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Dive into the research topics where Hiroyuki Akiho is active.

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Featured researches published by Hiroyuki Akiho.


Environmental Science & Technology | 2013

Elucidation of the mechanism of reaction between S2O8(2-), Selenite and Mn2+ in aqueous solution and limestone-gypsum FGD liquor.

Hiroyuki Akiho; Shigeo Ito; Hiromitsu Matsuda; Toshiaki Yoshioka

The mechanism of reaction between peroxodisulfate ion (S2O8(2-)), selenite (Se(IV)O3(2-)) and Mn(2+) as an inhibitor of selenite oxidation was studied using aqueous solutions composed of commercial reagents, as well as limestone-gypsum flue gas desulfurization (FGD) liquors sampled from coal fired power plants. The oxidation of selenite to selenate (Se(VI)O4(2-)) is promoted by the sulfate ion radical (SO4(-)) which results from decomposition of S2O8(2-). In the presence of Mn(2+), selenite oxidation was prevented due to the difference in rates of reaction with SO4(-). The ratio of the oxidation rate constants of selenite and Mn(2+) with SO4(-) was determined over a temperature range of 40-60 °C, and was found to be little influenced by the various coexisting components in FGD liquors.


Powder Technology | 2008

Mercury oxidation by copper oxides in combustion flue gases

Akimasa Yamaguchi; Hiroyuki Akiho; Shigeo Ito


Fuel | 2010

Effect of oxidizing agents on selenate formation in a wet FGD

Hiroyuki Akiho; Shigeo Ito; Hiromitsu Matsuda


Energy Conversion and Management | 2016

Carbon behavior in the cyclic operation of dry desulfurization process for oxy-fuel integrated gasification combined cycle power generation

Makoto Kobayashi; Hiroyuki Akiho


Energy | 2015

Performance evaluation of porous sodium aluminate sorbent for halide removal process in oxy-fuel IGCC power generation plant

Makoto Kobayashi; Hiroyuki Akiho; Yoshinobu Nakao


Fuel | 2012

Speciation and oxidation reaction analysis of selenium in aqueous solution using X-ray absorption spectroscopy for management of trace element in FGD liquor

Hiroyuki Akiho; Tohru Yamamoto; Yoshihisa Tochihara; Naoki Noda; Shinichi Noguchi; Shigeo Ito


Archive | 2008

Process of treating selenium-containing liquid

Hiroyuki Akiho; Shigeo Ito; Hiromitsu Matsuda


Journal of Environmental Management | 2017

Dry syngas purification process for coal gas produced in oxy-fuel type integrated gasification combined cycle power generation with carbon dioxide capturing feature

Makoto Kobayashi; Hiroyuki Akiho


Journal of The Japan Institute of Energy | 2004

Capturing Characteristic of Gaseous Mercury in Desulfurization Solutions Simulating the Limestone-Gypsum Process

Hiroyuki Akiho; Makoto Nunokawa; Hiromi Shirai


Fuel | 2017

Performance evaluation of honeycomb shaped sorbent for sulfur removal in advanced oxy-fuel IGCC power generation plant

Makoto Kobayashi; Hiroyuki Akiho

Collaboration


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Shigeo Ito

Central Research Institute of Electric Power Industry

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Makoto Nunokawa

Central Research Institute of Electric Power Industry

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Yoshihisa Tochihara

Central Research Institute of Electric Power Industry

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Hiromitsu Matsuda

Central Research Institute of Electric Power Industry

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Akimasa Yamaguchi

Central Research Institute of Electric Power Industry

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Masami Ashizawa

Central Research Institute of Electric Power Industry

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Naoki Noda

Central Research Institute of Electric Power Industry

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Tohru Yamamoto

Central Research Institute of Electric Power Industry

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Hiromi Shirai

Central Research Institute of Electric Power Industry

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