Hitoshi Sakata

HITTM cells—high‐efficiency crystalline Si cells with novel structure

Our unique, high-efficiency c-Si solar cell, named the HIT cell, has shown considerable potential to improve junction properties and surface passivation since it was first developed. The improved properties in efficiency and temperature dependence compared to conventional p – n diffused c-Si solar cells are featured in HIT power 21TM solar cell modules and other applications which are now on the market. In the area of research, further improvement in the junction properties of the a-Si/c-Si heterojunction has been examined, and the highest efficiency to date of 20.1% has recently been achieved for a cell size of 101 cm2. The high open circuit voltage exceeding 700 mV, due to the excellent surface passivation of the HIT structure, is responsible for this efficiency. In this paper, recent progress in HIT cells by Sanyo will be introduced. Copyright

Sanyo's Challenges to the Development of High-efficiency HIT Solar Cells and the Expansion of HIT Business

The worlds highest conversion efficiency levels of 21.8% (Voc: 0.718 V, Isc: 3.852 A, FF: 79.0%, confirmed by AIST) with a practical size of 100.4 cm2 has been achieved by using the HIT (hetero-junction with intrinsic thin layer) structure. This high efficiency has been mainly realized by the excellent c-Si/a-Si hetero-interface property obtained by our optimized surface cleaning process and high-quality and low-damage a-Si deposition technologies. This excellent c-Si/a-Si hetero-interface of the HIT structure results in a relatively high open circuit voltage (Voc) over 710 mV. Recently, we have succeeded in achieving an outstanding Voc of 730 mV for other efficient HIT solar cells. This result indicates the possibility of further improvement in the conversion efficiency of HIT solar cells. The higher Voc results in not only a higher conversion efficiency but also an improved temperature coefficient, which is another practical advantage for outdoor use

An approach for the higher efficiency in the HIT cells

The highest conversion efficiency to date of 21.5% (confirmed by AIST) with a size of 100.3 cm/sup 2/ has been achieved in an HIT cell. Because of this high efficiency and the cells superior temperature characteristics, HIT cells are highly regarded by consumers. Sanyo will increase the production volume of cells and modules to meet the demand both inside and outside of Japan. We have been investigating suitable materials based on Sanyos technology for fabricating high-quality a-Si solar cells to obtain higher build-in potential and control the junction properties, and have been studying how to treat the surface to create a good interface without introducing any damage. We will continue our efforts to obtain even higher levels of conversion efficiency by using the high potential that this structure has.

20.7% highest efficiency large area (100.5 cm2) HIT/sup TM/ cell

A world record total area conversion efficiency of 20.7% and high open circuit voltage (VOC) of 719 mV were achieved on a solar cell with HIT (heterojunction with intrinsic thin-layer) structures on both sides (wafer size: 100.5 cm/sup 2/, n-type solar-grade CZ-Si). This solar cell was fabricated with the same process as that used in our mass-production lines. The essence of this high performance is derived from the excellent passivation ability of the HIT structure on c-Si. This report discusses research for excess of 20% efficiency HIT cell (/spl sim/100 cm/sup 2/), focusing on the a-Si passivation effect estimated from the carrier lifetime, and describes product development for the industrialization of HIT cells.

Excellent power-generating properties by using the HIT structure

We are developing HIT solar cells with high conversion efficiency, which was achieved the worlds highest conversion efficiency of 22.3% in a practical size solar cell in July 2007. We have four main approaches to reducing power-generating cost: improve the conversion efficiency, apply the HIT structure to a thin wafer, improve the temperature coefficient, and apply HIT solar cells to a bifacial solar module. Using these approaches, we have achieved the remarkably high conversion efficiency of 21.4% due to a high Voc of 0.739 V with an 85-μm cell, which was measured at SANYO. A thinner Si wafer brings not only high Voc but also generating more output power at high temperature for a better temperature coefficient. We have confirmed that the HIT structure is suitable for use in thinner wafers, allowing us to reduce power-generating cost.

High-efficiency HIT solar cells with a very thin structure enabling a high Voc

To increase the competitiveness of HIT (Heterojunction with Intrinsic Thin-layer) solar cells, we have been working on the enhancing their conversion efficiency. This time, we improved the heterojunction of the HIT solar cell, which made it possible to enhance the cell conversion efficiency. In addition, we have developed module technologies such as a new tab design and anti-reflection coated glass. By combining these technologies, we have achieved 240-W model with module conversion efficiency of 19.0%. Those HIT solar cells have the worlds highest level of cell conversion efficiency 21.6 % at the mass-production stage. We have also been investigating the performance of thinner HIT solar cell using crystalline silicon (c-Si) wafers less than 100 μm in thickness. To minimize optical losses, such as the ultraviolet light absorption in the front transparent conductive oxide (TCO) layer and amorphous Si (a-Si) layers, and the near-infrared light absorption in the rear TCO layer, we have improved the deposition conditions of a-Si, and developed the TCO material respectively. To improve the surface passivation quality of the a-Si/c-Si heterointerface, we have examined our fabrication process from these three viewpoints: (1) the cleanliness of the c-Si surface, (2) the damage in the deposition process, and (3) the quality of the deposited a-Si layer. As a result, we have achieved an excellent Voc of 0.747 V with 58- and 75-μm-thick cells.

High-performance HIT solar cells for thinner silicon wafers

We have been researching and developing HIT (Heterojunction with Intrinsic Thin-layer) solar cells to obtain high conversion efficiency. Last year, we updated the worlds highest conversion efficiency, which was previously 22.3%, to 23.0% with a practical-sized HIT solar cell at the R&D stage. We have also been investigating the performance of thinner HIT solar cells using less than 100-µm-thick crystalline Si (c-Si) wafers in order to effectively reduce the production cost. By using improved technologies, we succeeded in gaining the high conversion efficiency of 22.8% in a HIT solar cell with a 98-µm-thick c-Si wafer and an excellent Voc of 743 mV at the R&D stage. The accomplishment of the 22.8% cell demonstrates that HIT solar cells are advantageous to the use of thinner Si wafers because of certain HIT solar cell features.

High-Efficiency HIT Solar Cells for Excellent Power Generating Properties

In order to achieve the widespread use of HIT (Hetero-junction with I etero-Intrinsic T ntrinsic Thin-layer) solar cells, it is important to reduce the power generating cost. There are three main approaches for reducing this cost: raising the conversion efficiency of the HIT cell, using a thinner wafer to reduce the wafer cost, and raising the open circuit voltage to obtain a better temperature coefficient. With the first approach, we have achieved the highest conversion efficiency values of 22.3%, confirmed by AIST, in a HIT solar cell. This cell has an open circuit voltage of 0.725 V, a short circuit current density of 38.9 mA/cm 2 and a fill factor of 0.791, with a cell size of 100.5 cm 2 . The second approach is to use thinner Si wafers. The shortage of Si feedstock and the strong requirement of a lower sales price make it necessary for solar cell manufacturers to reduce their production cost. The wafer cost is an especially dominant factor in the production cost. In order to provide low-priced, high-quality solar cells, we are trying to use thinner wafers. We obtained a conversion efficiency of 21.4% (measured by Sanyo) for a HIT solar cell with a thickness of 85μm. Even better, there was absolutely no sagging in our HIT solar cell because of its symmetrical structure. The third approach is to raise the open circuit voltage. We obtained a remarkably higher Voc of 0.739 V with the thinner cell mentioned above because of its low surface recombination velocity. The high Voc results in good temperature properties, which allow it to generate a large amount of electricity at high temperatures.