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Ian H. Smith

University of California, Berkeley

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Tetrahedron Letters | 1981

Epoxychrysahthemic acid as an intermediate in metabolic decarboxylation of chrysanthemate insecticides

Ian H. Smith; John E. Casida

Abstract Epoxychrysanthemic acid undergoes rapid decarboxylatlon in aqueous medium at physiological pH to form a ring-opened dienol. Epoxychrysanthemates degrade in dilute acid to cyclopropane ring-opened diols. Metabolic decarboxylation of tetramethrin ( 1 ) and related chrysanthemate insecticides involves sequential enzymatic isobutenyl epoxidation, hydrolysis of the epoxychrysanthemate, and a nonenzymatic concerted decarboxylation and oxirane-ring opening reaction.

Journal of Agricultural and Food Chemistry | 1991

1-(4-ethynylphenyl)-4-substituted-2,6,7-trioxabicyclo[2.2.2.]octanes : effect of 4-substituent on toxicity to houseflies and mice and potency at the GABA-gated chloride channel

Christopher J. Palmer; Loretta M. Cole; John P. Larkin; Ian H. Smith; John E. Casida

Journal of Agricultural and Food Chemistry | 1982

Pyrethroid photochemistry: photooxidation reactions of the chrysanthemates phenothrin and tetramethrin

Luis O. Ruzo; Ian H. Smith; John E. Casida

Journal of Agricultural and Food Chemistry | 1982

Glutathione conjugate of the pyrethroid tetramethrin

Ian H. Smith; Edgardo Wood; John E. Casida

Journal of Agricultural and Food Chemistry | 1991

Silylated 1-(4-ethynylphenyl)-2,6,7-trioxabicyclo[2.2.2]octanes: structural features and mechanisms of proinsecticidal action and selective toxicity

Christopher J. Palmer; Loretta M. Cole; Ian H. Smith; Matthew D. V. Moss; John E. Casida

Journal of Agricultural and Food Chemistry | 1990

1-[4-[(Trimethylsilyl)ethynyl]phenyl]-2,6,7-trioxabicyclo[2.2.2]octanes: a novel type of selective proinsecticide.

Christopher J. Palmer; Ian H. Smith; Matthew D. V. Moss; John E. Casida

Journal of Agricultural and Food Chemistry | 1993

Insecticidal 1-(alkynylalkyl)-3-cyano-2,6,7-trioxabicyclo[2.2.2]octanes

Ian H. Smith; Timothy C. Budd; Jill. Sills; John E. Casida

Archive | 1994

Trithiabicyclo[2,2,2]octanes

John E. Casida; Christopher J. Palmer; John P. Larkin; Ian H. Smith

Archive | 1989

Composés chimiques leurs procédés et intermédiaires de fabrication formulations pesticides les contenant et procédés les utilisant pour lutter contre des arthropodes et helminthes nuisibles

John B. Weston; John Patrick Larkin; Ian H. Smith

Archive | 1988

Substituted heterobicyclooctaner, pesticidal compositions containing such compounds, non-therapeutic methods of control of arthropod or worm or infestation by pests and processes for preparing the compounds

John B. Weston; John Patrick Larkin; Ian H. Smith

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John E. Casida

University of California

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Christopher J. Palmer

University of California

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Loretta M. Cole

University of California

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Luis O. Ruzo

Hebrew University of Jerusalem

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John B. Weston

University of Nottingham

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John Patrick Larkin

University of Nottingham

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Edgardo Wood

University of California

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John P. Larkin

Roussel Uclaf

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