Hiroo Kagami

JNdi-1 : a neodymium isotopic reference in consistency with LaJolla neodymium

Abstract A neodymium oxide with relative 143Nd/144Nd ratio 1.000503±1(1 σm) to LaJolla Nd was prepared as a new isotopic reference. The neodymium reagent was selected from two points of view as follows. The first is low abundance of neighboring elements Ce and Sm, which affects isobaric interference. The second is high 143Nd/144Nd ratio, which is closer to those of chondritic and mantle-derived materials. The 143Nd/144Nd ratio of the reagent was measured alternately with LaJolla Nd to get a coherency with LaJolla Nd using 12 mass spectrometers in 11 laboratories in Japan. Aliquots of this neodymium oxide reagent named JNdi-1 are available upon request from the Geological Survey of Japan and may be useful for precise interlaboratory calibration of Nd isotopes.

The relationships between drastic changes in Sr isotope ratios of magma sources beneath the NE Japan arc and the spreading of the Japan Sea back-arc basin

SummaryBased on Sr isotopic data for Tertiary and Quaternary basaltic rocks from the NE Japan arc, relationships are discussed between the temporal variation of magma source characteristics and the opening of the Japan Sea. The basaltic rocks from the trench side and from the transitional zone show initial87Sr/86Sr ratios (Sri ratios) in the range of 0.70411–0.70546 but no temporal variation in Sri ratios. The back-arc side basaltic rocks with ages of 29.8 to ≈ 15 Ma have Sri ratios similar to those of the trench side and the transitional zone, and these values also show no temporal change. In contrast, the basaltic rocks from the back-arc side, with ages younger than ≈ 15 Ma, show significantly lower Sri ratios (0.70396 to 0.70290), which are slightly higher than those of N-type MORB. These Sr isotopic features may imply that at least before ≈ 15 Ma the magma source regions (the sub-continental mantle) beneath the NE Japan arc had an enriched chemical character and that after ≈ 15 Ma, the magma sources for volcanic rocks from the back-arc side show a drastic change in Sr isotopic character, from an enriched nature to a depleted one. The depleted magmas may have been formed as a result of injection of depleted asthenosphere (or of a depleted mantle diapir) into the subcontinental mantle under the back-arc side of the NE Japan arc, during the spreading of the Japan Sea back-arc basin. The middle Miocene basaltic rocks from the back-arc side are characterized by lower contents of LIL elements such as K2O and Rb compared with those from the trench side, suggesting that during the middle Miocene (syn-opening stage of the Japan Sea) the degree of partial melting may have been higher in the back-arc side mantle than in the trench side mantle. High degree of partial melting in the back-arc side mantle can be attributed to an increasing geothermal gradient in the mantle due to the injection of hot asthenosphere. This injection might also have caused the melting of the lower crust from which the voluminous middle Miocene acidic volcanics in the back-arc side and transitional zone may have been produced.ZusammenfassungDie Beziehungen zwischen der zeitlichen Veränderung der Charakteristika von Magmenquellen und der Öffnung des Japanischen Meeres werden anhand von Sr-Isotopendaten tertiärer und quartärer basaltischer Gesteine diskutiert. Basaltische Gesteine von der Grabenseite und aus der Übergangszone ergaben initiale87Sr/86Sr Verhältnisse (Sri-Verhältnisse) von 0.70411–0.70546 und lassen keine zeitabhängige Änderung erkennen. Basaltische Besteine aus dem Back-Arc-Bereich mit Altern zwischen 29.8 und ca. 15 Ma zeigen ähnliche Sri-Verhältnisse und ebenfalls keine zeitliche Veränderung. Im Gegensatz dazu sind basaltische Gesteine aus dem Back-Arc-Bereich, die jünger als ca. 15 Ma sind, signifikant in ihren Sri-Verhältnissen (0.70396–0.70290) erniedrigt. Diese Verhältnisse liegen etwas höher als die von N-MORB. Die Sr-Isotopenergebnisse lassen vermuten, daß zumindest vor ca. 15 Ma der Herkunftsbereich der Magmen (subkontinentaler Mantel) unter dem NE japanischen Vulkanbogen chemisch angereichert war, während die Magmenquellen der jüngeren vulkanischen Gesteine des Back-Arc-Bereiches durch eine drastische Abreicherung charakterisiert sind. Die abgereicherten Magmen könnten, während der Öffnung des japanischen Back-Arc-Beckens, als Folge der Injektion abgereicherter Asthenosphäre (oder eines abgereicherten Manteldiapirs) in subkontinentalen Mantel unterhalb des Back-Arcs des NE japanischen Vulkanbogens, gebildet worden sein. Die miozänen basaltischen Gesteine des Back-Arc-Bereiches sind außerdem durch niedrigere Gehalte an LIL-Elementen, wie z.B. K2O und Rb charakterisiert. Dies wird als Hinweis auf eine erhöhte Aufschmelzungsrate in diesem Bereich im mittleren Miozän (im Zuge der gleichzeitigen Öffnung des japanischen Meeres) verstanden. Die erhöhte Aufschmelzrate im Mantel des Back-Arc-Breiches wird auf einer Erhöhung des geothermischen Gradienten infolge der Injektion von heißer Asthenosphäre zurückgeführt. Diese Injektion von Asthenosphäre könnte auch der Grund für die Aufschmelzung von Unterkruste und für die Produktion weitverbreiteter saurer miozäner Vulkanite im Back-Arc-Bereich und der Übergangszone sein.

Spatial variations of Sr and Nd isotope ratios of Cretaceous-Paleogene granitoid rocks, Southwest Japan Arc

Cretaceous-Paleogene granitoid rocks and contemporaneous volcanic rocks are widely distributed in the Inner Zone of Southwest Japan. This intense intermediate to felsic magmatism is considered to have taken place on the eastern margin of the Eurasian Continent, before the Southwest Japan Arc drifted away from the continent in the middle Miocene, resulting in the opening of the Japan Sea. The granitoid rocks show regional variations in terms of their radiometric age, petrography, Sr, Nd and O isotope ratios. Based on Sr and Nd isotope ratios, granitoid rocks can be divided into three zones (South, Transitional and North) between the Median Tectonic Line and the Japan Sea. Granitoid rocks and associated gabbros of the North Zone have low initial Sr isotope ratios (0.7048 to 0.7068) and high initial εNd values (+3 to-2.2), whereas granitoid rocks and gabbros from the South Zone have high initial Sr isotope ratios (0.7070 to 0.7088) and low initial εNd values (-3.0to-8.0). Most granitoid rocks from the Transitional Zone have Sr and Nd isotope ratios that lie between those of the North and South Zones, although there is some overlap. Contamination of magmas by upper crust cannot explain this geographical variation in Sr and Nd isotopes. Instead, the regional variation is attributed to compositionally different, magma sources (probably upper mantle and lower crust), beneath the North and South Zones. This is supported by the Sr and Nd isotopic ratios of upper mantle and lower crustal xenoliths included in Cenozoic volcanic rocks in the North and South Zones. These ratios are similar to those of the granitoid rocks in the respective zones. It is suggested that a micro-continent or island arc consisting of continental crust was underthrust beneath the South Zone before or during the Cretaceous, resulting in compositionally distinct sources for granitoid rocks of the North and South Zones. The large variation observed in Sr and Nd isotope ratios for Transitional Zone granitoid rocks is explained by variable proportions of the two different crustal and upper mantle components.

Geochronological constraints on the Late Proterozoic to Cambrian crustal evolution of eastern Dronning Maud Land, East Antarctica: a synthesis of SHRIMP U–Pb age and Nd model age data

Abstract In eastern Dronning Maud Land (DML), East Antarctica, there are several discrete, isolated magmatic and high-grade metamorphic regions. These are, from west (c. 20°E) to east (c. 50°E), the Sør Rondane Mountains (SRM), Yamato–Belgica Complex (YBC), Lützow-Holm Complex (LHC), Rayner Complex (RC) and Napier Complex (NC). To understand this region in a Gondwanan context, one must distinguish between Pan-African and Grenvillian aged magmatic and metamorphic events. Sensitive high-resolution ion microprobe U–Pb zircon ages and Nd model ages for metamorphic and plutonic rocks are examined in conjunction with published geological and petrological studies of the various terranes. In particular, the evolution of the SRM is examined in detail. Compilation of Nd model ages for new and published data suggests that the main part of eastern Dronning Maud Land, including the SRM, represents juvenile late Mesoproterozoic (c. 1000–1200 Ma) crust associated with minor fragments of an older continental component. Evidence for an Archaean component in the basement of the SRM is lacking. As for central DML, 1100–1200 Ma extensive felsic magmatism is recognized in the SRM. Deposition of sediments during or after magmatism and possible metamorphism at 800–700 Ma is recognized from populations of detrital zircon in metasedimentary rocks. The NE Terrane of the SRM, along with the YBC, was metamorphosed under granulite-facies conditions at c. 600–650 Ma. The SW and NE Terranes of the SRM were brought together during amphibolite-facies metamorphism at c. 570 Ma, and share a common metamorphic and magmatic history from that time. High-grade metamorphism was followed by extensive A-type granitoid activity and contact metamorphism between 560 and 500 Ma. In contrast, TDM and inherited zircon core ages suggest that the LHC is a collage of protoliths with a variety of Proterozoic and Archaean sources. Later peak metamorphism of the LHC at 520–550 Ma thus represents the final stage of Gondwanan amalgamation in this section of East Antarctica.

Interaction of a spreading ridge and an accretionary prism: Implications from MORB magmatism in the Hidaka magmatic zone, Hokkaido, Japan

In the Hidaka magmatic zone of central Hokkaido, Paleogene mafic plutons have intruded a Late Cretaceous to early Paleogene accretionary prism, resulting in high-temperature metamorphism and anatexis. Primitive basaltic rocks, which make up part of these mafic plutons, are typical normal mid-ocean ridge basalt (MORB). Because this magmatism is probably synchronous with arrival of the Kula-Pacific ridge, we propose that the Hidaka magmatism represents ridge-trench collision. Isotopic ratios vary significantly within the mafic plutons, indicating that intracrustal evolution of normal MORB was accompanied by assimilation of the accretionary prism. Thus, juvenile continental crust in the Hidaka magmatic zone formed in a near-trench setting through the interaction of a spreading ridge and an accretionary prism, in marked contrast to normal mid-ocean ridges.

Extreme Crustal Metamorphism during a Neoproterozoic Event in Sri Lanka: A Study of Dry Mafic Granulites

Garnet‐clinopyroxene‐quartz granulites of the central Highland Complex of Sri Lanka preserve textural and compositional features indicative of high‐pressure, ultrahigh‐temperature (HP‐UHT) crustal metamorphism and multistage retrogression. Grains of the peak metamorphic assemblage, garnet‐clinopyroxene‐quartz, are commonly separated and embayed by late orthopyroxene‐plagioclase symplectites; however, in some domains, rare grain‐to‐grain associations of the peak assemblages are still preserved. Thermodynamic modeling in the CaO‐Na2O‐K2O‐FeO‐MgO‐Al2O3‐SiO2 system indicates peak metamorphic conditions of 12.5 kbar at 925°C. The temperature estimates using garnet and clinopyroxene core compositions are in the range 844°–982°C, in agreement with the thermodynamic modeling. In conclusion, the textural, geochemical, and thermodynamic modeling and thermobarometric data indicate a multistage decompression after HP‐UHT metamorphism. U‐Pb zircon (laser ablation–inductively coupled plasma mass spectrometry) ages represent the timing of the peak metamorphism at ca. 580 Ma. A Sm‐Nd internal isochron from mineral phases (garnet, clinopyroxene, orthopyroxene, and felsic fraction) and from a whole rock yields an age of \documentclass{aastex} \usepackage{amsbsy} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{bm} \usepackage{mathrsfs} \usepackage{pifont} \usepackage{stmaryrd} \usepackage{textcomp} \usepackage{portland,xspace} \usepackage{amsmath,amsxtra} \usepackage[OT2,OT1]{fontenc} \newcommand\cyr{ \renewcommand\rmdefault{wncyr} \renewcommand\sfdefault{wncyss} \renewcommand\encodingdefault{OT2} \normalfont \selectfont} \DeclareTextFontCommand{\textcyr}{\cyr} \pagestyle{empty} \DeclareMathSizes{10}{9}{7}{6} \begin{document} \landscape

Multiple magma sources involved in marginal-sea formation: Pb, Sr, and Nd isotopic evidence from the Japan Sea region

534\pm 12

Effects of recycled materials involved in a mantle source beneath the southwest Japan arc region: evidence from noble gas, Sr, and Nd isotopic systematics

\end{document} Ma interpreted as the time of isothermal decompression (retrogression). Our results from the central Highland Complex of Sri Lanka provide important constraints on the Neoproterozoic orogeny associated with the assembly of Gondwana.