Ivan Martini

Provenance and geological significance of red mud and other clastic sediments of the Mugnano cave (Montagnola Senese, Italy)

The Mugnano Cave is characterized by a thick clastic sedimentary fill showing a great variability of sedimentary facies, ranging from clay to coarse-grained sand deposits. This paper deals with combined sedimentological and mineralogical (XRD and SEM) studies of these sediments and bedrock insoluble residues in order to understand the origin and geological significance of cave deposits, with particular attention to red mud sediments, often considered as the residue of host rock dissolution. Three different sedimentary facies were recognized: i) YS, yellow sand with occasionally shell fragments, testifying the arrival of sediments from the surrounding landscape; ii) RS, red laminated mud; iii) GS, grey and red-grey mud and sand, dolomite-rich sediments. Furthermore, the results obtained in the present study allowed the identification of two fingerprint minerals: i) quartz, present only as traces in the limestone host-rock, and ii) dolomite, certainly related to the incomplete bedrock dissolution. Results obtained by this multidisciplinary approach testify that no one of the investigated sediments is representative of a completely autochthonous sedimentation (i.e. accumulation of insoluble residue of limestone in a cave environment). In fact, all the three sedimentary facies show a bulk composition rich in quartz, a mineral indicating an external origin for these sediments. Also the grey sediments, despite of their high content of bedrock-related dolomite, are quite rich in quartz and they testify the mixing of autochthonous and allocthonous sediments. The clay fraction of cave sediments shows strong compositional similarities with bedrock insoluble residue and consequently its analysis cannot be considered as a clear proxy for distinguishing between different parent materials. Therefore, the origin of these cave deposits is dominantly related to external sediments inputs, with terra rossa surface soils as the most probable parent material for red mud sediments.

Geological map of the Pliocene succession of the Northern Siena Basin (Tuscany, Italy)

Abstract Please click here to download the map associated with this article. The late Miocene-Pliocene sedimentary fill of the Siena Basin (Tuscany, Italy) consists dominantly of clastics and has internal architecture that reflects the interplay of tectonics, relative sea-level changes and climate variations. Pliocene sediments are extensively exposed and overlay both late Miocene deposits and pre-Neogene bedrock. Specifically, Pliocene basin margin sediments consist largely of sand with gravel and mud intercalations, deposited mainly in nearshore settings with minor fluvial depositional episodes. They grade basinward to dominantly offshore fines with intervening turbiditic sand bodies. New fieldwork revealed that basin margin deposits, notwithstanding lithologically rather homogeneous, are made of a variety of sedimentary facies and bear several unconformities. They have been traditionally described and mapped using lithostratigraphic criteria, that have proven to be unfit to represent such complex stratigraphic architectures. The aim of this paper is to describe the allostratigraphic architecture of the Pliocene deposits exposed in a marginal key-area (45 km) of the northern Siena Basin by means of a 1:10,000 scale geological map. The recognized succession of allostratigraphic units and their bounding discontinuities, along with new biostratigraphic data from calcareous plankton, provides new insights into the geological history of the Siena Basin and represents valuable constraints for long-distance correlation.

Detection of detached forced-regressive nearshore wedges: a case study from the central-southern Siena Basin (Northern Apennines, Italy)

The detection of detached nearshore wedges formed in response to relative sea-level drops is considered one of the hottest topics in sequence stratigraphic analysis due to their importance as reservoir analogues. In fact, they usually constitute sandy and porous bodies generally encased in impermeable clay, thus presenting a good potential as traps for fluids. This paper focuses on the sequence stratigraphic analysis of the Pliocene deposits cropping out in the central-southern sector of the Siena Basin (Tuscany, Italy), a post-collisional basin of the Northern Apennines. The exposed sedimentary succession was investigated through a detailed sedimentological and stratigraphic approach, integrated by biostratigraphic analyses, aimed at a better characterization of the infilling history of this sector of the basin. Specifically, this study revealed the occurrence of repeated facies shifts that allowed the identification of two depositional sequences. In detail, a thick sand-rich body far from the basin margins, and previously considered as a turbiditic lobe, has been reinterpreted as formed in a nearshore setting during a fall in relative sea level. This body is totally encased in offshore clay, and due to the lack of physical connection with the related HST deposits, it has to be considered as a detached forced-regressive wedge. The present work led to the recognition of some sedimentological and stratigraphic features typical of falling stage systems tract deposits (e.g. presence of intrabasinal recycled materials, sedimentological evidence of a pre-existing fluvial network subsequently eroded) that can provide useful clues for the identification of detached forced-regressive nearshore wedges in core studies and poorly exposed settings.

Facies associations map of the Pliocene marine deposits of the central-southern Siena Basin (Tuscany, Italy)

The Siena Basin is a post-collisional basin of the inner Northern Apennines (Tuscany, Italy) characterized by a thick siliciclastic Neogene infill, mainly composed of marine sediments with subordinate alluvial deposits close to basin margins. The central-southern sector of the basin shows a more complex stratigraphy with the occurrence of sandy deposits also in distal areas, far from the basin margin. The aim of this paper is to provide a new 1:10,000-scale geological map of this key sector (about 45 km2) of the Siena Basin, helpful for a better reconstruction of its sedimentary evolution. The new fieldwork was based on the identification and mapping of different facies associations (expression of different sedimentary environments), whose shifts in time and space provide elements to understand the basin-fill history. The recognition of two main intra-Pliocene erosional surfaces allowed the subdivision of the succession into three alloformations. Therefore, a more complex depositional history, with respect to the previous knowledge for this key-sector of the Siena Basin, has been reconstructed, thus highlighting the importance of this kind of approach with respect to the classical lithostratigraphic criteria.

Geological map of Pliocene-Pleistocene deposits of the Ambra and Ombrone valleys (Northern Siena Basin, Tuscany, Italy)

The study area is located across the Chianti Ridge (Tuscany, Italy), between the Upper Valdarno Basin and the Siena Basin. This area covers about 25 km2, forming a narrow belt oriented N–S and drained by the Ambra and Ombrone creeks, which flow northward and southward, respectively. Field mapping was carried out at 1:10,000 scale through an allostratigraphic-sedimentological approach. The study area deposits represent the infill of a SW-draining paleovalley, cut both in pre-Neogene bedrock and marine Pliocene deposits of the Siena Basin. The valley-fill succession consists of two main allounits (V1 and V2), which are conformably stacked in the northern sector of the study area, and unconformably offset in the southern sector. V1 comprises gravelly to sandy fluvial deposits, whereas V2 deposits show noticeable downvalley variability. V2 consists of poorly drained floodplain deposits in the northern sector of the paleovalley, whereas gravel and sand-bed river deposits fill its southern part. Alluvial-fan and palustrine deposits are also associated with V2 fluvial facies. A normal fault trending NW–SE is the main structural feature of the area. This fault cuts the V2 unit lowering the upstream reach and is thought to have promoted the marked facies changes observed in the fluvial deposits of unit V2.

Calcareous plankton bio-chronostratigraphy and sedimentology of the “I Sodi” section (Siena Basin, Italy): a key section for the uppermost Neogene marine deposition in the inner northern Apennines

The I Sodi section is exposed in the homonymous quarry in the northern sector of the Siena Basin, one of the most extended Neogene-Quaternary post-collisional basins of the northern Apennines. The section is composed almost exclusively of marine mudstone containing a rich fossil assemblage and has been extensively investigated in past and recent times. It represents a key section to define the time interval of marine deposition in the Siena Basin and more generally in the inner northern Apennines, with important structural and stratigraphic implications.The marine infill of the Siena Basin is traditionally attributed to the Zanclean-Piacenzian (Pliocene) age. However, recently published data provided a more recent age for the I Sodi section (Calabrian, Lower Pleistocene) and, consequently, for the Siena Basin. This paper provides new data on this scientific debate, from sedimentological and biostratigraphical investigations. Analyses of planktonic foraminifera and calcareous nannofossils have been carried out in order to better constrain the depositional age of the section. As a result, this section is now dated more accurately to the Piacenzian and possibly to the lowermost Gelasian in its upper part.

SEDIMENTATION AND BASIN-FILL HISTORY OF THE PLIOCENE SUCCESSION EXPOSED IN THE NORTHERN SIENA-RADICOFANI BASIN (TUSCANY, ITALY): A SEQUENCE-STRATIGRAPHIC APPROACH

Basin-margin paralic deposits are sensitive indicators of relative sea-level changes and typically show complex stratigraphic architectures that only a facies-based sequence-stratigraphic approach, supported by detailed biostratigraphic data, can help unravel, thus providing constraints for the tectono-stratigraphic reconstructions of ancient basins. This paper presents a detailed facies analysis of Pliocene strata exposed in a marginal key-area of the northern Siena-Radicofani Basin (Tuscany, Italy), which is used as a ground for a new sequence-stratigraphic scheme of the studied area. The study reveals a more complex sedimentary history than that inferred from the recent geological maps produced as part of the Regional Cartographic Project (CARG), which are based on lithostratigraphic principles. Specifically, four sequences (S1 to S4, in upward stratigraphic order) have been recognised, each bounded by erosional unconformities and deposited within the Zanclean-early Gelasian time span. Each sequence typically comprises fluvial to open marine facies, with deposits of different sequences that show striking lithological similarities.The architecture and internal variability shown by the studied depositional sequences are typical of low-accommodation basin-margin settings, that shows: i) a poorly-developed to missing record of the falling-stage systems tract; ii) a lowstand system tract predominantly made of fluvio-deltaic deposits; iii) a highstand system tract with substantial thickness variation between different sequences due to erosional processes associated with the overlying unconformity; iv) a highly variable transgressive system tract, ranging from elementary to parasequential organization.

The Scaglia Toscana Formation of the Monti del Chianti: new lithostratigraphic and biostratigraphic data

The Scaglia Toscana Formation (Scisti Policromi Auctt.) is one of the most investigated formation of the Tuscane Nappe. The Formation is widely exposed in the Chianti Mounts and despite the number of studies in this area, some aspects remain poorly known and debated. In this paper new litho- and bio-stratigraphic data from eight key-sections distributed over the entire area are provided and discussed in order to clarify the stratigraphic relationshpis among different lithostratigraphic members, as well as the depositional ages of each member. The Formation deposited in the Cretaceous-Oligocene time interval and it can be subdivided into five lithostratigraphic members: i) the Argilliti di Brolio (wine-red shales with sporadic siliceous calcilutites and rare interbedded cherts); ii) the Marne del Sugame (red and pink marls, calcareous marls and marly limestones with interbedded calcarenitic beds and ruditic lens-shaped bodies including calcareous-siliceous clasts); iii) the Argilliti di Cintoia (grey-green to black shales, locally with manganese-rich siliceous calcilutites and cherts); iv) the Calcareniti di Montegrossi (thin beds of calcilutites and calcarenites with varicoloured shaly-marly interbeds); and v) the Argilliti e Calcareniti di Dudda (alternating thin beds of calcilutites and calcarenites with varicoloured shaly-marly interbeds). These members deposited in a marine environment and have been interpreted as deposited in a turbiditic system, in which shaly and calcareous turbiditic members have been attributed to a basin plain below the CCD, whereas the marls and marly limestones of the Marne del Sugame Member can be settled in a slope/ramp environment above or close to the CCD. Furthermore, the combination of these new data with structural informations coming from literatures allowed to a better paleogeographic reconstruction of the paleobasin. In order to better explain these data, the paper is accompanied by two geological maps realized in the past but never distributed. The two geological maps, at the scale of 1:25,000, cover the whole area from the Cintoia (south of Florence) to the San Gusme (north of Siena) villages.