Héctor O. Di Rocco

A New Method for Determination of Self-Absorption Coefficients of Emission Lines in Laser-Induced Breakdown Spectroscopy Experiments

In this paper we present a new method for determining the self-absorption coefficients of emission lines in laser-induced breakdown spectroscopy (LIBS) experiments. With respect to other methods already present in the literature, the proposed approach has the advantage of not requiring, providing some conditions are fulfilled, any knowledge of the plasma parameters such as temperature and electron number density and of the emission line spectral coefficients such as transition probability. An example of the application of the approach is given for emission lines measured at different delay times after laser ablation of a silver target.

The Calculation of the Optical Depths of Homogeneous Plasmas: Analytical, Experimental, and Numerical Considerations

Starting from the general expressions describing the line emission by a homogeneous plasma in local thermal equilibrium (LTE), in the approximation of Lorentzian shape of the line profile, a universal expression can be obtained relating the optical depth of the line to measurable quantities such as integrated line intensity, peak value, and full width at half-maximum (FWHM). This universal curve could be used for calculating the optical depth from experimental spectra without knowledge of the spectroscopic parameters of the emission line. Examples are given using experimental and computer-generated synthetic spectra.