I. Tobías

Plasmonic light enhancement in the near-field of metallic nanospheroids for application in intermediate band solar cells

In order to enhance infrared light absorption in sub-bandgap transitions in an intermediate band solar cell, the scattered near-field potential from uncoated and coated metallic nanoparticles with a spheroidal shape is calculated with the electrostatic model. The absorption enhancement produced at the surface plasmon frequency of the nanoparticles can be of several orders of magnitude in some cases.

Light intensity enhancement by diffracting structures in solar cells

A simplified three-dimensional study is presented of the light confinement, that is, of the enhancement of the Poynting vector of the electromagnetic radiation of the light inside a solar cell absorbing the light weakly when diffracting structures are used. The model is based on the theory of periodic radiation arrays and is easily applied to one- and two-dimensional diffraction gratings. Realistically wide illumination bundles are considered. The extended nature of illumination severely limits the enhancement capabilities of diffraction structures. Results are compared to those of the more widely used Lambertian light confinement.

Nanoimprinted diffraction gratings for crystalline silicon solar cells: implementation, characterization and simulation

Light trapping is becoming of increasing importance in crystalline silicon solar cells as thinner wafers are used to reduce costs. In this work, we report on light trapping by rear-side diffraction gratings produced by nano-imprint lithography using interference lithography as the mastering technology. Gratings fabricated on crystalline silicon wafers are shown to provide significant absorption enhancements. Through a combination of optical measurement and simulation, it is shown that the crossed grating provides better absorption enhancement than the linear grating, and that the parasitic reflector absorption is reduced by planarizing the rear reflector, leading to an increase in the useful absorption in the silicon. Finally, electro-optical simulations are performed of solar cells employing the fabricated grating structures to estimate efficiency enhancement potential.

Random pyramidal texture modelling

Abstract A simple model of random pyramidal texture is presented here for its implementation on a ray tracing program. Several simulations have been done in which it has been studied how the distribution of sizes of pyramids affects the reflectivity. On the basis of this model wafers with front and/or back textured faces are analyzed leading to the conclusion that no metal coating is necessary for a strong confinement of the light.

Self-organized colloidal quantum dots?and metal nanoparticles for plasmon-enhanced intermediate-band solar cells

A colloidal deposition technique is presented to construct long-range ordered hybrid arrays of self-assembled quantum dots and metal nanoparticles. Quantum dots are promising for novel opto-electronic devices but, in most cases, their optical transitions of interest lack sufficient light absorption to provide a significant impact in their implementation. A potential solution is to couple the dots with localized plasmons in metal nanoparticles. The extreme confinement of light in the near-field produced by the nanoparticles can potentially boost the absorption in the quantum dots by up to two orders of magnitude.In this work, light extinction measurements are employed to probe the plasmon resonance of spherical gold nanoparticles in lead sulfide colloidal quantum dots and amorphous silicon thin-films. Mie theory computations are used to analyze the experimental results and determine the absorption enhancement that can be generated by the highly intense near-field produced in the vicinity of the gold nanoparticles at their surface plasmon resonance.The results presented here are of interest for the development of plasmon-enhanced colloidal nanostructured photovoltaic materials, such as colloidal quantum dot intermediate-band solar cells.

Understanding the operation of quantum dot intermediate band solar cells

In this paper, a model for intermediate band solar cells is built based on the generally understood physical concepts ruling semiconductor device operation, with special emphasis on the behavior at low temperature. The model is compared to JL-VOC measurements at concentrations up to about 1000 suns and at temperatures down to 20 K, as well as measurements of the radiative recombination obtained from electroluminescence. The agreement is reasonable. It is found that the main reason for the reduction of open circuit voltage is an operational reduction of the bandgap, but this effect disappears at high concentrations or at low temperatures.In this paper, a model for intermediate band solar cells is built based on the generally understood physical concepts ruling semiconductor device operation, with special emphasis on the behavior at low temperature. The model is compared to JL-VOC measurements at concentrations up to about 1000 suns and at temperatures down to 20 K, as well as measurements of the radiative recombination obtained from electroluminescence. The agreement is reasonable. It is found that the main reason for the reduction of open circuit voltage is an operational reduction of the bandgap, but this effect disappears at high concentrations or at low temperatures.

Near-field scattering by dielectric spheroidal particles with sizes on the order of the illuminating wavelength

We present a theoretical study of electric field scattering by wavelength-sized spheroids. The incident, internal, and scattered fields are computed analytically by a spheroidal coordinate separation-of-variables solution, assuming axially incident monochromatic illumination. The main sources of possible numerical errors are identified and an additional point-matching procedure is implemented to provide a built-in test of the validity of the results. Numerical results were obtained for prolate and oblate particles with particular aspect ratios and sizes, and a refractive index of 1.33 relative to the surrounding medium. Special attention is paid to the characteristics of the near-field in close proximity to the spheroids. It is shown that particles with sizes close to the incident wavelength can produce high field enhancements whose spatial location and extension can be controlled by the particle geometry.

Radiative thermal escape in intermediate band solar cells

To achieve high efficiency, the intermediate band (IB) solar cell must generate photocurrent from sub-bandgap photons at a voltage higher than that of a single contributing sub-bandgap photon. To achieve the latter, it is necessary that the IB levels be properly isolated from the valence and conduction bands. We prove that this is not the case for IB cells formed with the confined levels of InAsquantum dots(QDs) in GaAs grown so far due to the strong density of internal thermal photons at the transition energies involved. To counteract this, the QD must be smaller.

Light absorption in the near field around surface plasmon polaritons

A semiclassical method is developed to calculate the energy absorption of an electronic system located in the near field of a metal nanoparticle sustaining surface plasmons. The results are found to be similar to those of photon absorption from ordinary transversal radiation. However, they are affected by a geometrical factor that can increase the absorption by several orders of magnitude. As example, we investigate ellipsoidal-shaped metal nanoparticles which, under favorable conditions, may provide near field aborption enhancements almost as large as 104, and in many cases above 10.

The influence of quantum dot size on the sub-bandgap intraband photocurrent in intermediate band solar cells

The effect of quantum dot (QD) size on the performance of quantum dot intermediate band solar cells is investigated. A numerical model is used to calculate the bound state energy levels and the absorption coefficient of transitions from the ground state to all other states in the conduction band. Comparing with the current state of the art, strong absorption enhancements are found for smaller quantum dots, as well as a better positioning of the energy levels, which is expected to reduce thermal carrier escape. It is concluded that reducing the quantum dot size can increase sub-bandgap photocurrent and improve voltage preservation.