How Wei Benjamin Teo

Adsorption Characteristics of Modified MiL-101(Cr) for Gas (Mainly CH4) Storage Applications

As promising material for gas storage applications, MIL-101(Cr) can further be modified by doping with alkali metal (Li+, Na+, K+) ions. However, the doping concentration should be optimized below 10% to improve the methane adsorption. This article presents (i) the synthesis of MIL-101 (Cr) Metal Organic Frameworks, (ii) the characterization of the proposed doped adsorbent materials by X-ray Diffraction, Scanning Electron Microscopy, N2 Adsorption, Thermo-Gravimetric Analyzer, and (iii) the measurements of methane uptakes for the temperatures ranging from 125 K to 303 K and pressures up to 10 bar. It is found that the Na+ doped MIL-101(Cr) exhibits CH4 uptake capacity of (i) 295 cm3/cm3 at 10 bar and 160 K and (ii) 95 cm3/cm3 at 10 bar at 298 K. This information is important to design adsorbed natural gas (ANG) storage tank under ANG-LNG (liquefied natural gas) coupling conditions.Copyright

Study of Waste Heat Driven Adsorption Cooling System Employing Doped MiL-101(Cr) and Water as Adsorbent Adsorbate Pair

This article presents the dynamic behaviors of two bed adsorption chiller utilizing the composite adsorbent “immobilization of NH2, -NO2, -OH groups to MiL-101(Cr)” as adsorbent and water as adsorbate, which is based on the experimentally confirmed adsorption isotherms and kinetics data. The experimentally measured MOFs + water based isotherms and kinetics data are fitted with adsorption isotherm models and linear driving force kinetics equations. Compared with the experimental data of conventional adsorption chiller based on zeolites/silica gel-water system, we found that the newly working pair provides better cooling capacity and performances in terms of COP and adsorption bed size. From numerical simulation, it is also found that the cooling capacity can be increased up to 20 percent of the parent silica gel-water adsorption chiller and the COP can be improved up to 25% more at optimum conditions.Copyright