Hema Achyuthan

Bisphenol A and other bisphenol analogues including BPS and BPF in surface water samples from Japan, China, Korea and India.

Concentrations of eight bisphenol analogues (BPs) including BPA, BPS, and BPF were determined in surface waters collected from select rivers in Japan, Korea, China, and India. BPA was found at a concentration in the range of several tens to several hundreds of nanograms per liter in most of the rivers surveyed and some of the highest concentrations (54-1950 ng/L) were found in rivers in Chennai, India. Concentrations of BPF were one to two orders of magnitude higher than those of BPA in river and sea waters collected from Japan, Korea and China, which suggested that BPF is a major contaminant in surface waters in several Southeast Asian countries. BPF concentrations as high as 2850 ng/L were found in the Tamagawa River in Japan. The flux of BPs through riverine discharges into Tokyo Bay was calculated to be approximately 5.5 t per year. Based on the flux estimates and the mass of BPF found in water column and sediment in Tokyo Bay, it was found that BPF degrades faster than BPA in the environment. Elevated concentrations of BPF found in surface waters suggest the need for further studies to determine the fate and toxicity of this compound.

Petrologic analysis and geochemistry of the Late Neogene-Early Quaternary hardpan calcretes of Western Rajasthan, India

Abstract Calcretes formed over bedrock such as Precambrian hornblende-chlorite schist, rhyolite and carbonaceous phyllites in Western Rajasthan, India, were studied for their mineralogical composition and geochemistry. They form a distinct element of the Quaternary landscape of Western Rajasthan, India. The study area is located within the Nagaur–Churu–Jaipur tract of Western Rajasthan. The purpose of this study was to determine the processes governing the development of hardpan calcretes, and to evaluate the local and regional controls on their formation. Micromorphology included pedogenetic and groundwater features within the hardpan calcretes. Thickening of calcite laminae downward and tapering at the sideward edges around the unweathered minerals of quartz and feldspars indicated cumulative and compound pedogenesis, which probably occurred locally, and downward movement of carbonate solution and pore water. Carbonate solutions were probably derived from the upper horizons or surfaces bringing about the process of dissolution and recementation of individual laminae. Occurrence of fibrous palygorskite as coatings around the detrital grains and siderite (oolitic and pisolitic in shape) points to a subalkaline–subacidic process of pedogenesis in a semi-arid to arid climate. Stable δ13C and δ18O isotope data of the hardpan calcrete laminae vary between 0.3‰ to 1.5‰ and −5.9‰ and −1.5‰, respectively indicating their formation at or near surface (capillary fringe), probably supporting a thin column of soil. The source of most of the calcite is groundwater; however, calcite nodule formation was largely dependent on pedogenic processes associated with evaporation, evapotranspiration and /or microenvironmental changes in pH and CO2 partial pressure. Dust is also a major source for carbonate precipitation. Although it is commonly assumed that the powdery calcretes are younger in age compared to the more complex forms, the occurrence of Middle Palaeolithic tools below the hardpan calcrete at Roopangarh and Dayalpura, and above the hardpan calcretes at Mitri, Genana and Rol, indicates that the morphology of calcretes is not a reliable indicator of age.

PALAEOFLOOD RECORDS FROM UPPER KAVERI RIVER, SOUTHERN INDIA: EVIDENCE FOR DISCRETE FLOODS DURING HOLOCENE

Palaeoflood Records from Upper Kaveri River, Southern India: Evidence for Discrete Floods During Holocene A record of six discrete middle Holocene floods has been established based on sedimentological and stratigraphical studies in the upper Kaveri catchment at Siddapur. The flood events are represented by six discrete, sharp-bounded, sand-silt couplets. Texturally and geochemically the suite of couplets is quite distinct from the overlying and underlying structureless fluvial deposits. Based on OSL ages the suite of couplets cover the Holocene from ~8 to ~2 ka. Such evidence is not present or reported from any other river originating in the Western Ghat in the Indian Peninsula. We argue that the six couplets represent short-term, high discharge events or flash floods. The initiation of this phase of flash floods broadly corresponds with the southward migration of ITCZ and a gradual decline in Indian summer monsoon precipitation starting at ~7.8 ka. Comparison of the elevation of the highest couplet with the high flood level (HFL) of the 1961 extraordinary flood on Kaveri demonstrates that the 20th century flood was higher than the mid-Holocene palaeofloods.

Residual Luminescence in Quartz from Slack Water Deposits in Kaveri Basin, South India: A Single Aliquot Approach

Residual Luminescence in Quartz from Slack Water Deposits in Kaveri Basin, South India: A Single Aliquot Approach Optical bleaching of quartz may be incomplete due to decreased daylight intensity and narrower wavelength spectrum in water column, leading to age overestimation in young fluvial sediments. This hypothesis was tested on a low energy slack water deposits from Kaveri Basin in south India using the SAR protocol. Various tests suggest successful application of SAR on quartz from the study area despite low sensitivity and few numbers of bright grains. Partial bleaching can be ruled out if using SAR on small aliquots. The results suggest a uniform residual luminescence and a common sedimentary condition in this area. Due to partial bleaching, the lowest values of palaeodoses should be considered in preference to the average values.

Geomorphic evolution and genesis of laterites around the east coast of Madras, Tamil Nadu, India

Abstract Laterites and lateritic soils (Red soils) of the east coast especially around Madras, Tamil Nadu have been formed in different geomorphic conditions and on various geological deposits. They occur as caprocks over recent alluvium, Upper Gondwana sandstones and shales, and Precambrian basement rocks. The laterite profiles studied around Madras are generally 2 to 5 m thick and exposed 5 to 45 km inland from the present-day shoreline. Detailed analysis (micromorphological and chemical) and the bore hole litho-log data reveal that lateritisation was not continuous but occurred in phases. Lateritisation could have taken place in humid to sub-humid conditions with a rich source of iron in the parent rock and sediment and efficient internal drainage. Geoarchaeological investigations and Quaternary stratigraphical studies date the lateritic crust surface to the early late Neogene. Neotectonics have played a vital role in shaping the present landscape.

Coastal response to changes in sea level since the last 4500 BP on the east coast of Tamil Nadu, India.

Geomorphology, clay mineral composition, and radiocarbon dates from Muttukadu to Marakkanam estuaries and the tidal zone along the east coast of Tamil Nadu, India, have been used to reconstruct coastal evolution between approximately 4500 and 1100 BP. Formation of alternate oyster beds with intervening tidal clay units indicate fluctuation in the sea level may be a consequence of changes in the Mid-Holocene sedimentation pattern and coastal configuration. (super 14) C dates from Muttukadu indicate a rapid relative sea-level rise (RSL) subsequent to 3500 BP and tidal flat sedimentation between 3475 and 3145 BP. Marine conditions along the east coast area returned around 1900 BP. Comparison of dates with other sites, e.g. Muttukadu, Mammallapuram, and Marakkanam, points toward short removal of marine conditions, ample sediment supplies in the tidal zones, and neotectonic activity. Reactivation of the north-south trending fault line occurred not earlier than approximately 1050 BP. Our study indicates that Middle to Late Holocene coastal sedimentation and the chronology of the tidal zone formation have been strongly influenced by local factors. These have provided considerable scope for internal reorganization with changing coastal processes.

A Record of Palaeo-Tsunami in the Indian Ocean

The history of catastrophic events on the Indian coast helps us to understand the frequency and magnitude of the tsunamis that occurred in the Indian Ocean. These catastrophic events have changed the coastal landscape and have left significant records for further studies. These rare events have occurred in the Indian Ocean. There have been megatsunamigenic events in the past due to volcanic eruptions and earthquakes. Those events due to earthquakes have proved more catastrophic than the volcanic activities. There has been limited official records of the causality and magnitude of palaeo-tsunamigenic events. These have been studied using the various proxies. The rate of sedimentation is a proportional tool to study the magnitude of a tsunami and this has proved to be a successful tool along with foraminiferal assemblages. Causes for a tsunami to occur are by and large, the subduction zone earthquakes of the Indian plate has been the most common source for tsunami in the Indian Ocean. More often the Andaman and Nicobar and the Indonesian islands have been vulnerable to tsunami than the mainland of India and Sri Lanka. In summary, in the last 200 years at least three basin-wide tsunamis have occurred, with several smaller tsunami affecting one or more coastlines in the region. The December 2004 M-9 tsunami seems to have been the largest and most destructive in the last two centuries, suggesting most tsunami are likely to be smaller but still allowing the possibility that even larger tsunami could be generated in propitious circumstances.

Geochemistry of Manasbal lake sediments, Kashmir: Weathering, provenance and tectonic setting

This paper presents a detailed sediment chemistry investigation of the Manasbal lake, Srinagar, Jammu and Kashmir, India, which is one of the high altitude lakes in the Kashmir valley. 22 lake floor sediment samples covering the entire lake were collected and analyzed for textural characteristics, CaCO3, organic matter, TOC, TN contents, C/N ratio, major and trace element chemistry. These analyses were conducted to trace the provenance of the sediments. Textural parameters reveal that the lake sediments consist predominantly clay and silt fractions. The C/N ratio of the sediments indicates a mixed source of TOC, both autochthonous and allochthonous in origin. The log (Fe2O3/K2O) Vs. log (SiO2/ Al2O3) graph of the sediments discriminates the rock types of the catchment area that are Fe-shale, Fe-sand, wacke, shale and litharenite. The Chemical Index of Alteration (CIA) falls between 59.11 to 90.16% and Chemical Index of Weathering (CIW) between 63.97 to 99.68% and these values are higher than the Post-Archaean Australian Shale (PAAS), indicating moderate to highly chemically weathered lake floor sediments. Plagioclase Index of Alteration (PIA) values (60.74-99.63%) suggests the occurrence of plagioclase feldspars in the lake floor sediments. Geochemical characteristics signify a mixed-nature of provenance of the lake floor sediments due to the tectonic settings of the lake basin in a complex catchment area.

Ferricretes in Tamil Nadu, Chennai, South-Eastern India: From Landscape to Micromorphology, Genesis, and Paleoenvironmental Significance

Ferricretes located in the coastal plain around Chennai, southeastern India, were analysed in thin sections using the concept of pedo-sedimentary sequence of events based on the hierarchy of sedimentary and pedological features and organisations. Field characteristics of investigated ferricretes are similar to those described in the literature. From top to bottom, they consist of a pisolithic crust, lying on hard ferruginous crust merging into a plinthite developed on mottled clays. Frequently the hard crust is hosted on ferruginous gravels. A sandy clay layer covers the ferricrete in one of the surveyed site. These ferricretes appear as inliers above the Late Pleistocene and Holocene riverbeds. Micromorphological analysis lead to conclude that the genesis of ferricretes studied have a complex succession of phases and attributes which were overlapping. Some of these phases are purely pedogenic, characterised by an intense iron oxide accretion, which occurred during episodes of landscape stability characterised by high ground water levels. Other phases reveal two different modes of erosion that have been recognised as, (i) deep erosion of plinthitic soils followed by a local deposition in the form of ferruginous gravel, (ii) surface erosion of hard ferruginous crust, long distance transportation and sedimentation in the form of a nodular layer. The sandy clay layers, which were found in one site, also confirmed the aeolian input in the area. A reconstruction of the local past landscapes is also proposed as well as a discussion on the environmental significance of the ferricretes studied.

Early-Holocene to present palaeoenvironmental shifts and short climate events from the tropical wetland and lake sediments, Kukkal Lake, Southern India: Geochemistry and palynology

The Kukkal basin, Tamil Nadu, India, receives most of its rain from the southwest monsoon (SWM). A sediment core from Kukkal Lake preserves a continuous sediment record from the early-Holocene to present (9000 yr BP to present). The present lake is situated at an elevation of ~1887 m a.s.l., in a small basin that appears to have alternated between a and wetland depositional environment. Climate proxies, including sediment texture, total organic carbon (TOC), total nitrogen (TN), C/N, pollen and geochemical composition indicate a steady progression to wetter conditions, with two stepwise changes at about 8000, and between 3200 and 1800 yr BP. The change at 8000 yr BP appears to correspond to a brief (100–150 years) dry spell recorded elsewhere in India. The change at 3200–1800 yr BP consisted in a rapid intensification of the SWM, and may correlate with the initiation of the ‘Roman Warm Period’. There is no clear evidence of changes at the times of the ‘Medieval Warm Period’ (‘MWP’) and the ‘Little Ice Age’ (‘LIA’). The C/N ratio of the sediments ranges from 14.02 to 8.31, indicating that the organic matter originated from a mixture of lacustrine algae, vascular and terrestrial plants. Chemical weathering indices (Chemical Index of Alteration (CIA), Chemical Index of Weathering (CIW), and Plagioclase Index of Alteration (PIA)) are consistent with extreme silicate weathering. Pollen data show a development from savanna vegetation prior to about 8000 yr BP, followed by grassland with palms, the appearance of ferns just prior to 3200 yr BP and the establishment of the tropical humid forest between 3200 and about 1800 yr BP.