Ines D. Donato

Viscosity studies of solutions of water inn-aliphatic alcohols at various temperatures

Viscosity measurements have been made at 25°C on solutions of water inn-propanol, and at 15, 25, 35, and 45°C on solutions of water inn-butanol,n-pentanol, andn-hexanol over the respective solubility ranges. For most of the systems, water decreases the viscosity of the dry alcohols, while for the lower members of the series literature data report an increase in viscosity on addition of water. These results are rationalized in terms of two kinds of interaction between water molecules and alcohols: participation of water molecules in chain formation for the lower alcohols and formation of water-centered complexes for butanol and higher alcohols.

Molecular association and dynamics in n-pentanol and 2-methyl-2-butanol

Static dielectric constant, viscosity, density, ultrasonic and dielectric relaxation measurements are reported for two pentanol isomers (n-pentanol and 2-methyl-2-butanol) in a wide range of temperatures. The results show a different extent of H-bonds self-association in relation to the molecular geometry of the alcohol. The activation energies obtained from dielectric and ultrasonic studies are compared with those obtained from viscous flow. Such a comparison, together with the analysis of all the dielectric and ultrasonic relaxation data, show that in n-pentanol a correlation between viscosity and ultrasonic relaxation exists, while dielectric relaxation is not correlated with the other two processes. This finding has been rationalized in terms of different mechanisms. In 2-methyl-2-butanol a correlation between ultrasonic and dielectric relaxation processes has been observed. Additional contribution of ultrasonic absorption associated with isomeric internal rotational of the molecules has been assumed ...

Molecular interactions in 1-pentanol +2-methyl-2-butanol mixtures: Static dielectric constant, viscosity and refractive index investigations at 5, 25 and 45°C

Static dielectric constants, refractive indices and viscosities of 1-pentanol +2-methyl-2-butanol mixtures were measured at 5, 25 and 45°C. The results show that the mixing of the two isomers modifies the polarizability and the resistence of viscous flow of the system depending on the composition and temperature. Short range intermolecular interactions producing hetero-alcohol open dimers are considered.

Calorimetric investigation of the interaction between α,β-poly(N-hydroxyethyl)-DL-aspartamide and surfactants

Abstract The enthalpic effect due to the interaction between α,β- poly (N- hydroxyethyl )- dl -aspartamide (PHEA) and sodium dodecyl sulfate, cetyltrimethylammonium bromide, and Octylphenoxypolyethoxyethanol in aqueous solutions, as a function of the surfactant concentration, was measured by the Calorimetric technique. Below the critical micellar concentration, no enthalpic effect was measured. At higher concentrations, the enthalpic effect, exothermic for the interaction of PHEA with the anionic micelles and endothermic for that with the cationic and nonionic micelles, was interpreted in terms of the binding of micelles to the polymeric chain. The influence of a simple electrolyte (sodium chloride) on the PHEA-micelle interaction was also investigated and is discussed here.

Calorimetric study on the solubilization of some primary alcohols by reversed AOT micelles

A calorimetric method to evaluate, at the same time, the distribution constant and the standard enthalpy of transfer of a solute partitioned between organic phase and reversed micelles is proposed. The method was applied to the partition of methanol, 1-propanol and 1-pentanol between n-heptane and AOT reversed micelles containing water at 25°C. The results show that the distribution constant decreases as the alcohol alkyl chain length increases and that the solubilization site can change as the water content of reversed AOT micelles increases. In particular, at sufficiently high water content, methanol seems to be preferably solubilized in the aqueous pseudophase whereas 1-pentanol prefers always the palisade layer as site of solubilization.

Volumetric and transport properties of aerosol-OT reversed micelles containing light and heavy water

Densities and viscosities of sodium bis(2-ethylhexyl) sulfosuccinate (AOT in-heptane system containing light and heavy water, as a function of the molar ratio R (R=[H2O or D2O]/[AOT]) were measured at 0, 5, 25 and 40°C. At low R values, the apparent molar volume of deuterium oxide is smaller than that of light water. The difference is related to the strength of the hydrogen bonding H2O and D2O. The viscosities of both H2O-AOT-n-heptane and D2O-AOT-n-heptane systems were explained in terms of intermicellar interactions mainly governed by hydration of the head groups of AOT.

Dielectric polarization and polarizability of 1-pentanol+n-octane mixtures from static dielectric constant and refractive index data at 0,25 and 45°C

Static dielectric constants and refractive indices of 1-pentanol+n-octane mixtures were measured in the temperature range between 0 and 45°C. Data discussed in terms of Kirkwood correlation factor and Lorentz-Lorenz molar refractivity give information on the short range intermolecular interactions between the components. The role played by the nonpolar n-octane in the destruction of 1-pentanol oligomers is also pointed out.

Hydration phenomena and hydrogen bond connectivity in polymeric aqueous solutions

Ultrasonic velocity and density measurements were performed in polymeric aqueous solutions of ethylene glycol (EG) and poly(ethylene glycol) (PEG) as functions of concentration and temperature in the stable liquid region. The non-ideal behaviour of the compressibility allows us to evaluate the hydration number of the polymer as a function of temperature. The experimental data show the presence of an arrangement in which two water molecules are bonded for each oxygen of the oxirane monomeric group.

Calorimetric study of the solubilization of cholesterol, retinol and retinal by reversed AOT micelles

Distribution constants and standard enthalpies of transfer of cholesterol, retinol and retinal partitioned between n-heptane and water containing reversed sodium bis(2-ethylhexyl) sulfosuccinate (AOT) micelles as a function of the molar concentration ratio (R=[water]/[AOT]) were evaluated by a calorimetric method. The results indicate that, in spite of the bulky hydrocarbon radical, these solubilizates behave like alcohols with a short alkyl chain. Moreover, cholesterol is always solubilized in the palisade layer of the reversed micelles whereas retinol and retinal are preferentially solubilized in the aqueous pseudophase. The influence of the enthalpic and the entropic contributions to the transfer of the solubilizates from n-heptane to reversed AOT micelles are also considered.

Complex formation in Aerosol OT reversed micelles between sodium counterion and Kryptofix 221D macrobicyclic ligand

The interaction between 5-decyl-4,7,13,16,21-pentaoxa-1,10-diazabicyclo-[8,8,5]-tricosan (Kryptofix 221D) and reversed micelles of sodium bis(2-ethylhexyl) sulfosuccinate (AOT) in n-heptane as a function of AOT and water concentration was investigated by a calorimetric technique. The solubilization of the cryptand in the reversed AOT micelles produces an exothermic effect that increases with R (R=[water]/[AOT]) and is slightly dependent on AOT concentration. Processes due to the formation of a 1:1 complex between the cryptand and the sodium counterion of the AOT and to the transfer of Kryptofix 221D from bulk n-heptane to the micellar palisade layer have been taken into account to rationalize the experimental results. The peculiar solvation state of the sodium counterions near the water-AOT interface has also been considered.