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Synthetic Communications | 1975

SYNTHESIS OF SULFINYL CYANIDES

A. Boerma-Markerink; J. C. Jagt; H. Meyer; Jurjen Wildeman; A. M. Van Leusen

Abstract m-Chloroperbenzoic acid oxidation of thiocyanates provides a synthetic route to sulfinyl cyanides (2). 1-Adamantane-sulfinyl cyanide (2c) is prepared more efficiently from the corresponding sulfinyl chloride and sodium cyanide.


Synthetic Communications | 1974

Synthesis of C-Sulfonylcarbohydroximoyl Chlorides from α-Diazosulfones and Nitrosyl Chloride1

J. C. Jagt; Ineke van Buuren; J. Strating; A. M. Van Leusen

Abstract Previous investigations in this laboratory have been concerned with reactions of α-diazosulfones2 (1) with electrophilic reagents, such as sulfenyl chlorides2, t-butyl hypochlorite2,3 and halogens4, which lead to threefold electronegatively substituted methanes (2). As was anticipated, α-diazosulfones closely resemble α-diazoketones in these reactions.5


Tetrahedron Letters | 1970

Nucleophilic displacements on sulfonyl cyanides

A. M. Van Leusen; J. C. Jagt


Recueil des Travaux Chimiques des Pays-Bas | 2010

Chemistry of sulfonyl cyanides. Part 4: Diels‐alder cycloadditions of sulfonyl cyanides with dienes

J. C. Jagt; A. M. Van Leusen


Tetrahedron Letters | 1970

Cycloaddition reactions of sulfonyl cyanides

A. M. Van Leusen; J. C. Jagt


Recueil des Travaux Chimiques des Pays-Bas | 2010

Nucleophilic additions on sulfonyl cyanides. Formation of C-(arylsulfonyl)- and C-(alkylsulfonyl)formamidrazones and their conversion to 1,2,4-triazoles†

J. C. Jagt; A. M. Van Leusen


Recueil des Travaux Chimiques des Pays-Bas | 2010

Thermal addition of tosyl cyanide to norbornadiene. A Homo‐Diels‐Alder cycloaddition versus homo‐conjugate 1,4‐addition

J. C. Jagt; A. M. Van Leusen


Recueil des Travaux Chimiques des Pays-Bas-Journal of the Royal Netherlands Chemical Society | 1977

CHEMISTRY OF SULFONYL CYANIDES .7. THERMAL ADDITION OF TOSYL CYANIDE TO NORBORNADIENE - HOMO-DIELS-ALDER CYCLOADDITION VERSUS HOMO-CONJUGATE 1,4-ADDITION

J. C. Jagt; A.M. van Leusen


ChemInform | 1977

CHEMISTRY OF SULFONYL CYANIDES. PART 7. THERMAL ADDITION OF TOSYL CYANIDE TO NORBORNADIENE. A HOMO-DIELS-ALDER CYCLOADDITION VERSUS HOMO-CONJUGATE 1,4-ADDITION

J. C. Jagt; A. M. Van Leusen


Recueil des Travaux Chimiques des Pays-Bas-Journal of the Royal Netherlands Chemical Society | 1975

CHEMISTRY OF SULFONYL CYANIDES .6. NUCLEOPHILIC ADDITIONS ON SULFONYL CYANIDES - FORMATION OF C-(ARYLSULFONYL)FORMAMIDRAZONES AND C-(ALKYLSULFONYL)FORMAMIDRAZONES AND THEIR CONVERSION TO 1,2,4-TRIAZOLES

J. C. Jagt; A.M. van Leusen

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J. Strating

University of Groningen

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