Honghao Hou

Reversible Diels–Alder Reaction To Control Wrinkle Patterns: From Dynamic Chemistry to Dynamic Patterns

A facile and robust strategy to produce a reversible wrinkle pattern is presented by controlling a dynamic D-A reaction between furan and maleimide. The smart surface with highly reversible morphology and tunable adhesion, wettability, self-healing, and transparency is realized by the thermoreversible generation and erasure of the wrinkle pattern, which might find broad applications in functional intelligent materials with properties that can be tuned on-demand without altering the materials intrinsic properties.

Simultaneous Formation of a Self-Wrinkled Surface and Silver Nanoparticles on a Functional Photocuring Coating.

Bioinspired functional surface with micro/nanostructures are particularly attractive because of the potential for outstanding characteristics, such as self-cleaning, self-replenishing and antibiosis. Here, we presented a facile approach to fabricate a functional photocuring coating with both a self-wrinkling patterned surface and incorporated silver nanoparticles (Ag NPs). Fluorinated polymeric photoinitiator (FPPI) and silver precursor (TFAAg) can self-assemble together on the air/acrylate interface to form a top layer of photocuring liquid resin. Under UV irradiation, a wrinkled pattern was formed as a result of the mismatch in shrinkage caused by photopolymerization between the top layer and the bulk layer. Simultaneously, Ag NPs with sizes of 15 ± 8 nm in diameter were in situ generated in the photocuring coating through the photoreduction of TFAAg. Their number density is higher in the top layer than in the bulk. Scanning electron microscope (SEM) and atomic force microscope (AFM) measurements revealed that the characteristic wavelength (λ) and amplitude (A) of the wrinkled morphology increased with growing concentration of FPPI, and that the generation of Ag NPs led to the wrinkle-to-fold transition. Furthermore, the obtained functional coatings possess a low surface energy and self-replenishing and antibiosis capabilities as a result of the synergistic effect of the wrinkled surface covered by FPPI and Ag NPs.

Light-reversible hierarchical patterns by dynamic photo-dimerization induced wrinkles

Hierarchical patterns are playing an increasing role for various fields due to their integrated functions. Herein we created a novel library of multi-scale complex patterns where hierarchical wrinkles can be dynamically generated and eliminated by in situ photo-control. Atom Force Microscopy (AFM) results and UV-vis kinetics manifest that the change of surface modulus induced by dynamic photo-dimerization of the anthracene-containing polymer (PAN) top-layer plays a crucial role in triggering the morphology switch of the resulting wrinkled surface with self-healing, tunable adhesion and wettability properties. Based on the temporal and spatial characteristics of dynamic photo-dimerization, the ordered and hierarchical patterns can be obtained through adapting selective exposure and photolithography. Furthermore, a series of hierarchical patterns in which the smaller-scale wrinkles can be prescriptively generated on the assigned micro-pillar arrays, making up sets of Braille characters, was demonstrated for Braille text refreshable typography through photo-reversible formation and erasure. This novel and effective approach for photoreversible hierarchical wrinkle patterns offers great promise for smart devices and surfaces with dynamic tunable morphology and surface properties on demand in response to light stimuli without altering the bulk properties.

Near-infrared light–responsive dynamic wrinkle patterns

NIR-responsive dynamic wrinkles with excellent reversibility and sensitivity are presented for the first time. Dynamic micro/nanopatterns provide an effective approach for on-demand tuning of surface properties to realize a smart surface. We report a simple yet versatile strategy for the fabrication of near-infrared (NIR) light–responsive dynamic wrinkles by using a carbon nanotube (CNT)–containing poly(dimethylsiloxane) (PDMS) elastomer as the substrate for the bilayer systems, with various functional polymers serving as the top stiff layers. The high photon-to-thermal energy conversion of CNT leads to the NIR-controlled thermal expansion of the elastic CNT-PDMS substrate, resulting in dynamic regulation of the applied strain (ε) of the bilayer system by the NIR on/off cycle to obtain a reversible wrinkle pattern. The switchable surface topological structures can transfer between the wrinkled state and the wrinkle-free state within tens of seconds via NIR irradiation. As a proof-of-concept application, this type of NIR-driven dynamic wrinkle pattern was used in smart displays, dynamic gratings, and light control electronics.

Polymerization-Induced Growth of Microprotuberance on the Photocuring Coating

Surface pattern on the nano- and microscale is of great interest due to its special optical effect, which might find potential application in optical devices such as LCD display, packaging of LED chip, and thin-film solar cell. We here developed a facile bottom-up approach to fabricate microprotuberance (MP) on surface by using curable resin via sequential photocuring at room temperature and thermal polymerization at high temperature. The curable resin is composed of random fluorinated polystyrene (PSF) as blinder and trimethylolpropane trimethacrylate (TMPTA) as cross-linker. The polymerization of TMPTA during the annealing process at high temperature induces phase separation between the PSF and TMPTA cross-linked network, resulting in the extrusion of PSF and the formation of protuberance on the surface. The formation mechanism of MP was studied in detail by investigating the effect of annealing time, temperature, thickness of film, and PSF on the size and morphology. MPs with size from one to tens of micrometers were fabricated through this one-pot strategy. Moreover, encapsulation of integrated GaN/InGaN-based LED chip by the cross-linked coating with MP can enhance the light extraction efficiency and light diffusion obviously.

Reversible Surface Patterning by Dynamic Crosslink Gradients: Controlling Buckling in 2D

Harnessing the self-organization of soft materials to make complex, well-ordered surface patterns in a noninvasive manner is challenging. The wrinkling of thin films provides a compelling strategy to achieve this. Despite much attention, however, a simple, single-step, reversible method that gives rise to controlled, two-dimensional (2D) ordered, continuous, and discontinuous patterns has proven to be elusive. Here a novel, robust method is described to achieve this using an ultraviolet-light-sensitive anthracene-containing polymer thin film. The origin of the patterns is the local buckling of the thin film, where the control over the topology is given by laterally patterning out-of-plane gradients in the crosslink density of the film. The underlying buckling mechanics and formation of the surface features are well-described by finite element analysis. By illuminating the film with a photomask, local and long-range patterns that can be both continuous and discontinuous are able to be written. Furthermore, the patterning is fully reversible over multiple cycles. The results demonstrate a simple strategy for erasable storage of information in a surface topography that has applications in memory, anticounterfeiting, and plasmonics.