Helmut W Fischer

Increase in African dust flux at the onset of commercial agriculture in the Sahel region

The Sahara Desert is the largest source of mineral dust in the world. Emissions of African dust increased sharply in the early 1970s (ref. 2), a change that has been attributed mainly to drought in the Sahara/Sahel region caused by changes in the global distribution of sea surface temperature. The human contribution to land degradation and dust mobilization in this region remains poorly understood, owing to the paucity of data that would allow the identification of long-term trends in desertification. Direct measurements of airborne African dust concentrations only became available in the mid-1960s from a station on Barbados and subsequently from satellite imagery since the late 1970s: they do not cover the onset of commercial agriculture in the Sahel region ∼170 years ago. Here we construct a 3,200-year record of dust deposition off northwest Africa by investigating the chemistry and grain-size distribution of terrigenous sediments deposited at a marine site located directly under the West African dust plume. With the help of our dust record and a proxy record for West African precipitation we find that, on the century scale, dust deposition is related to precipitation in tropical West Africa until the seventeenth century. At the beginning of the nineteenth century, a sharp increase in dust deposition parallels the advent of commercial agriculture in the Sahel region. Our findings suggest that human-induced dust emissions from the Sahel region have contributed to the atmospheric dust load for about 200 years.

Sediment Trapping by Dams Creates Methane Emission Hot Spots

Inland waters transport and transform substantial amounts of carbon and account for ∼18% of global methane emissions. Large reservoirs with higher areal methane release rates than natural waters contribute significantly to freshwater emissions. However, there are millions of small dams worldwide that receive and trap high loads of organic carbon and can therefore potentially emit significant amounts of methane to the atmosphere. We evaluated the effect of damming on methane emissions in a central European impounded river. Direct comparison of riverine and reservoir reaches, where sedimentation in the latter is increased due to trapping by dams, revealed that the reservoir reaches are the major source of methane emissions (∼0.23 mmol CH4 m(-2) d(-1) vs ∼19.7 mmol CH4 m(-2) d(-1), respectively) and that areal emission rates far exceed previous estimates for temperate reservoirs or rivers. We show that sediment accumulation correlates with methane production and subsequent ebullitive release rates and may therefore be an excellent proxy for estimating methane emissions from small reservoirs. Our results suggest that sedimentation-driven methane emissions from dammed river hot spot sites can potentially increase global freshwater emissions by up to 7%.

The use of dinoflagellate cysts to separate human-induced from natural variability in the trophic state of the Po River discharge plume over the last two centuries.

To obtain insight into the natural and/or human-induced changes in the trophic state of the distal portion of the Po River discharge plume over the last two centuries, high temporal resolution dinoflagellate cyst records were established at three sites. Cyst production rates appear to reflect the natural variability in the rivers discharge, whereas cyst associations reflect the trophic state of the upper waters, which in turn can be related to agricultural development. The increased abundances of Lingulodinium machaerophorum and Stelladinium stellatum found as early as 1890 and 1920 correspond to the beginning of the industrial revolution in Italy and the first chemical production and dispersion of ammonia throughout Europe. After 1955, the increased abundances of these species and of Polykrikos schwartzii, Brigantedinium spp. and Pentapharsodinium dalei correspond to agriculturally induced alterations of the hypertrophic conditions. A slight improvement in water quality can be observed from 1987 onward.

Medical radioisotopes in the environment – following the pathway from patient to river sediment

Motivated by the detection of (131)I in river sediment in routine long-term surveillance samples, a systematic short-term study of the wastewater treatment chain was planned and conducted. Inflow, effluent and primary sludge were collected on a daily basis during two weeks at a regional wastewater treatment plant. Samples were investigated by gamma spectroscopy. Four medically used isotopes could be identified ((131)I and (99m)Tc regularly, (153)Sm and (123)I sporadically). The concentration levels coincide well with literature data for (131)I, and with our own long-term data for (131)I and (99m)Tc for the same plant. Cosmogenic (7)Be activity in primary sludge correlated well with rainfall intensity. Surface sediment was sampled at low tide at both shores of the river, up- and downstream of the plant. (131)I was identified in all samples, with a sharp maximum (about 100 Bq kg(-1)d.m.) at the discharge point of the plant and lower levels elsewhere, decreasing monotonically in downstream direction. (7)Be and (137)Cs showed the same behaviour, but no peak at the discharge point. Predictions from simple equilibrium models for the transport and sedimentation of (131)I show good agreement with the experimental data and suggest that the wastewater treatment plant is the main source for this isotope.

Comparison of activation products and induced dose rates in different high-energy medical linear accelerators.

Sequences of in situ gamma spectra, accompanied by continuous dose rate measurements, have been obtained at the isocenters of four different brands of high-energy medical linear accelerators shortly after beam-off in order to study the effects of radioactivation. Spectral analysis revealed up to 20 different radionuclides per machine, with a total of 21 found isotopes having half-lives between 2.3 min and 5.3 y. Important isotopes as judged from activity, dose rate, and half-life were 28Al, 54Mn, 56Mn, 57Ni, 60Co, 62Cu, 64Cu, 124Sb, 187W, and 196Au. Dose rates at isocenter calculated from the results of spectrum analysis ranged between 0.78 and 3.16 &mgr;Sv h−1 after beam-off, decaying to values between 0.18 and 0.54 &mgr;Sv h−1 within 30 min. Measured dose rates were systematically higher by up to a factor of 2, which is attributed mainly to the effect of beta radiation. No systematic dependence on machine properties or manufacturer could be identified. Assuming realistic working scenarios, absorbed dose values for the radiotherapy technologist staff range between 0.62 and 2.53 mSv y−1.

Activation processes in a medical linear accelerator and spatial distribution of activation products

Activation products have been identified by in situ gamma spectroscopy at the isocentre of a medical linear accelerator shortly after termination of a high energy photon beam irradiation with 15 x 15 cm field size. Spectra have been recorded either with an open or with a closed collimator. Whilst some activation products disappear from the spectrum with closed collimator or exhibit reduced count rates, others remain with identical intensity. The former isotopes are neutron-deficient and mostly decay by positron emission or electron capture; the latter have neutron excess and decay by beta(-) emission. This new finding is consistent with the assumption that photons in the primary beam produce activation products by (gamma, n) reactions in the treatment head and subsequently the neutrons created in these processes undergo (n, gamma) reactions creating activation products in a much larger area. These findings are expected to be generally applicable to all medical high energy linear accelerators.

Effect of ship locking on sediment oxygen uptake in impounded rivers

In the majority of large river systems, flow is regulated and/or otherwise affected by operational and management activities, such as ship locking. The effect of lock operation on sediment-water oxygen fluxes was studied within a 12.9 km long impoundment at the Saar River (Germany) using eddy-correlation flux measurements. The continuous observations cover a time period of nearly 5 days and 39 individual locking events. Ship locking is associated with the generation of surges propagating back and forth through the impoundment which causes strong variations of near-bed current velocity and turbulence. These wave-induced flow variations cause variations in sediment-water oxygen fluxes. While the mean flux during time periods without lock operation was 0.5 6 0.1 g m�2 d�1, it increased by about a factor of 2 to 1.0 6 0.5 g m�2 d�1 within time periods with ship locking. Following the daily schedule of lock operations, fluxes are predominantly enhanced during daytime and follow a pronounced diurnal rhythm. The driving force for the increased flux is the enhancement of diffusive transport across the sediment-water interface by bottom-boundary layer turbulence and perhaps resuspension. Additional means by which the oxygen budget of the impoundment is affected by lock-induced flow variations are discussed.

The importance of nuclear magnetic relaxation dispersion (NMRD) profiles in MRI contrast media development.

Muller RN, Vander Elst L, Rinck PA, Vallet P, Maton F, Fischer H, Roch A, Van Haverbeke Y. The importance of nuclear magnetic relaxation dispersion (NMRD) profiles in MRI contrast media development. Invest Radiol 1988;23(Suppl 1):S229‐S231. Observation of the relaxivity of MRI contrast media over a wide range of magnetic fields is not only necessary for predicting their efficiency at any field but also compulsory for understanding and improving their mechanisms of action. The best experimental approach to this problem is the field cycling method, which allows the exploration of nuclear relaxation over a broad interval of magnetic field intensity but requires a specially dedicated instrument called a relaxometer. Particularly relevant are the relaxivity profiles of the two chelates Gd‐DOTA and Gd‐DTPA. Both show an important decrease from low to high fields within the current imaging range (0.02 T to 1.5 T). Although high field relaxivities of these chelates are similar, Gd‐DTPA becomes less efficient in facilitating water protons relaxation at fields lower than 0.15 T. This behavior has to be related to different electronic relaxation times due to a different chelate symmetry.

Estimating the distribution of radionuclides in agricultural soils - dependence on soil parameters.

In this study it is shown how radionuclide distributions in agricultural soils and their dependence on soil parameters can be quantitatively estimated. The most important sorption and speciation processes have been implemented into a numerical model using the geochemical code PHREEQC that is able to include specific soil and soil solution compositions. Using this model, distribution coefficients (Kd values) for the elements Cs, Ni, U and Se have been calculated for two different soil types. Furthermore, the dependencies of these Kd values on various soil parameters (e.g. pH value or organic matter content) have been evaluated. It is shown that for each element, an individual set of soil parameters is relevant for its solid-liquid distribution. The model may be used for the calculation of input parameters used by reference biosphere models (e.g. used for the risk assessment of nuclear waste repositories).

Direct air activation measurements at a 15-MV medical linear accelerator

Direct radiometric determination of (14)N (γ, n) (13)N air activation was achieved at a 15-MV medical linear accelerator operating in a high-energy photon mode. (13)N was identified by irradiating a gas-tight Marinelli beaker filled with nitrogen gas and later observing the 10-min half-life of the 511-keV positron-electron annihilation line using high-resolution gamma spectroscopy. Quantitative evaluation of the spectral signal yielded a (13)N production rate of 836.8 ± 32 Bq Gy(-1) in air per 40 × 40 cm(2) field cross section at 100 cm source-surface distance.