Hoon k Seo

Air stable, ambipolar organic transistors and inverters based upon a heterojunction structure of pentacene on N,N′-ditridecylperylene-3,4,9,10-tetracarboxylic di-imide

In this paper, we report on the fabrication and electrical characterization of top-contact, ambipolar organic field-effect transistors (OFETs) and inverters based upon a heterostructure of p-type pentacene on n-type N,N′-ditridecylperylene-3,4,9,10-tetracarboxylic di-imide (P13), using the neutral cluster beam deposition (NCBD) method. The device characteristics measured as a function of both P13 and pentacene layer thicknesses revealed that OFETs with thicknesses of P13 (300 A) and pentacene (200 A) showed high air-stability and well-balanced ambipolarity with hole and electron mobilities of 0.12 and 0.08 cm2/V s. The complementary inverters, comprising two identical ambipolar OFETs, were found to operate both in the first and third quadrants of the transfer curves and exhibited a high voltage inversion gain of 13, good noise margins, and little hysteresis under ambient conditions. The results presented demonstrate that the NCBD-based ambipolar transistors and inverters qualify them as promising potentia...

Performance and transport characteristics of α,ω-dihexylsexithiophene- based transistors with a high room-temperature mobility of 0.16cm2∕Vs

Organic thin-film transistors (OTFTs) based upon α,ω-dihexylsexithiophene (DH6T) have been fabricated and characterized. The DH6T thin films were prepared using neutral cluster beam deposition (NCBD) methods on room-temperature SiO2 substrates. The effects of surface modification were examined. The geometric effects of the gate dielectric thickness, channel length, and width on the device characteristics were also systematically studied. A combination of the NCBD technique and octadecyltrichlorosilane (OTS) pretreatment was most efficient for producing high-quality crystalline DH6T films. The temperature dependence of the field-effect mobility (μeff) indicated that the transistor performance was strongly correlated with the structural and morphological properties of the DH6T active layers and that the surfactant pretreatment significantly enhanced the μeff. A room-temperature μeff of 0.16cm2∕Vs for the OTS-pretreated transistors was found to be best so far reported for DH6T-based OTFTs using a SiO2 gate d...

Study on copper phthalocyanine and perylene-based ambipolar organic light-emitting field-effect transistors produced using neutral beam deposition method

The neutral cluster beam deposition (NCBD) method has been applied to the production and characterization of ambipolar, heterojunction-based organic light-emitting field-effect transistors (OLEFETs) with a top-contact, multi-digitated, long-channel geometry. Organic thin films of n-type N,N′-ditridecylperylene-3,4,9,10-tetracarboxylic diimide and p-type copper phthalocyanine were successively deposited on the hydroxyl-free polymethyl-methacrylate (PMMA)-coated SiO2 dielectrics using the NCBD method. Characterization of the morphological and structural properties of the organic active layers was performed using atomic force microscopy and X-ray diffraction. Various device parameters such as hole- and electron-carrier mobilities, threshold voltages, and electroluminescence (EL) were derived from the fits of the observed current-voltage and current-voltage-light emission characteristics of OLEFETs. The OLEFETs demonstrated good field-effect characteristics, well-balanced ambipolarity, and substantial EL unde...

Influence of gate dielectrics on the performance of single-layered organic transistors and bi-layered organic light-emitting transistors prepared by the neutral cluster beam deposition method

The influence of two different SiO2 and polymethylmethacrylate (PMMA) gate dielectrics on the performance of single-layered organic field-effect transistors and bi-layered organic light-emitting field-effect transistors was examined. Organic active layers of p-type α,ω-dihexylsexithiophene and n-type N,N′-ditridecylperylene-3,4,9,10-tetracarboxylic diimide were prepared using the neutral cluster beam deposition method. Characterization of surface morphology, contact angles, structural properties and temperature dependence of field-effect mobilities measured over the temperature range of 10–300 K revealed that compared to the SiO2 dielectrics, the hydroxyl-free PMMA dielectrics provided better conditions for crystalline film growth. The PMMA-based device characteristics exhibited excellent field-effect mobilities, stress-free operational stability, and electroluminescence through efficient carrier transport and well-balanced ambipolarity under ambient conditions.

ZrO2 dielectric-based low-voltage organic thin-film inverters

In this paper, the authors first report ZrO2-dielectric based low-voltage organic thin-film complementary metal-oxide semiconductor inverters. Two active layers of p-type pentacene and n-type N,N′-dioctyl-3,4,9,10-perylenedicarboximide were successively deposited on the thermally stable, transparent ZrO2 using the neutral cluster beam deposition method. Based on the good balance between p- and n-type transistors, the complementary inverters exhibited ideal characteristics including sharp inversions, complete switching, high gains, and large voltage swings at low operating voltage levels.