Hyun-Cheol Song

Lead-free epitaxial ferroelectric material integration on semiconducting (100) Nb-doped SrTiO3 for low-power non-volatile memory and efficient ultraviolet ray detection

We report lead-free ferroelectric based resistive switching non-volatile memory (NVM) devices with epitaxial (1-x)BaTiO3-xBiFeO3 (x = 0.725) (BT-BFO) film integrated on semiconducting (100) Nb (0.7%) doped SrTiO3 (Nb:STO) substrates. The piezoelectric force microscopy (PFM) measurement at room temperature demonstrated ferroelectricity in the BT-BFO thin film. PFM results also reveal the repeatable polarization inversion by poling, manifesting its potential for read-write operation in NVM devices. The electroforming-free and ferroelectric polarization coupled electrical behaviour demonstrated excellent resistive switching with high retention time, cyclic endurance, and low set/reset voltages. X-ray photoelectron spectroscopy was utilized to determine the band alignment at the BT-BFO and Nb:STO heterojunction, and it exhibited staggered band alignment. This heterojunction is found to behave as an efficient ultraviolet photo-detector with low rise and fall time. The architecture also demonstrates half-wave rectification under low and high input signal frequencies, where the output distortion is minimal. The results provide avenue for an electrical switch that can regulate the pixels in low or high frequency images. Combined this work paves the pathway towards designing future generation low-power ferroelectric based microelectronic devices by merging both electrical and photovoltaic properties of BT-BFO materials.

A Review on Piezoelectric Energy Harvesting: Materials, Methods, and Circuits

Abstract Piezoelectric microelectromechanical systems (PiezoMEMS) are attractive for developing next generation self-powered microsystems. PiezoMEMS promises to eliminate the costly assembly for microsensors/microsystems and provide various mechanisms for recharging the batteries, thereby, moving us closer towards batteryless wireless sensors systems and networks. In order to achieve practical implementation of this technology, a fully assembled energy harvester on the order of a quarter size dollar coin (diameter=24.26 mm, thickness=1.75 mm) should be able to generate about 100 μW continuous power from low frequency ambient vibrations (below 100 Hz). This paper reviews the state-of-the-art in microscale piezoelectric energy harvesting, summarizing key metrics such as power density and bandwidth of reported structures at low frequency input. This paper also describes the recent advancements in piezoelectric materials and resonator structures. Epitaxial growth and grain texturing of piezoelectric materials is being developed to achieve much higher energy conversion efficiency. For embedded medical systems, lead-free piezoelectric thin films are being developed and MEMS processes for these new classes of materials are being investigated. Non-linear resonating beams for wide bandwidth resonance are also reviewed as they would enable wide bandwidth and low frequency operation of energy harvesters. Particle/granule spray deposition techniques such as aerosol-deposition (AD) and granule spray in vacuum (GSV) are being matured to realize the meso-scale structures in a rapid manner. Another important element of an energy harvester is a power management circuit, which should maximize the net energy harvested. Towards this objective, it is essential for the power management circuit of a small-scale energy harvester to dissipate minimal power, and thus it requires special circuit design techniques and a simple maximum power point tracking scheme. Overall, the progress made by the research and industrial community has brought the energy harvesting technology closer to the practical applications in near future.

Thermo-Magneto-Electric Generator Arrays for Active Heat Recovery System

Continued emphasis on development of thermal cooling systems is being placed that can cycle low grade heat. Examples include solar powered unmanned aerial vehicles (UAVs) and data storage servers. The power efficiency of solar module degrades at elevated temperature, thereby, necessitating the need for heat extraction system. Similarly, data centres in wireless computing system are facing increasing efficiency challenges due to high power consumption associated with managing the waste heat. We provide breakthrough in addressing these problems by developing thermo-magneto-electric generator (TMEG) arrays, composed of soft magnet and piezoelectric polyvinylidene difluoride (PVDF) cantilever. TMEG can serve dual role of extracting the waste heat and converting it into useable electricity. Near room temperature second-order magnetic phase transition in soft magnetic material, gadolinium, was employed to obtain mechanical vibrations on the PVDF cantilever under small thermal gradient. TMEGs were shown to achieve high vibration frequency at small temperature gradients, thereby, demonstrating effective heat transfer.

Correlation between tunability and anisotropy in magnetoelectric voltage tunable inductor (VTI)

Electric field modulation of magnetic properties via magnetoelectric coupling in composite materials is of fundamental and technological importance for realizing tunable energy efficient electronics. Here we provide foundational analysis on magnetoelectric voltage tunable inductor (VTI) that exhibits extremely large inductance tunability of up to 1150% under moderate electric fields. This field dependence of inductance arises from the change of permeability, which correlates with the stress dependence of magnetic anisotropy. Through combination of analytical models that were validated by experimental results, comprehensive understanding of various anisotropies on the tunability of VTI is provided. Results indicate that inclusion of magnetic materials with low magnetocrystalline anisotropy is one of the most effective ways to achieve high VTI tunability. This study opens pathway towards design of tunable circuit components that exhibit field-dependent electronic behavior.

Engineered domain configuration and piezoelectric energy harvesting in 0.7Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 single crystals

The performance of cantilever piezoelectric energy harvesters using three types of piezoelectric materials, relaxor ferroelectric 0.7Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 (PMN-PT) single crystals oriented along the 〈110〉 and 〈001〉 directions, and a PZT-based ceramic, were investigated. The 〈110〉 and 〈001〉 oriented PMN-PT single crystals, which have a rhombohedral phase and spontaneous polarization along the 〈111〉 direction, presented electromechanical coupling factor k31’s of 0.78 and 0.42, respectively. The cantilever-type energy harvester operated by 31 resonance mode generated a larger output power of 1.07 mW for the 〈110〉 oriented PMN-PT single crystal compared to those of the other materials. The effective electromechanical coupling factor of the piezoelectric energy harvester with the 〈110〉 oriented crystal also reached 0.25, not achievable with the other piezoelectric materials. These results demonstrate that the domain engineering of the piezoelectric single crystals can provide higher design flexibility for a tiny energy harvester.

Soft phonon mode dynamics in Aurivillius-type structures

We report the dynamics of soft phonon modes and their role towards the various structural transformations in Aurivillius materials by employing terahertz frequency-domain spectroscopy, atomic pair distribution function analysis, and first-principles calculations. We have chosen Bi4Ti3O12 as a model system and identified soft phonon modes associated with the paraelectric tetragonal to the ferroelectric monoclinic transition. Three soft phonon modes have been discovered which exhibit a strong temperature dependence. We have determined that the anharmonicity in Bi-O bonds plays a significant role in phonon softening and that Bi cations play an important role in the emergence of ferroelectricity.

Frequency tuning of unimorph cantilever for piezoelectric energy harvesting

Thin Film Materials Research Center, Korea Institute of Science & Technology, Cheongryang, Seoul 130-650, Korea*School of Electrical Engineering, College of Engineering, Korea Univ. Korea(2007 9 21 :2007 12 6 )Abstract Piezoelectric energy harvesting from our surrounding vibration has been studied for driving thewireless sensor node. To change the vibration energy into the electric-energy efficiently, the natural frequency ofcantilever needs to be adjusted to that of a vibration source. When adding 6.80g mass on the end of the fabricatedcantilever, a natural frequency shifts from 136 Hz into 49.5 Hz. In addition, electro-mechanical coupling factorincreased from 10.20% to 11.90% and resulted in the 1.18 times increase of maximum output power.Key wordsEnergy harvesting, Piezoelectric, Frequency tuning.

Enhanced Self-Biased Magnetoelectric Coupling in Laser-Annealed Pb(Zr,Ti)O3 Thick Film Deposited on Ni Foil

Enhanced and self-biased magnetoelectric (ME) coupling is demonstrated in a laminate heterostructure comprising 4 μm-thick Pb(Zr,Ti)O3 (PZT) film deposited on 50 μm-thick flexible nickel (Ni) foil. A unique fabrication approach, combining room temperature deposition of PZT film by granule spray in vacuum (GSV) process and localized thermal treatment of the film by laser radiation, is utilized. This approach addresses the challenges in integrating ceramic films on metal substrates, which is often limited by the interfacial chemical reactions occurring at high processing temperatures. Laser-induced crystallinity improvement in the PZT thick film led to enhanced dielectric, ferroelectric, and magnetoelectric properties of the PZT/Ni composite. A high self-biased ME response on the order of 3.15 V/cm·Oe was obtained from the laser-annealed PZT/Ni film heterostructure. This value corresponds to a ∼2000% increment from the ME response (0.16 V/cm·Oe) measured from the as-deposited PZT/Ni sample. This result is also one of the highest reported values among similar ME composite systems. The tunability of self-biased ME coupling in PZT/Ni composite has been found to be related to the demagnetization field in Ni, strain mismatch between PZT and Ni, and flexural moment of the laminate structure. The phase-field model provides quantitative insight into these factors and illustrates their contributions toward the observed self-biased ME response. The results present a viable pathway toward designing and integrating ME components for a new generation of miniaturized tunable electronic devices.

Compositionally Graded Multilayer Ceramic Capacitors

Multilayer ceramic capacitors (MLCC) are widely used in consumer electronics. Here, we provide a transformative method for achieving high dielectric response and tunability over a wide temperature range through design of compositionally graded multilayer (CGML) architecture. Compositionally graded MLCCs were found to exhibit enhanced dielectric tunability (70%) along with small dielectric losses (<2.5%) over the required temperature ranges specified in the standard industrial classifications. The compositional grading resulted in generation of internal bias field which enhanced the tunability due to increased nonlinearity. The electric field tunability of MLCCs provides an important avenue for design of miniature filters and power converters.

Temperature Dependences of Piezoelectric and Linear Electrooptic Properties of Rhombohedral 0.67Pb(Mg1/3Nb2/3)O3–0.33PbTiO3 Single Crystal Oriented in Direction

We characterized the temperature dependences of the linear electrooptical (E-O) and piezoelectric coefficients of the rhombohedral 0.67Pb(Mg1/3Nb2/3)O3–0.33PbTiO3 single crystals oriented along the direction (the spontaneous polarization direction). The E-O coefficients of the 0.67PMN–0.33PT single crystals were r333=107 pm/V at room temperature and 950 pm/V at 80 °C. The piezoelectric coefficient d311 of the 0.67PMN–0.33PT single crystals increased from 45 pC/N at room temperature to 1015 pC/N at 80 °C. Large E-O and piezoelectric coefficients at 80 °C were from the engineering domain configuration induced by a transition from the rhombohedral phase othorhombic phase.