Insub Jung

Direct growth of graphene nanomesh using a Au nano-network as a metal catalyst via chemical vapor deposition

Herein, we report a simple and facile method on the direct formation of graphene nanomesh (GNM) on insulating substrates by chemical vapor deposition using the Au metal nano-network as a metal catalyst. Well-ordered hexagonal honeycomb shapes of Au nano-network films synthesized using an anodized aluminum oxide template, served as catalysts for the growth of GNM. As-prepared GNM was characterized by various techniques and fabricated as a conducting channel in field effect transistors. Enhanced mobility and a relatively high ON/OFF ratio confirmed our synthetic strategy of the fabrication of GNM as an alternative to a conventional top-down lithographic approach.

Fourier Transform Surface Plasmon Resonance of Nanodisks Embedded in Magnetic Nanorods

In this study, we demonstrate the synthesis and application of magnetic plasmonic gyro-nanodisks (GNDs) for Fourier transform surface plasmon resonance based biodetection. Plasmonically active and magnetically responsive gyro-nanodisks were synthesized using electrochemical methods with anodized aluminum templates. Due to the unique properties of GNDs (magnetic responsiveness and surface plasmon bands), periodic extinction signals were generated under an external rotating magnetic field, which is, in turn, converted into frequency domains using Fourier transformation. After the binding of a target on GNDs, an increase in the shear force causes a shift in the frequency domain, which allows us to investigate biodetection for HA1 (the influenza virus). Most importantly, by modulating the number and the location of plasmonic nanodisks (a method for controlling the hydrodynamic forces by rationally designing the nanomaterial architecture), we achieved enhanced biodetection sensitivity. We expect that our results will contribute to improved sensing module performance, as well as a better understanding of dynamic nanoparticle systems, by harnessing the perturbed periodic fluctuation of surface plasmon bands under the modulated magnetic field.

Surface plasmon resonance extension through two-block metal-conducting polymer nanorods

Research on surface plasmon resonance coupling of metallic nanostructures is an important area in the field of plasmonics because distinctive collective optical properties can be realized that are different from the individual constituents. Here we report the localized surface plasmon resonance of hybrid metal-organic nanorods. Colloidal-dispersed Au-PPy nanorods were synthesized as a representative material using a modified electrochemical method, and the collective oscillation properties were systematically investigated by comparing these materials with pure Au nanorods. We observed the extended surface plasmon resonance of a hybrid system. The presence of doped-PPy segments on Au segments induced an enhanced coherent electric field due to the partial contribution of π-electrons on the PPy segment, which led to a red-shifted plasmon feature. Additionally, we demonstrated that surface plasmon resonance extension can be tuned by dopant anions, which demonstrates a way of tuning a dopant-induced plasmonic system.Localized surface plasmon resonance can be exploited for a range of applications, but remains difficult to tailor in metal-organic nanostructures. Here the authors synthesize gold-polypyrrole nanorods and observe a unique extended surface plasmon resonance, which they find to be tunable through doping.

Fourier Transform Surface Plasmon Resonance (FTSPR) with Gyromagnetic Plasmonic Nanorods

An unprecedented active and dynamic sensing platform based on a LSPR configuration that is modulated by using an external magnetic field is reported. Electrochemically synthesized Au/Fe/Au nanorods exhibited plasmonically active behavior through plasmonic coupling, and the middle ferromagnetic Fe block responded to a magnetic impetus, allowing the nanorods to be modulated. The shear force variation induced by the specific binding events between antigens and antibodies on the nanorod surface is used to enhance the sensitivity of detection of antigens in the plasmonics-based sensor application. As a proof-of-concept, influenza A virus (HA1) was used as a target protein. The limit of detection was enhanced by two orders of magnitude compared to that of traditional LSPR sensing.

Multi-block magnetic nanorods for controlled drug release modulated by Fourier transform surface plasmon resonance

Stimuli-responsive tunable drug release using nanocarriers is an important subject in smart drug delivery systems. Specifically, magnetic-responsive nanocarriers provide a great opportunity for remote control as well as on-demand command. To effectively utilize magnetic-responsive nanocarriers in vivo and in vitro, drug release should not only be controlled in an efficient way, but also monitored in situ. To satisfy those prerequisites, a template-assisted electrochemical deposition method can be a great option for the synthesis of designer materials that are targeted for specific purposes. Here, we synthesized plasmonic-magnetic nanocarriers by template-assisted electrochemical deposition and covered their surface with a silica shell for drug loading. By appropriately designing the blocks, we synthesized nanocarriers that were plasmonically active and magnetically active with spaces for drug payload. These nanocarriers could be modulated under an external magnetic field and their rotation (or agitation) could be monitored by Fourier transform conversion. Using our nanocarriers, we systematically investigated the tunable release of the anticancer drug doxorubicin as a function of the external magnetic field. Additionally, by applying this modulation system to an in vitro system using HeLa cells we were able to not only monitor the modulation systems but also tailor the drug release in a controlled manner. We expect that our approach will contribute to understanding of nanocarriers in a simulative manner in vitro.