Helge Meggers

Temperature:δ18O relationships of planktonic foraminifera collected from surface waters

Abstract Most of the isotopic paleotemperature equations used for paleoceanographic reconstructions have been derived from culture experiments or inorganic precipitates of calcium carbonate. To test these equations in the modern ocean, we measured the oxygen isotope composition of planktonic foraminifera (Globigerinoides ruber, Globigerinoides sacculifer, Globigerina bulloides and Neogloboquadrina pachyderma) collected from Atlantic and Southern Ocean surface waters, and added published plankton tow data from the Pacific, Indian and Arctic Oceans. The resulting species-specific regression equations of the temperature:δ18O relationships for G. ruber, G. sacculifer and G. bulloides are statistically indistinguishable. The equations derived for G. sacculifer and G. bulloides agree with relationships obtained from laboratory experiments, in which these species were cultured at pH values close to modern surface waters. The equation derived from N. pachyderma has a significantly lower slope and offset than the other three species but produces a regression equation that is nearly identical to the one for the epifaunal benthic foraminifer Cibicides sp. Our work on plankton tow and pumped samples indicates that culture-derived equations appear to be more appropriate for predicting the absolute δ18O of the species examined compared to equations derived from inorganic precipitates. However, over the oceanic temperature range, the slopes of the equations we derive for living species agree with the slopes obtained from inorganic precipitates.

Orbital forcing of dust supply to the North Canary Basin over the last 250kyr

Abstract The Canary Basin lies in a region of strong interaction between the atmospheric and ocean circulation systems: Trade winds drive seasonal coastal upwelling and dust storm outbreaks from the neighbouring Sahara desert are the major source of terrigenous sediment. To investigate the forcing mechanisms for dust input and wind strength in the North Canary Basin, the temporal pattern of variability of sedimentological and geochemical proxy records has been analysed in two sediment cores between latitudes 30°30′N and 31°40′N. Spectral analysis of the dust proxy records indicates that insolation changes related to eccentricity and precession are the main periods of temporal variation in the record. Si/Al and grain-size of the terrigenous fraction show an increase in glacial–interglacial transitions while Al concentration and Fe/Al ratio are both in phase with minima in the precessional index. Hence, the results obtained show that the wind strength was intensified at Terminations. At times of maxima of Northern Hemisphere seasonal insolation, when the African monsoon was enhanced, the North Canary Basin also received higher dust input. This result suggests that the moisture brought by the monsoon may have increased the availability of dust in the source region.

An evaluation of 14C age relationships between co‐occurring foraminifera, alkenones, and total organic carbon in continental margin sediments

[ 1] Radiocarbon age relationships between co- occurring planktic foraminifera, alkenones, and total organic carbon in sediments from the continental margins of southern Chile, northwest Africa, and the South China Sea were compared with published results from the Namibian margin. Age relationships between the sediment components are site- specific and relatively constant over time. Similar to the Namibian slope, where alkenones have been reported to be 1000 - 4500 years older than co- occurring foraminifera, alkenones were significantly ( similar to 1000 years) older than co- occurring foraminifera in the Chilean margin sediments. In contrast, alkenones and foraminifera were of similar age ( within 2 sigma error or better) in the NW African and South China Sea sediments. Total organic matter and alkenone ages were similar off Namibia ( age difference TOC alkenones: 200 - 700 years), Chile ( 100 - 450 years), and NW Africa ( 360 - 770 years), suggesting minor contributions of preaged terrigenous material. In the South China Sea, total organic carbon is significantly ( 2000 - 3000 years) older owing to greater inputs of preaged terrigenous material. Age offsets between alkenones and planktic foraminifera are attributed to lateral advection of organic matter. Physical characteristics of the depositional setting, such as seafloor morphology, shelf width, and sediment composition, may control the age of co- occurring sediment components. In particular, offsets between alkenones and foraminifera appear to be greatest in deposition centers in morphologic depressions. Aging of organic matter is promoted by transport. Age offsets are correlated with organic richness, suggesting that formation of organic aggregates is a key process.

Carbonate Dissolution in the Deep-Sea: Methods, Quantification and Paleoceanographic Application

Understanding spatial and temporal changes in oceanic carbonate dissolution and preservation patterns is of key importance for testing models which seek to explain past changes in atmospheric pCO2 and surface water PCO2 through changes in the global carbon cycle. As part of the South Atlantic Dissolution Experiment, three deep-sea transects covering areas above and below the calcite lysocline into the Brazil and through the Cape Basin were investigated. Our work includes (1) determination of sediment surface assemblages of coccolithophores and planktic foraminifera; (2) SEM ultrastructure analysis of the planktic foraminifera Globigerina bulloides; and (3) comparative assessment of different carbonate dissolution proxies. We find that all dissolution proxies are able to distinguish the area above the calcite lysocline from the area below. Moreover, some parameters are qualified to distinguish the upper continental margin of upwelling areas from the open ocean. Regarding three different oceanographic regimes, only the carbonate ion content and the percentage of sediment carbonate content put us in the position to determine the total scale of the calcite transition zone. If these parameters are not available, a combination of the Globigerina bulloides Dissolution Index, the Calcidiscus leptoporus — Emiliania huxleyi Dissolution Index, and the rain ratio give the best approach to the authentic conditions.

Influence of lateral particle advection and organic matter degradation on sediment accumulation and stable nitrogen isotope ratios along a productivity gradient in the Canary Islands region

Abstract We compare total and biogenic particle fluxes and stable nitrogen isotope ratios (δ15N) at three mooring sites along a productivity gradient in the Canary Islands region with surface sediment accumulation rates and sedimentary δ15N. Higher particle fluxes and sediment accumulation rates, and lower δ15N were observed in the upwelling influenced eastern boundary region (EBC) compared to the oligotrophic sites north of Gran Canaria [European Station for Time-Series in the Ocean, Canary Islands (ESTOC]] and north of La Palma (LP). The impact of organic matter degradation and lateral particle advection on sediment accumulation was quantified with respect to the multi-year flux record at the ESTOC. Remineralisation of organic matter in the water column and at the sediment surface resulted in an organic carbon preservation of about 0.8% and total nitrogen preservation of about 0.4% of the estimated export production. Higher total and carbonate fluxes and accumulation rates in the lower traps and surface sediment compared to the upper traps indicated that at least 50% of the particulate matter at the ESTOC was derived from allochthonous sources. Low δ15N values in the lower traps of the ESTOC and LP point to a source region influenced by coastal upwelling. We conclude from this study that the reconstruction of export production or nutrient regimes from sedimentary records in regions with strong productivity gradients might be biased due to the mixture of particles originating from autochthonous and allochthonous sources. This could result in an imprint of high productivity signatures on sedimentation processes in oligotrophic regions.

Upwelling intensity and filament activity off Morocco during the last 250,000 years

Abstract The high-productive upwelling area off Morocco is part of one of the four major trade-wind driven continental margin upwelling zones in the world oceans. While coastal upwelling occurs mostly on the shelf, biogenic particles derived from upwelling are deposited mostly at the upper continental slope. Nutrient-rich coastal water is transported within the Cape Ghir filament region at 30°N up to several hundreds of kilometers offshore. Both upwelling intensity and filament activity are dependent on the strength of the summer Trades. This study is aimed to reconstruct changes in trade wind intensity over the last 250,000 years by the analysis of the productivity signal contained in the sedimentary biogenic particles of the continental slope and beneath the Cape Ghir filament. Detailed geochemical and geophysical analyses (TOC, carbonate, C/N, δ13Corg, δ15N, δ13C of benthic foraminifera, δ18O of benthic and planktic foraminifera, magnetic susceptibility) have been carried out at two sites on the upper continental slope and one site located further offshore influenced by the Cape Ghir filament. A second offshore site south of the filament was analyzed (TOC, magnetic susceptibility) to distinguish the productivity signal related to the filament signal from the general offshore variability. Higher productivity during glacial times was observed at all four sites. However, the variability of productivity during glacial times was remarkably different at the filament-influenced site compared to the upwelling-influenced continental slope sites. In addition to climate-related changes in upwelling intensity, zonal shifts of the upwelling area due to sea-level changes have impacted the sedimentary productivity record, especially at the continental slope sites. By comparison with other proxies related to the strength and direction of the prevailing winds (Si/Al ratio as grain-size indicator, pollen) the productivity record at the filament-influenced site reflects mainly changes in trade-wind intensity. Our reconstruction reveals that especially during glacial times trade-wind intensity was increased and showed a strong variability with frequencies related to precession.

Carbonate preservation records of the past 3 Myr in the Norwegian–Greenland Sea and the northern North Atlantic: implications for the history of NADW production

Carbonate preservation records from a number of drill sites in the North Atlantic and adjacent Norwegian–Greenland Sea (NGS) are used to reconstruct variations in North Atlantic Deep Water (NADW) production over the past 3 Myr. Before the initiation of major Northern Hemisphere glaciation, good carbonate preservation was recorded in the North Atlantic and the NGS supporting the superconveyor model of accelerated NADW formation in the late Pliocene. After the inception of main Northern Hemisphere glaciation, NADW formation in the NGS was blocked-off during the period 2.8–1.9 Ma. Carbonate was only badly preserved due to (1) low production of carbonate shells in surface waters, (2) sluggish renewal of deep waters induced by a rather stable sea-ice cover, and/or (3) production of carbonate-corrosive dense brines during sea-ice formation (e.g. sea ice dissolution mode). In contrast, contemporaneous good preservation in the adjacent North Atlantic indicates efficient NADW production. During the middle Matuyama (1.9–1.4 Ma), the first intrusions of the Proto-Norwegian Current into a narrow corridor in the southeastern NGS are evidenced by much better carbonate preservation. A decrease both in carbonate content and preservation towards the north and west of this corridor indicates the proximity of the polar front and gives evidence that NADW production was efficiently triggered by the Atlantic water entrainment mode. During the past 1.2 Myr carbonate preservation patterns in the NGS clearly reflect major global events like the Mid-Pleistocene Transition and the mid-Brunhes dissolution event. The onset of the Mid-Pleistocene Transition at 1.2 Ma is characterized by a complete shift to higher carbonate contents in the southeastern NGS and Labrador Sea. Overall, good preservation during both interglacials and glacials is only interrupted by high-frequency, short-term dissolution spikes, which were induced by ice sheet collapse and development of extensive meltwater lids. As a consequence, NADW was produced nearly continuously during glacials in the Nordic Seas. However, due to its lower density it was entrained into intermediate water levels in the North Atlantic and, thus, enforced the intermediate water circulation loop, whereas a decrease in lower-NADW production is observed contemporaneously.

Impacts of the North Atlantic gyre circulation on Holocene climate off northwest Africa

We present well-dated high-resolution Holocene records of sea-surface temperature (SST) and upwelling intensity off northwest (NW) Africa. We identify long-term cooling trends over the Holocene in the subtropical North Atlantic in response to boreal summer insolation. A pronounced cooling event of similar to 1 degrees C ca. 8.5 cal ka indicates a large-scale reorganization of the ocean current system possibly induced by meltwater from the northern North Atlantic. Our alkenone SST record off Cape Ghir provides strong evidence for the impact of ocean circulation changes on subtropical North Atlantic SSTs. It is likely that cold waters were propagated to the subtropics via the Canary Current in a way similar to Heinrich events and the Younger Dryas off Cape Blanc. We find 2-3 k.y. periodic variations in SST and upwelling intensity off NW Africa superimposed on the cooling trend. Such a cycle has been documented in various paleoclimate archives in phase with solar forcing. We show that these variations on millennial time scales are linked to the North Atlantic subtropical gyre circulation and the Northern Hemisphere atmospheric circulation, and in particular to changes in the pressure gradient between the Icelandic Low and the Azores High. This suggests that oceanic circulation, in response to solar forcing, played a more important role in the generation of 2-3 k.y. cyclicity than has been previously considered.

Assessment of geochemical and micropaleontological sedimentary parameters as proxies of surface water properties in the Canary Islands region

Abstract The Canary Islands region occupies a key position with respect to biogeochemical cycles, with the zonal transition from oligotrophic to nutrient-rich waters and the contribution of Saharan dust to the particle flux. We present the distribution of geochemical proxies (TOC, carbonate, δ15N, δ13Corg, C/N-ratio) and micropaleontological parameters (diatoms, dinoflagellates, foraminifera, pteropods), in 80 surface-sediment samples in order to characterise the influence of coastally upwelled water on the domain of the subtropical gyre. Results of the surface-sediment analyses confirmed the high biomass gradient from the coast to the open ocean inferred from satellite data of surface chlorophyll or SST. The distribution of total dinoflagellate cysts, the planktic foraminifera species Globigerina bulloides, the diatom resting spore Chaetoceros spp., and TOC concentration coincided well with the areas of strong filament production off Cape Ghir and Cape Yubi. The warm-water planktic foraminifera Globigerinoides ruber (white), the diatom Nitzschia spp., and the δ15N-values showed the opposite trend with high values in the open ocean. Factor analyses on the planktic foraminifera species distribution indicated three major assemblages in the Canary Islands region that represent the present surface-water conditions from the upwelling influenced region via a mixing area towards the subtropical gyre.

Recent and Pleistocene carbonate dissolution in sediments of the Norwegian–Greenland Sea

Surface sediment samples from the Norwegian–Greenland Sea were investigated to reconstruct the spatial distribution of recent carbonate dissolution on the seafloor. Additionally, carbonate dissolution records of Ocean Drilling Program sites 985 and 987 are presented to outline the development of Pleistocene carbonate preservation. Today, well-preserved carbonate tests can be observed along the inflow of warm Atlantic surface water, extending as far as into the northernmost Norwegian–Greenland Sea. Increased dissolution is indicated along the continental margins and in the deepest parts of the Greenland Basin. Factors favoring carbonate preservation were found to be supersaturation of the water column with respect to calcium carbonate, high carbonate rain and probably excess alkalinity of bottom waters supplied by the arctic river discharge. Supralysoklinal dissolution is most important for recent carbonate dissolution in the Norwegian–Greenland Sea, whereas the deepest parts of the Greenland Basin reaches the calcite saturation horizon. Pleistocene dissolution records show some prominent peaks of extreme carbonate dissolution. During the Brunhes chron, carbonate dissolution maxima can be related to meltwater pulses, which probably inhibited deep-water formation in the Norwegian–Greenland Sea during deglaciation events. Long-term severe carbonate dissolution is evident during the late Matuyama chron. This can be probably related to low carbonate rain, due to a more eastwards located East Greenland Current and the nearly absence of the not yet polar adapted Neogloboquadrina pachyderma sin. during that period. Extreme dissolution events during the late Matuyama indicate strongly reduced deep-water formation.