Hideko Takayanagi

Carbon and Oxygen Isotope Records from Tridacna derasa Shells: Toward Establishing a Reliable Proxy for Sea Surface Environments.

We report the carbon (δ13C) and oxygen (δ18O) isotope records of three modern Tridacna derasa shells from Ishigaki-jima, southwestern Japan. The high-resolution δ13C profiles of samples from the inner shell layer on cross-sections fall within similar narrow ranges and display no regular variations or trends, such as an ontogenetic trend or abrupt short-term drops likely to be related to reproductive activity. This suggests that the calcification site of this species is not likely affected by photosynthetic CO2 uptake or CO2 incorporation during respiration. The δ18O profiles show distinct seasonal cycles. The intraspecific variability in the δ18O values is small in parts of the shell precipitated in the adult stage, but is not negligible in the juvenile and senescent stages. The differences in the monthly and seasonally resolved δ18O values among shells are less than 0.51‰ and 0.76‰, respectively. The shell δ18O values are nearly identical or close to the δ18O values for aragonite precipitated in oxygen isotope equilibrium with ambient seawater (δ18OEA). The largest differences between the shell δ18O and δ18OEA values calculated from the monthly and seasonally resolved data correspond to an overestimate of the seawater temperature by as much as 1.7°C and 2.3°C, respectively. However, these differences are smaller in the adult stage (<0.25‰) than in the other stages. This small difference allows an accurate reconstruction of the seawater temperature with an error of <1.1°C. Consequently, we recommend that multiple shell records be obtained because of the non-negligible intraspecific variations in their δ18O values. Growth banding, composed of alternating narrow white bands and wide light-grey bands, is discernible on cross-sections of the inner shell layer. The δ18Oshell data indicate that they were formed in winter and the other seasons, respectively.

Temporal changes in biotic and abiotic composition of shallow-water carbonates on submerged seamounts in the northwestern Pacific Ocean and their controlling factors

ABSTRACT The lithology of Cretaceous to Pleistocene shallow-water carbonates, which were collected from 29 sites on 24 submerged seamounts in the northwestern Pacific Ocean using the Deep-sea Boring Machine System, are described. The shallow-water carbonate deposits examined in the present study can be roughly divided into three types based on their composition: Cretaceous, Eocene (to lowest Oligocene?), and Oligocene to Pleistocene. The Cretaceous type is characterized by an abundance of molluscs (including rudists), smaller foraminifers, microencrusters, non-skeletal grains (e.g., peloids, cortoids, and intraclasts), and microbial sediments. Most components have been micritized and possess thick micrite envelopes. The Eocene type is characterized by the dominance of larger foraminifers, Halimeda spp., nongeniculate and geniculate coralline algae, bryozoans, and dasycladacean algae. Scleractinian corals are very minor components. The Oligocene to Pleistocene type is similar in composition to the Eocene type, but it differs from the latter by the abundant occurrence of scleractinian corals and nongeniculate coralline algae. Corals, nongeniculate coralline algae, and Halimeda spp., which precipitate carbonates within closed to semi-closed spaces in and around their bodies (intra-tissue), are major components of the Eocene and Oligocene to Pleistocene types. In contrast, the Cretaceous-type sediments contain relatively more carbonates of extra-tissue origin (i.e. carbonates deposited in relatively open spaces around the bodies of organisms, such as rudists, as well as microbialite and ooids) than the Eocene and Oligocene to Pleistocene types. The changes in the major constituents of the carbonate factory depend on local environments, such as nutrient availability, as well as a global factor: seawater chemistry in the surface waters. Temporal variations in the abundance of the shallow-water carbonates on the examined seamounts suggest that carbonate accumulation was not necessarily controlled by climatic conditions; instead, it was related to the volcanism and tectonics that served as the foundations for reef/carbonate-platform formation.

Geochemical, petrographical, and petrophysical evaluations of a heterogeneous, stratiform dolomite from a Barremian oil field, offshore Abu Dhabi (United Arab Emirates)

A stratiform dolomite is developed in the Barremian carbonates of offshore Abu Dhabi, United Arab Emirates. Although the average thickness is only 1.1 m (3.6 ft), it is an important drilling target characterized by heterogeneous porosity–permeability values in the studied oil field. We discuss the origin and development of the dolomite based on geochemical, petrographical, and petrophysical evaluations using 81 cores recovered from the field. The δ13C values of the dolomites are relatively high (>5‰), and 87Sr/86Sr mostly fall in the range of Barremian seawater. The thin stratiform geometry and the geochemical signatures of the dolomite suggest early dolomitization just below the seafloor that was driven by the diffusion of Mg2+ from the seawater on top of a shallow platform. Lateral changes in the degree of dolomitization seem to be controlled by the permeability of the precursors. Dolomitization progressed further in packstone precursors (higher permeability) than in wackestone precursors (lower permeability), which led to greater permeability improvement in the packstone by replacement of fine matrix with larger dolomite crystals. Subsequently, late burial dolomite cementation occurred during oil migration, which preferentially affected the higher-permeability early dolomite, and areally, it progressed more in the flank of the field because of the delayed oil charge there. Dolomite-to-dolomite recrystallization became dominant after the oil emplacement. The recrystallization has been continuing under current burial temperatures (>100°C [>212°F]), fully resetting δ18O values and modifying the Fe and Mn concentrations of the dolomites, but has not significantly affected their petrography and petrophysics in the oil leg.

Penetrative trace fossils from the late Ediacaran of Mongolia: early onset of the agronomic revolution

The Cambrian radiation of complex animals includes a dramatic increase in the depth and intensity of bioturbation in seafloor sediment known as the ‘agronomic revolution’. This bioturbation transition was coupled with a shift in dominant trace fossil style from horizontal surficial traces in the late Precambrian to vertically penetrative trace fossils in the Cambrian. Here we show the existence of the first vertically penetrative trace fossils from the latest Ediacaran: dense occurrences of the U-shaped trace fossil Arenicolites from late Precambrian marine carbonates of Western Mongolia. Their Ediacaran age is established through stable carbon isotope chemostratigraphy and their occurrence stratigraphically below the first appearance of the trace fossil Treptichnus pedum. These Arenicolites are large in diameter, penetrate down to at least 4 cm into the sediment, and were presumably formed by the activity of bilaterian animals. They are preserved commonly as paired circular openings on bedding planes with maximum diameters ranging up to almost 1 cm, and as U- and J-shaped tubes in vertical sections of beds. Discovery of these complex penetrative trace fossils demonstrates that the agronomic revolution started earlier than previously considered.