Hirochika Sumino

Lithium isotopic systematics of the mantle-derived ultramafic xenoliths: implications for EM1 origin

Isotopic signatures of mantle-derived xenoliths have provided much information on the evolution of their mantle source regions. A recently developed multiple-collector inductively coupled plasma mass spectrometry method allows precise and accurate lithium isotopic determinations of Li-poor samples such as peridotites. We present Li–Sr–Nd isotopic systematics of clinopyroxenes (CPXs) in mantle-derived ultramafic xenoliths. The results show that Ichino-megata (Northeastern Japan) and Bullenmerri (Southeastern Australia) samples have positive δ7Li values (δ7Li∼+4 to +7‰, δ7Li=[[7Li/6Li]sample/[7Li/6Li]L-SVEC standard−1]×1000) common to values previously reported for terrestrial volcanic rocks. By contrast, unusually low δ7Li values (δ7Li∼−17‰) are observed in many samples from the Far East region of Russia (Sveyagin, Ennokentiev, and Fevralsky) and southwestern Japan (Kurose and Takashima). The δ7Li values of Sikhote-Alin (Sveyagin and Ennokentiev) samples vary widely from −17.1‰ to −3.1‰, while the δ7Li values are positively correlated with 143Nd/144Nd, and negatively correlated with 87Sr/86Sr. On the other hand, the δ7Li values of the Bullenmerri samples are essentially constant (δ7Li=+5.0 to +6.0‰), while the 87Sr/86Sr (0.7027∼0.7098) and 143Nd/144Nd ratios (0.51224∼0.51297) vary widely. These features can be explained by the results of a binary mixing between a depleted component (low-87Sr/86Sr, and high-143Nd/144Nd) and an enriched component (high-87Sr/86Sr, and low-143Nd/144Nd). The enriched component (metasomatic agent) in the mantle beneath the Sikhote-Alin area has extraordinarily low δ7Li value ( altered MORB) from the subducted slab during dehydration at low temperature. Consequently, it is deduced that Li of metasomatic agent with an extremely low δ7Li value is derived from subducted highly altered basalt. The enrichment of isotopically light Li (low δ7Li) may be a general property of EM1 mantle reservoir. The Li isotopic data suggest further that the EM1 and HIMU sources originate from different parts of a recycling oceanic crust. This is essentially the same as the models proposed previously based on the radiogenic isotopic data, but with the Li isotopic data requiring uppermost, highly altered basaltic crust as well as pelagic sediment in the EM1 source, but not so in the HIMU end-member. Because of the apparent sensitivity of Li isotopic composition to the alteration profile of subducted MORB, it may provide complementary information to Sr, Nd, and Pb isotopic compositions regarding the mantle source.

Reply to comment from Blanco et al. (2015) on “Evidence from acoustic imaging for submarine volcanic activity in 2012 off the west coast of El Hierro (Canary Islands, Spain) by Pérez et al. [Bull. Volcanol. (2014), 76:882–896]

We begin by noting our appreciation for the comment from Blanco et al. (2015) on BEvidence from acoustic imaging for submarine volcanic activity in June 2012 off the west coast of El Hierro (Canary Islands, Spain)^ by Pérez et al. (2014) because it provides the opportunity to maintain an open scientific debate on this issue within the right framework. This is especially important because one of the co-authors of the comment from Blanco et al. (2015) had previously made a suggestion to us that we should not send the acoustic imaging data taken on June 28, 2012, for publication. In our opinion, this recommendation was detrimental to open scientific debate, which is always tremendously beneficial for the development of science. Secondly, the comment from Blanco et al. (2015) suggests that readers may have been confused; we emphasize that the submarine volcanic activity in 2012 off the west coast of El Hierro described by Pérez et al. (2014) was not, as inferred by Blanco et al. (2015), a volcanic eruption. It has been well documented (e.g., Italiano and Nuccio 1991; Caracausi et al. 2005; García et al. 2006; Pérez and Hernández 2007) that new and/or sporadic volcanic activities, such as relatively weak or significant visible degassing processes during volcanic unrest, have commonly occurred both in subaerial and submarine environments of volcanic systems. Such activity includes things that are not a volcanic eruption, which implies release of juvenile volcanic material and not just the sudden release of steam/gas. Pérez et al. (2014) used only acoustic imaging data taken on June 28 as evidence for submarine volcanic activity in 2012 off the west coast of El Hierro. Without this data, it would have been impossible for us to submit our scientific contribution for publication.

Diffusive helium emissions as a precursory sign of volcanic unrest

Significant increases in helium emissions from the soil and 3 He/ 4 He ratios in groundwater on El Hierro Island (Canary Islands, Spain) were observed prior to the 2011–2012 submarine eruption off the coast of the island. The changes of diffusive helium emissions rate were observed one month prior to the submarine eruption onset (12 October 2011) and the major increase preceded increases in seismic energy release during the volcanic unrest. Measured 3 He/ 4 He ratios in groundwaters from a well in El Hierro Island increased from 2–3 R A to 7.2 R A (R A = 3 He/ 4 He ratio in air) 1 month prior to the eruption onset, and reached a peak of 8.2 R A , indicating a dominant magmatic contribution to the dissolved gases in ground waters. 3 He/ 4 He values and diffusive helium emission studies have been extremely important for forecasting the onset of the volcanic unrest and subsequent volcanic eruption. An aseismic exsolution of magmatic gases from magma bodies beneath El Hierro Island through fractures and vertical permeability structures increased the diffusive helium emission rate prior to episodes of seismic energy release associated with the volcanic unrest.

Precursory diffuse carbon dioxide degassing signature related to a 5.1 magnitude earthquake in El Salvador, Central America

Abstract Anomalous changes in the diffuse emission of carbon dioxide have been observed before some of the aftershocks of the 13 February 2001 El Salvador earthquake (magnitude 6.6). A significant increase in soil CO 2 efflux was detected 8 days before a 5.1 magnitude earthquake on 8 May 2001 25 km away from the observation site. In addition, pre- and co-seismic CO 2 efflux variations have also been observed related to the onset of a seismic swarm beneath San Vicente volcano on May 2001. Strain changes and/or fluid pressure fluctuations prior to earthquakes in the crust are hypothesized to be responsible for the observed variations in gas efflux at the surface environment of San Vicente volcano.

Adjacent releases of mantle helium and soil CO2 from active faults: observations from the Marmara region of the North Anatolian Fault zone, Turkey.

Volatile releases, in terms of CO2 efflux and noble gas of mantle origin, are investigated in the Marmara region of the seismically active North Anatolian Fault (NAF) zone. A total of 180 CO2 efflux measurements (1 to 309 g m−2d−1) were carried out along four transects across the NAF. Spatial variability of surface CO2 effluxes was higher at faulted sites, relative to comparable background areas. The δ13C values of soil CO2 are −24.0 to −15.6‰ without correlation with CO2 efflux values, which suggest that CO2 efflux anomaly is caused by fault-related biogenic gas flow. Furthermore, 36 gas and water samples from spring sites were investigated for 3He/4He ratios which resulted in a range from 0.26 R/RA to 4.22 R/RA. Large mantle helium contributions were observed from several sources along the NAF. The high CO2 efflux sector on the Gazikoy-Saros fault along the NAF coincides with the area of high mantle helium flux. This shows that fault zones play an important role both in transferring mantle helium to the surface and in causing fault-related biogenic gas flow.

Mössbauer studies on laser evaporated iron atoms and their reactions with oxygen in argon matrices

Laser-evaporated iron atoms were isolated in low-temperature Ar matrices and their chemical reactions with oxygen were investigated by means of Mössbauer spectroscopy. Reactions of iron atoms with oxygen produce FeO, Fe(O2), FeO3, (O2)FeO2 and OFeO isolated in the Ar matrices and their yields vary depending on the concentration of oxygen. Similarly, FeO and Fe(O2) were obtained by the reaction of iron atoms with N2O. Infrared spectroscopy and molecular orbital calculations were applied to support their assignments.

Ore-forming mechanism for the Xiaoxinancha Au-rich Cu deposit in Yanbian, Jilin Province, China: Evidence from noble gas isotope geochemistry of fluid inclusions in minerals

The Xiaoxinancha Au-rich copper deposit is one of important Au-Cu deposits along the continental margin in Eastern China. The deposit consists of two sections: the Beishan mine (North), composed of altered rocks with veinlet-dissemination sulfides and melnicovite-dominated sulfide-quartz veins, and the Nanshan mine (South), composed of pyrrhotite-dominated sulfide-quartz veins and pure sulfide veins. The isotope compositions of noble gases extracted from fluid inclusions in ore minerals, i.e. ratios of 3He/4He, 20Ne/22Ne and 40Ar/36Ar are in the ranges of 4.45–0.08 Ra, 10.2–8.8 and 306–430, respectively. Fluid inclusions in minerals from the Nanshan mine have higher 3He/4He and 20Ne/22Ne ratios whereas those from the Beishan mine have lower 3He/4He ratios. The analysis of origin, and evolution of the ore fluids and its relations with the ore-forming stages and the ages of mineralization suggests that the initial hydrothermal fluids probably come from the melts generated by partial melting of oceanic crust with the participation of fluids from the mantle (mantle-plume type)/aesthenosphere. This also corresponds to the continental margin settings during the subduction of Izanagi ocaneic plate towards the palaeo-Asian continent (123–102 Ma). The veinlet-dissemination ore bodies of the Beishan mine were formed through replacement and crystallization of the mixed fluids generated by mixing of the ascending high-temperature boiling fluid with young crustal fluid whereas the melnicovite-dominated sulfide-quartz veins were formed subsequently by filling of the high-temperature ore fluid in fissures. Pyrrhotite-dominated sulfide-quartz veins in the Nanshan mine were formed by filling-deposition-crystallization of the moderate-temperature ore fluids and the pure sulfide veins were formed later by filling-deposition-crystallization of ore substance-rich fluids after boiling of the moderate-temperature ore fluids. The metallogenic dynamic processes can be summarized as: (1) formation of fluid- and ore substance-bearing Adakitic magma by degassing, dewatering and partial melting during subduction of the Izanagi plate; (2) separation and formation of ore fluids from the Adakitic magma; and (3) success-sive ascending of the ore fluids and final formation of the Au-rich Cu deposit of veinlet-dissemination and vein types by secondary boiling.

High ³He/4He ratio in xenoliths from Takashima: Evidence for plume type volcanism in southwestern Japan

Cenozoic basalts distributed along the southwestern Japan arc system have geochemical features different from typical island-arc basalts, suggesting that the volcanism might have been triggered by a mantle plume. To identify the source materials in these volcanics, noble gas isotopic compositions of olivines separated from dunite xenoliths in alkaline basalts from Takashima, northwestern Kyushu, were measured. Most samples contain MORB-type helium. However, some samples showed ³He/4He ratios significantly higher than the MORB value, from 9.4 up to 16.6 times the atmospheric ratio of 1.4×10−6. This finding strongly supports the contribution of a mantle plume to the volcanism of this region.

Development of time projection chamber for precise neutron lifetime measurement using pulsed cold neutron beams

Abstract A new time projection chamber (TPC) was developed for neutron lifetime measurement using a pulsed cold neutron spallation source at the Japan Proton Accelerator Research Complex (J-PARC). Managing considerable background events from natural sources and the beam radioactivity is a challenging aspect of this measurement. To overcome this problem, the developed TPC has unprecedented features such as the use of polyether-ether-ketone plates in the support structure and internal surfaces covered with 6 Li-enriched tiles to absorb outlier neutrons. In this paper, the design and performance of the new TPC are reported in detail.

Carbon dioxide and helium dissolved gases in groundwater at central Tenerife Island, Canary Islands: chemical and isotopic characterization

Seismic-volcanic unrest was detected between 2004 and 2005 in the central and northwest zones of Tenerife Island (Canary Islands, Spain). With the aim of strengthening the program of geochemical and seismic-volcanic surveillance, a study of the origin, characteristics, and spatial distribution of dissolved carbon dioxide (CO2) and helium (He) gases in the volcanic aquifer of central Tenerife Island and around Teide volcano was carried out. This work also improves the hydrogeological and hydrogeochemical conceptual model of groundwater flow. Dissolved CO2 concentrations in sampled groundwater are several orders of magnitude higher than that of air-saturated water (ASW) suggesting a significant contribution of non-atmospheric CO2, mainly magmatic, confirmed through measurement of isotopic compositions (δ13CTDIC) and total dissolved inorganic carbon (TDIC) concentrations. A vertical stratification of dissolved CO2 and δ13CTDIC values was observed in the volcanic aquifer at the eastern region of Las Cañadas Caldera. Stratification seems to be controlled by both degree of magmatic CO2-water interaction and CO2 degassing and the original δ13Cco2(g) isotopic composition. The highest dissolved helium (4He) concentrations in groundwater seem to be related to radiogenic contributions resulting from water-rock interactions, and increase with residence time, instead of with endogenous magmatic inputs. Isotopic systematics show that the dissolved gases in groundwater of central Tenerife are variable mixtures of CO2–3He-rich fluids of volcanic-hydrothermal origin with both organic and atmospheric components. The results suggest that the eastern area of Las Cañadas Caldera, the South Volcanic Ridge, and the Teide summit cone are the areas most affected by degassing of the volcanic-hydrothermal system, and they are therefore the most suitable zones for future geochemical monitoring.