3,10,17,24-tetrachloro-phthalocyaninatopalladium(II) with partial decarboxylation. Its electronic spectrum in aqueous solution indicated no appreciable change over a pH range from 7 to 12.
Russian Journal of Electrochemistry | 2006
Atıf Koca; Hatice Dinçer; Makbule Burkut Koçak; Ahmet Gül
In this study, electrochemical behaviors of Co(II) and Pd(II) phthalocyanines carrying tetrakisdiethoxymalonyl and Pd(II) phthalocyanine carrying tetrakiscarboxymethyl substituents at the peripheral positions are investigated by cyclic voltammetry and applied potential chronocoulometry techniques. Cyclic voltammetric studies show that, while Pd(II) phthalocyanines carrying diethoxymalonyl and carboxymethyl substituents give up to three common phthalocyanine ring reductions, Co(II) phthalocyanine carrying diethoxymalonyl substituents gives a metal-centered oxidation and a metal-centered reduction and three ligand-centered reduction and a ligand-centered oxidation processes. First reduction processes of both the PdPc complexes have shoulders. This different voltammetric behaviors of Pd(II) phthalocyanines carrying carboxymethyl and diethoxymalonyl substituents results from interaction of this distinctive substituents with the phthalocyanine ring π electron system and interaction with the different solvent systems. Observation of the splitting of the first reduction process of Pd(II) phthalocyanines carrying diethoxymalonyl and carboxymethyl substituents suggests the aggregation of the complex. Very small diffusion coefficient of the complexes with respect to Co(II) phthalocyanine also confirms the existence of the aggregation of the complex during the electrochemical studies. Effects of the substituents and the solvent media are clearly observed from the differences of the voltammograms of Pd(II) phthalocyanines carrying diethoxymalonyl and carboxymethyl substituents in DMSO and THF solvent media, respectively.
Journal of Coordination Chemistry | 2012
Şerıfe Bayar; Hatice Dinçer; Ahmet Lütfi Uğur
Synthesis and characterization of zinc and cobalt phthalocyanines substituted with biphenylmethylpropionic acids, methyl-o-tolylpropionic acids, and methyl-p-tolylpropionic acids are described in this study. The new compounds have been characterized by elemental analyses, FT-IR, UV-Vis, MALDI-TOF, and 1H NMR spectroscopy. All new compounds are soluble in THF, DMF, DMSO, and dilute sodium hydroxide solution. The influence of the carboxylic acid and bulky biphenyl, ortho-methylbenzyl and para-methylbenzyl groups on the spectroscopic properties has been investigated. UV-Vis experiments suggest that the tendency of phthalocyanines to aggregate in polar solvents is significantly reduced owing to the carboxylic acid groups and bulky peripheral substituents.
Journal of Porphyrins and Phthalocyanines | 2008
Ergün Gonca; Ümmü Gülsüm Baklacı; Hatice Dinçer
Magnesium porphyrazinates substituted with eight (p-tolyl) and (o-tolyl) units on the peripheral positions have been synthesized for the first time by cyclotetramerization of 1,2-bis(p-tolyl)maleonitrile and 1,2-bis(o-tolyl)maleonitrile in the presence of magnesium butanolate. Their demetalation by the treatment with trifluoroacetic acid resulted in partially oxidized products, namely, octakis(p-tolyl)-2-seco-porphyrazine-2,3-dione and octakis(o-tolyl)-2-seco-porphyrazine-2,3-dione. Further reactions of these products with copper(II) acetate, zinc(II) acetate and cobalt(II) acetate have led to the metallo derivatives, [octakis(p-tolyl)-2-seco-2,3-dioxoporphyrazinato]M(II) and [octakis(o-tolyl)-2-seco-2,3-dioxoporphyrazinato]M(II) (M = Cu, Zn, Co). These novel compounds have been characterized by elemental analysis, together with FT-IR, 1H NMR, UV-vis and mass spectral data.
Journal of Porphyrins and Phthalocyanines | 2009
Atıf Koca; Hatice Dinçer; Ergün Gonca; Ahmet Gül
In this work, voltammetric, spectroelectrochemical, and electrocatalytic properties of the metallophthalocyanines bearing four chloro and four biphenyl-malonic ester bulky groups were investigated. Voltammetric and spectroelectrochemical measurements of the metallophthalocyanines show that while cobalt phthalocyanine presents both metal-based and ring-based redox processes, all other complexes give only ring-based reduction and oxidation processes. The redox processes have generally diffusion-controlled, reversible and one-electron transferred mechanisms. Cobalt phthalocyanine electrocoated easily on the glassy carbon working electrode during the repeating cycles, a very useful feature for application in fabrication of thin films. Electrocatalytic activity of cobalt phthalocyanine to hydrogen evolution reaction was studied in solution titrated with perchloric acid and on glassy carbon electrode modified with cobalt phthalocyanine in aqueous solution. Electrocatalytic measurements show that cobalt phthaloc...
Journal of Coordination Chemistry | 2015
Saida Kaipova; Hatice Dinçer; Ahmet Altındal
The tert-butylsulfanylphthalonitrile has been prepared with optimized synthetic procedure. Metal free (H2Pc) and metallo phthalocyanines (Pcs) (ZnPc, CoPc, CuPc, PbPc) have been synthesized by cyclotetramerization of tert-butylsulfanylphthalonitrile in the presence of DBU and metal salts. Thus, tert-butylsulfanyl groups enhance the solubility, shift the Q band absorption to the red visible region, and inhibit efficient cofacial interaction of the Pcs (2–6) as evaluated by UV–vis spectra. The electrical conduction and dielectric properties of the synthesized Pc thin films sandwiched between indium tin oxide and aluminum electrodes (ITO–Pc–Al) were investigated from 300 to 500 K. At low bias voltage the conduction is ohmic while at high bias voltage the conduction becomes space charge limited with an exponential distribution of traps. The measured ac conductivity data are discussed in terms of classical models based on pair approximation. It was found that the ac conductivity obeys the power law given by σac = σ0ωs, in which the frequency exponent s decreases with temperature. The real and imaginary parts of the impedance are found to be dependent on both frequency and temperature.
Electrochimica Acta | 2006
Atıf Koca; Hatice Dinçer; Hatice Çerlek; Ahmet Gül; Makbule Burkut Koçak
Dyes and Pigments | 2008
Hatice Dinçer; Atıf Koca; Ahmet Gül; M. Burkut Koçak
Electrochimica Acta | 2009
Atıf Koca; Şerife Bayar; Hatice Dinçer; Ergün Gonca
Dyes and Pigments | 2013
Hatice Dinçer; Humeyra Mert; Betül Nur Şen; Aydan Dag; Sinem Bayraktar