J. C. Santamarina

Mechanical properties of sand, silt, and clay containing tetrahydrofuran hydrate

[1] The mechanical behavior of hydrate-bearing sediments subjected to large strains has relevance for the stability of the seafloor and submarine slopes, drilling and coring operations, and the analysis of certain small-strain properties of these sediments (for example, seismic velocities). This study reports on the results of comprehensive axial compression triaxial tests conducted at up to 1 MPa confining pressure on sand, crushed silt, precipitated silt, and clay specimens with closely controlled concentrations of synthetic hydrate. The results show that the stress-strain behavior of hydrate-bearing sediments is a complex function of particle size, confining pressure, and hydrate concentration. The mechanical properties of hydrate-bearing sediments at low hydrate concentration (probably 50% of pore space), the behaviorbecomesmoreindependentofstressbecausethehydratescontrolbothstiffnessand strength and possibly the dilative tendency of sediments by effectively increasing interparticle coordination, cementing particles together, and filling the pore space. The cementation contribution to the shear strength of hydrate-bearing sediments decreases with increasing specific surface of soil minerals. The lower the effective confining stress, the greater the impact of hydrate formation on normalized strength.

Observations related to tetrahydrofuran and methane hydrates for laboratory studies of hydrate‐bearing sediments

The interaction among water molecules, guest gas molecules, salts, and mineral particles determines the nucleation and growth behavior of gas hydrates in natural sediments. Hydrate of tetrahydrofuran (THF) has long been used for laboratory studies of gas hydrate-bearing sediments to provide close control on hydrate concentrations and to overcome the long formation history of methane hydrate from aqueous phase methane in sediments. Yet differences in the polarizability of THF (polar molecule) compared to methane (nonpolar molecule) raise questions about the suitability of THF as a proxy for methane in the study of hydrate-bearing sediments. From existing data and simple macroscale experiments, we show that despite its polar nature, THFs large molecular size results in low permittivity, prevents it from dissolving precipitated salts, and hinders the solvation of ions on dry mineral surfaces. In addition, the interfacial tension between water and THF hydrate is similar to that between water and methane hydrate. The processes that researchers choose for forming hydrate in sediments in laboratory settings (e.g., from gas, liquid, or ice) and the pore-scale distribution of the hydrate that is produced by each of these processes likely have a more pronounced effect on the measured macroscale properties of hydrate-bearing sediments than do differences between THF and methane hydrates themselves.

Parametric study of the physical properties of hydrate‐bearing sand, silt, and clay sediments: 2. Small‐strain mechanical properties

v and sediment specific surface. The S velocity increases with hydrate saturation owing to an increase in skeletal shear stiffness, particularly when hydrate saturation exceeds Shyd≈ 0.4. At very high hydrate saturations, the small strain shear stiffness is determined by the presence of hydrates and becomes insensitive to changes in effective stress. The P velocity increases with hydrate saturation due to the increases in both the shear modulus of the skeleton and the bulk modulus of pore‐filling phases during fluid‐to‐hydrate conversion. Small‐strain Poisson’s ratio varies from 0.5 in soft sediments lacking hydrates to 0.25 in stiff sediments (i.e., subject to high vertical effective stress or having high Shyd). At Shyd ≥ 0.5, hydrate hinders expansion and the loss of sediment stiffness during reduction of vertical effective stress, meaning that hydrate‐rich natural sediments obtained through pressure coring should retain their in situ fabric for some time after core retrieval if the cores are maintained within the hydrate stability field.

Numerical Simulation of Inverted Pavement Systems

Conventional pavements rely on stiff upper layers to spread traffic loads onto less rigid lower layers. In contrast, an inverted pavement system consists of an unbound aggregate base compacted on top of a stiff cement-treated base and covered by a relatively thin asphalt concrete layer. The unbound aggregate interlayer in an inverted pavement experiences high cyclic stresses that incite its inherently nonlinear granular media behavior. A physically sound, nonlinear elastoplastic material model is selected to capture the unbound granular base in a finite-element simulator developed to analyze the performance of inverted pavement structures. The simulation results show that an inverted pavement can deliver superior rutting resistance, as compared with a conventional flexible pavement structure with similar fatigue life.