Ian Jacobi

Controlled Uniform Coating from the Interplay of Marangoni Flows and Surface-Adsorbed Macromolecules.

Surface coatings and patterning technologies are essential for various physicochemical applications. In this Letter, we describe key parameters to achieve uniform particle coatings from binary solutions. First, multiple sequential Marangoni flows, set by solute and surfactant simultaneously, prevent nonuniform particle distributions and continuously mix suspended materials during droplet evaporation. Second, we show the importance of particle-surface interactions that can be established by surface-adsorbed macromolecules. To achieve a uniform deposit in a binary mixture, a small concentration of surfactant and surface-adsorbed polymer (0.05 wt% each) is sufficient, which offers a new physicochemical avenue for control of coatings.

Experimental manipulation of wall turbulence: a systems approach

We review recent progress, based on the approach introduced by McKeon and Sharma [J. Fluid Mech. 658, 336–382 (2010)10.1017/S002211201000176X], in understanding and controlling wall turbulence. The origins of this analysis partly lie in nonlinear robust control theory, but a differentiating feature is the connection with, and prediction of, state-of-the-art understanding of velocity statistics and coherent structures observed in real, high Reynolds number flows. A key component of this line of work is an experimental demonstration of the excitation of velocity response modes predicted by the theory using non-ideal, but practical, actuation at the wall. Limitations of the approach and promising directions for future development are outlined.

Overflow cascades in liquid-infused substrates

Liquid-infused patterned surfaces offer a promising new platform for generating omniphobic surface coatings. However, the liquid infused in these surfaces is susceptible to shear-driven dewetting. Recent work [Wexler et al., “Shear-driven failure of liquid-infused surfaces,” Phys. Rev. Lett. 114, 168301 (2015)] has shown how the substrate pattern in these surfaces can be designed to exploit capillary forces in order to retain infused lubricants against the action of an immiscible shear flow. In this study, we explore the behavior of the infused lubricant when external shear causes the lubricant to overflow finite or “dead-end” surface features, resulting in either temporary or permanent lubricant loss. Microfluidic experiments illustrate how both geometry and chemical Marangoni stresses within liquid-infused surfaces generate an overflow cascade in which the lubricant escapes from the substrate and forms droplets on the surface, after which the droplets depin and are washed away by the external shear flow...

Variation in polydispersity in pump- and pressure-driven micro-droplet generators

The polydispersity of droplets produced in a typical T-junction microfluidic channel under both syringe-pump-driven and pressure-driven flow configurations is measured quantitatively. Both flow systems exhibit high-frequency flow fluctuations that result in an intrinsic polydispersity due to the mechanism of droplet generation. In addition to this intrinsic polydispersity, the syringe-pump-driven device also exhibits low-frequency fluctuations due to mechanical oscillations of the pump, which overwhelm the high-frequency flow fluctuations and produce a signficantly heightened level of polydispersity. The quantitative difference in polydispersity between the two configurations and time-resolved measurements of individual droplet sizes are presented in order to enable the design of better flow control systems for droplet production.

Stratified thin-film flow in a rheometer

When two immiscible layered fluids are present in a rheometer, interfacial distortions driven by the centripetal pressure gradient can modify torque measurements and induce dewetting. In particular, we examine the steady-state interface shape of a thin film coating a stationary substrate beneath a second immiscible fluid that is driven by a rotating parallel-plate or cone. An asymptotic analysis of the interfacial distortion for the parallel-plate flow is compared with numerical solutions for both the parallel-plate and cone and plate configurations. We develop asymptotic criteria for dewetting of the thin film as a function of fluid and flow properties, and show that significant interfacial distortion and dewetting can occur due to secondary flow effects even at low Reynolds numbers. The distortion of the interface can result in increased or decreased torque measurements depending on the viscosity and density ratios between the two fluid layers. We relate these effects to recent experimental studies on l...

Bénard-Marangoni instability driven by moisture absorption

Glycerol is a viscous liquid widely used in industry and known for its strong hygroscopic nature. While this unusual property has been well documented from the perspective of solution chemistry, its impact on the mechanical properties of glycerol remains largely unknown. Here, we report a spontaneous Benard-Marangoni instability in pure glycerol driven by absorption of water vapor. Even under standard laboratory conditions, ambient humidity is sufficient to drive distinct Benard-Marangoni convection cells for hours. We describe the mechanism of this instability in terms of the vapor transport process and competition between solutal and thermal Marangoni forces, and provide insight into potential uses and impact of this aspect of dynamics driven by moisture absorption in various common settings.

Perturbation of a turbulent boundary layer by spatially-impulsive dynamic roughness

First experimental measurements of manipulation of the structure of a canonical zero pressure gradient turbulent boundary layer using a low frequency (compared to the viscous frequency) mechanical dynamic roughness are presented. “Dynamic” (or time-dependent) surface roughness is proposed as a method for both control and diagnosis of turbulent boundary layers.