xiang He

Pinhole-Free and Surface-Nanostructured NiOx Film by Room-Temperature Solution Process for High-Performance Flexible Perovskite Solar Cells with Good Stability and Reproducibility

Recently, researchers have focused on the design of highly efficient flexible perovskite solar cells (PVSCs), which enables the implementation of portable and roll-to-roll fabrication in large scale. While NiOx is a promising material for hole transport layer (HTL) candidate for fabricating efficient PVSCs on a rigid substrate, the reported NiOx HTLs are formed using different multistep treatments (such as 300-500 °C annealing, O2-plasma, UVO, etc.), which hinders the development of flexible PVSCs based on NiOx. Meanwhile, the features of nanostructured morphology and flawless film quality are very important for the film to function as highly effective HTL of PVSCs. However, it is difficult to have the two features coexist natively, particularly in a solution process that flawless film will usually come with smooth morphology. Here, we demonstrate the flawless and surface-nanostructured NiOx film from a simple and controllable room-temperature solution process for achieving high performance flexible PVSCs with good stability and reproducibility. The power conversion efficiency (PCE) can reaches a promising value of 14.53% with no obvious hysteresis (and a high PCE of 17.60% for PVSC on ITO glass). Furthermore, the NiOx-based PVSCs show markedly improved air stability. Regarding the performance improvement, the flawless and surface-nanostructured NiOx film can make the interfacial recombination and monomolecular Shockley-Read-Hall recombination of PVSC reduce. In addition, the formation of an intimate junction of large interfacial area at NiOx film/the perovskite layer improve the hole extraction and thus PVSC performances. This work contributes to the evolution of flexible PVSCs with simple fabrication process and high device performances.

A PCBM Electron Transport Layer Containing Small Amounts of Dual Polymer Additives that Enables Enhanced Perovskite Solar Cell Performance

A polymer/PCBM hybrid electron transport layer is reported that enables high‐performance perovskite solar cells with a high power conversion efficiency of 16.2% and with negligible hysteresis. Unlike previous approaches of reducing hysteresis by thermal annealing or fullerene passivation, the success of our approach can be mainly attributed to the doping of the PCBM layer using an insulating polymer (polystyrene) and an amine‐containing polymeric semiconductor named PFNOX.

Smooth CH3NH3PbI3 from controlled solid–gas reaction for photovoltaic applications

The merits of high power conversion efficiency (PCE) and easy preparation make organic–inorganic perovskite solar cells one of the most promising solar devices. However, PCE is greatly dependent on the morphology of perovskite thin film. Here, we report a solid–gas reaction method to fabricate very smooth CH3NH3PbI3 thin film with high coverage. Through controlling the reaction rate between CH3NH3I and PbI2 by tuning the PbI2 substrate temperature and the evaporation rate of CH3NH3I, we obtain a CH3NH3PbI3 layer with roughness of 7.37 nm. Besides, no post-treatment annealing is needed after film formation using our approach. With about 250 nm perovskite active layer, the solar cells exhibit a PCE of 10.0% with little hysteresis.

Accelerated wavefront determination technique for optical imaging through scattering medium

Wavefront shaping applied on scattering light is a promising optical imaging method in biological systems. Normally, optimized modulation can be obtained by a Liquid-Crystal Spatial Light Modulator (LC-SLM) and CCD hardware iteration. Here we introduce an improved method for this optimization process. The core of the proposed method is to firstly detect the disturbed wavefront, and then to calculate the modulation phase pattern by computer simulation. In particular, phase retrieval method together with phase conjugation is most effective. In this way, the LC-SLM based system can complete the wavefront optimization and imaging restoration within several seconds which is two orders of magnitude faster than the conventional technique. The experimental results show good imaging quality and may contribute to real time imaging recovery in scattering medium.

An improved wavefront determination method based on phase conjugation for imaging through thin scattering medium

Wavefront shaping applied on scattering light is an efficient method for imaging through thin scattering layers. Normally, optimized modulation can be obtained by a liquid-crystal spatial light modulator (LCSLM) and CCD hardware iteration. In this paper, an improved method for such an optimization process is introduced. The core of the proposed method is to firstly detect the disturbed wavefront, and then to calculate the modulation phase pattern by computer simulation. Fast processing speed resulting in high quality images have been achieved with this new approach. Using supposition of conjugated phase of the scattering wavefront and a Fresnel phase scheme, more than two orders of magnitude improvement in processing speed for imaging restoration was shown compared to the LCSLM-CCD iteration method.