Iulian Mircea

Interfacial Fracture Toughness Measurement of Thick Ceramic Coatings by Indentation

The basic requirement for the use of a ceramic coating is sufficient adhesion to its substrate. A measure of the adhesive properties of a coating is the interfacial fracture toughness. The test method applicable for interfacial fracture toughness measurements depends on the mechanical properties of the material system and the geometry of the test piece. In this work, indentation methods have been evaluated for the estimation of the fracture toughness of ceramic thermal barrier coatings on metallic substrates. Coatings of 100 to 300 µm thickness were applied by electron beam – physical vapour deposition. The performed test types were Vickers indentation at the interface of polished cross sections of the coating system and Rockwell indentation with a brale C indenter, penetrating the coating perpendicular to the surface. Both tests generate delamination, in which the delamination crack length corresponds to the interfacial fracture toughness. Fracture surfaces and cross sections of the fractured coatings were investigated by optical and scanning electron microscope. Determined fracture toughness values are discussed with respect to the loading conditions in the test and the fracture process – i.e. interaction between indenter and coating system and the crack propagation path.

Testing and Characterization of Ceramic Thermal Barrier Coatings

This paper gives a short overview of tests applied for the investigation of long term behaviour of thermal barrier coating systems. A variety of tests has been conducted on an exemplary material system with the coatings applied by electron beam physical vapour deposition. Damages and damage evolution in different tests are compared. Since the observed damage mechanisms are different, it is proposed to design laboratory tests as realistic as possible, especially if the test data are used for lifetime assessment. In order to get reasonable testing times, the damage accumulation has to be described as a function of loading history, long time before failure. For the case of final failure by spallation of the ceramic top coat, it is proposed to use the apparent interfacial fracture toughness as damage parameter. Several methods for measuring the apparent fracture toughness of brittle coatings are discussed with respect to their application to thermal barrier coating systems.

Determining the Elastic Moduli of the Individual Component Layers of Cylindrical Thermal Barrier Coatings by Means of a Mixed Numerical - Experimental Technique

Cylindrical specimens made of the Ni-based super-alloy Inconel 625 (IN 625) were coated with (a) NiCoCrAlY, or (b) NiCoCrAlY and yttria-stabilised zirconia (YSZ: in this case, zirconia with 7-8 wt% yttria), using the electron beam - physical vapor deposition (EB-PVD) technique. In the bi-layer coatings, the YSZ layer is the thermal barrier coating (TBC) and the NiCoCrAlY layer is the metallic bond coat (BC). The BC improves the bonding between the substrate and the ceramic TBC, while the low thermal conductivity of the TBC oers high-temperature protection to the substrate. This paper focuses on the determination of the elastic moduli of the substrate and the coating layers of the test samples. The elastic moduli of the three dierent materials (IN 625, NiCoCrAlY and YSZ) were determined by means of a mixed numerical - experimental technique (MNET). The employed MNET was based on the comparison of the experimentally measured resonant frequencies of the rst bending mode of the test samples to the numerically calculated ones. The unknown elastic properties were determined by ne-tuning the elastic material parameters of the numerical models so as to enable the reproduction of the experimentally measured resonant frequencies.

Time-Economic Lifetime Assessment for high Performance Thermal Barrier Coating Systems

Strategies for time-economic lifetime assessment of thermal barrier coatings (TBC) in service are described and discussed on the basis of experimental results, achieved on material systems with coatings applied by electron beam physical vapour deposition. Service cycles for gas turbine blades have been simulated on specimens in thermo-mechanical fatigue tests, accelerating the fatigue processes by an increase of load frequency. Time dependent changes in the material system were imposed by a separate ageing, where the samples were pre-oxidized prior to the fatigue test. Results of thermo-mechanical fatigue tests on pre-aged and as-coated specimens gave evidence of interaction between fatigue and ageing processes. An alternative approach is used, which is focused on the evolution of a failure relevant damage parameter in the TBC system. The interfacial fracture toughness was selected as a damage parameter, since one important failure mode of TBCs is the spallation near the interface between the metal and the ceramic. Fracture mechanical experiments based on indentation methods have been evaluated for monitoring the evolution of the interfacial fracture toughness as a function of ageing time. It was found that the test results were influenced by both changes of the interface (which is critical in service) and changes in the surrounding material.

Comparison of the damping and stiffness properties of 8wt% yttria stabilized zirconia ceramic coating deposited by the APS and EB-PVD techniques

Recent research into the use of thermal barrier coatings has shown that they can provide sufficient additional damping, reducing vibration levels and significantly extending the life of the coated component. Various deposition techniques may be employed to apply ceramic coatings with Air Plasma Spraying (APS) and Electron Beam - Physical Vapour Deposition (EB-PVD) being the most widely used. However, one has to take into account that even when the starting ceramic material is the same, the microstructures of the resultant coatings depend strongly on the deposition technique. The objective of this paper is to study of the differences in the damping behaviour and stiffness of an yttria-stabilised zirconia (YSZ with 8%wt yttria) coating deposited by APS and by EB-PVD. Both damping and stiffness of these two YSZ coatings were estimated from tests performed at room and high temperatures. Moreover, this paper presents the microstructural characterisation of these two YSZ coatings using scanning electron microscopy, and attempts a correlation of the differences in their properties to their microstructure.