J Christina Obert

Tides in the Last Interglacial: insights from notch geometry and palaeo tidal models in Bonaire, Netherland Antilles

The study of past sea levels relies largely on the interpretation of sea-level indicators. Palaeo tidal notches are considered as one of the most precise sea-level indicators as their formation is closely tied to the local tidal range. We present geometric measurements of modern and palaeo (Marine Isotope Stage (MIS) 5e) tidal notches on Bonaire (southern Caribbean Sea) and results from two tidal simulations, using the present-day bathymetry and a palaeo-bathymetry. We use these two tools to investigate changes in the tidal range since MIS 5e. Our models show that the tidal range changes most significantly in shallow areas, whereas both, notch geometry and models results, suggest that steeper continental shelves, such as the ones bordering the island of Bonaire, are less affected to changes in tidal range in conditions of MIS 5e sea levels. We use our data and results to discuss the importance of considering changes in tidal range while reconstructing MIS 5e sea level histories, and we remark that it is possible to use hydrodynamic modelling and notch geometry as first-order proxies to assess whether, in a particular area, tidal range might have been different in MIS 5e with respect to today.

Last Interglacial Hydroclimate Seasonality Reconstructed From Tropical Atlantic Corals

The seasonality of hydroclimate during past periods of warmer than modern global temperatures is a critical component for understanding future climate change scenarios. Although only partially analogous to these scenarios, the last interglacial (LIG, Marine Isotope Stage 5e, ~127–117 ka) is a popular test bed. We present coral δ18O monthly resolved records from multiple Bonaire (southern Caribbean) fossil corals (Diploria strigosa) that date to between 130 and 118 ka. These records represent up to 37 years and cover a total of 105 years, offering insights into the seasonality and characteristics of LIG tropical Atlantic hydroclimate. Our coral δ18O records and available coral Sr/Ca-sea surface temperature (SST) records reveal new insights into the variable relationship between the seasonality of tropical Atlantic seawater δ18O (δ18Oseawater) and SST. Coral δ18O seasonality is found to covary with SST and insolation seasonality throughout the LIG, culminating in significantly higher than modern values at 124 and 126 ka. At 124 ka, we reconstruct a 2 month lead of the coral δ18O versus the Sr/Ca-SST annual cycle and increased δ18Oseawater seasonality. A fully coupled climate model simulates a concomitant increase of southern Caribbean Sea summer precipitation and depletion of summer δ18Oseawater. LIG hydroclimate at Bonaire differed from todays semiarid climate with a minor rainy season during winter. Cumulatively, our coral δ18O, δ18Oseawater, and model findings indicate a mid-LIG northward expansion of the South American Intertropical Convergence Zone into the southern Caribbean Sea, highlighting the importance of regional aspects within model and proxy reconstructions of LIG hydroclimate seasonality.

Chemical separation and MC-ICPMS analysis of U, Th, Pa and Ra isotope ratios of carbonates

Diagenetic alteration of fossil reef corals may have severe effects on the reliability of 230Th/U-ages. The widely applied criteria introduced to test for the reliability of coral 230Th/U-ages are often not sufficient to identify all altered ages. The combination of 230Th/U- with 231Pa/U-dating has been suggested as a promising method to identify altered ages. Furthermore, 226Ra/230Th ratios can provide information about the diagenetic history during the last 10 000 years. Here we present a method to chemically separate U, Th, Pa and Ra from the same aliquot of a carbonate sample. The isotope ratios of our mixed U–Th–Pa–Ra spike are calibrated using a secular equilibrium material treated in the same way as the samples during chemical separation and mass spectrometric analysis. This approach does not only circumvent corrections for the radioactive decay of the short-lived 233Pa spike, but also enables us to estimate the reproducibility of the spike calibration. The relative standard deviation (RSD) of the spike ratios is 0.27% for 229Th/236U, 4.2% for 228Ra/236U and between 0.6 and 4.0% for 233Pa/236U. The RSDs of the final ratios are 1.2% for 231Pa/235U and 3.4% for 226Ra/230Th. We assess the individual sources of uncertainty (e.g., mass spectrometric corrections, counting statistics, and spike calibration) in detail and quantify their contribution to the total uncertainties of the final isotope ratios. Most corrections contribute only moderately to the final uncertainties. However, in the case of a large abundance of natural isotopes in the spike, this correction can have a large influence on both the ratios and their uncertainties. Another parameter affecting the final uncertainties and the reproducibility of the method is the sample size and, thus, the concentration of the natural isotopes. This discussion provides useful guidelines for future applications and can be adjusted to the individual requirements of a specific user.

7) (Figure 3) Monthly interpolated coral Sr/Ca record from Bonaire coral BON-33-BI.2, 129.7 ka

Fossil coral U/Th Age: 129.7 ± 1.7 kyr before the year of measurement (which is AD 2014) / Time period: 10 years around 129.7 ka / Internal chronology starts at base (oldest part) of coral / Data acquired through projects CaribClim (Seasonality and interannual to centennial climate variability in the Caribbean during the last interglacial - Combining coral records, stalagmite records and climate models (CaribClim II)) and Saisonalitat und zwischenjahrliche Klimavariabilitat in der Karibik wahrend des letzten Interglazials rekonstruiert anhand von Korallenzeitreihen.