J. Comas

Pharmaceuticals occurrence in a WWTP with significant industrial contribution and its input into the river system

Occurrence and removal of 81 representative Pharmaceutical Active Compounds (PhACs) were assessed in a municipal WWTP located in a highly industrialized area, with partial water reuse after UV tertiary treatment and discharge to a Mediterranean river. Water monitoring was performed in an integrated way at different points in the WWTP and river along three seasons. Consistent differences between therapeutic classes were observed in terms of influent concentration, removal efficiencies and seasonal variation. Conventional (primary and secondary) treatment was unable to completely remove numerous compounds and UV-based tertiary treatment played a complementary role for some of them. Industrial activity influence was highlighted in terms of PhACs presence and seasonal distribution. Even if global WWTP effluent impact on the studied river appeared to be minor, PhACs resulted widespread pollutants in river waters. Contamination can be particularly critical in summer in water scarcity areas, when water flow decreases considerably.

Effects on activated sludge bacterial community exposed to sulfamethoxazole.

The bacterial community shift on a lab scale Sequencing Batch Reactor (SBR) fed with synthetic wastewater and exposed to 50μgL(-1) of sulfamethoxazole (SFX) for 2months was investigated in this study. The impact on biological nutrient removal performance and SFX removal efficiencies were also studied. Satisfactory biological nutrient removal was observed as regards to COD and Nitrogen. SFX removal efficiencies ranged between 20% and 50% throughout the experimental period, enhanced within the aerobic phases of the SBR cycle, with no evident signs of biomass acclimation. Nevertheless, denaturing gradient gel electrophoresis (DGGE) analysis showed significant variance leading to not only the fading, but also the emergence of new species in the bioreactor bacterial community after SFX dosage. According to the phylogenetic analysis, bacteria belonging to Betaproteobacteria and Gammaproteobacteria classes were the dominant species, among them, the Thiotrix spp. (Gammaproteobacteria) cell number increased due to its tolerance to the antibiotic. On the other hand, the classes Sphingobacteria, Actinobacteria, Chloroflexi and Chlorobi were found to be more vulnerable to the antibiotic load and disappeared. The sulphonamide resistance gene sulI was also quantified and discussed, as there are very few studies on bacterial resistance in lab-scale treatment reactors.

A knowledge-based approach to the deflocculation problem: integrating on-line, off-line, and heuristic information

A knowledge-based approach for the supervision of the deflocculation problem in activated sludge processes was considered and successfully applied to a full-scale plant. To do that, a methodology that integrates on-line, off-line and heuristic information has been proposed. This methodology consists of three steps: (i). development of a decision tree (which involves knowledge acquisition and representation); (ii). implementation into a rule-based system; and (iii). validation. The set of symptoms most useful in diagnosing the deflocculation problem has been identified, the different branches to diagnose pin-point floc and dispersed growth have been built (using generic and specific knowledge), and all this knowledge has been codified into an object-oriented shell. The results obtained in the application of this knowledge-based approach to the Granollers WWTP (which treats about 130000 inhabitants-equivalents) showed that the system was able to identify correctly the problem with reasonable accuracy. Our positive experience building this system suggests that this approach is a practical and valuable element to include in an intelligent supervisory system combining numerical and reasoning techniques.

Removal of ibuprofen and its transformation products: experimental and simulation studies.

Pharmaceutically active compounds (PhACs) deserve attention because of their effect on ecosystems and human health, as well as their continuous introduction into the aquatic environment. Classification schemes are suggested to characterise their biological degradation, e.g., based on pseudo-first-order kinetics, but these schemes can vary significantly, presumably due to pharmaceutical loads, sludge characteristics and experimental conditions. Degradation data for PhAC transformation products (TPs) are largely lacking. The present work focuses not only on the biodegradation of the pharmaceutical compound ibuprofen but also on its best-known TPs (i.e., carboxyl ibuprofen and both hydroxyl ibuprofen isomers). Ibuprofen is one of the most commonly consumed PhACs and can be found in different environmental compartments. The experiment performed consisted of a set of aerated batch tests with different suspended solid and ibuprofen concentrations to determine the influence of these parameters on the calculated biodegradation constant (K(biol)). Sampling of the liquid phase at different scheduled times was assessed, removal efficiencies were calculated and pseudo-first-order kinetics were adjusted to obtain experimental K(biol) values for the parent compound and its TPs. The experimental data were successfully fitted to ASM-based models, with K(biol) values for the target compounds ranging from almost 1 to 17 L gSST(-1) d(-1), depending on the concentrations of the biomass and ibuprofen. This work provides innovative knowledge not only regarding the removal of TPs but also the formation kinetics of these TPs.

Benchmark simulation models, quo vadis?

As the work of the IWA Task Group on Benchmarking of Control Strategies for wastewater treatment plants (WWTPs) is coming to an end, it is essential to disseminate the knowledge gained. For this reason, all authors of the IWA Scientific and Technical Report on benchmarking have come together to provide their insights, highlighting areas where knowledge may still be deficient and where new opportunities are emerging, and to propose potential avenues for future development and application of the general benchmarking framework and its associated tools. The paper focuses on the topics of temporal and spatial extension, process modifications within the WWTP, the realism of models, control strategy extensions and the potential for new evaluation tools within the existing benchmark system. We find that there are major opportunities for application within all of these areas, either from existing work already being done within the context of the benchmarking simulation models (BSMs) or applicable work in the wider literature. Of key importance is increasing capability, usability and transparency of the BSM package while avoiding unnecessary complexity.

Energy Saving in a Wastewater Treatment Process: an Application of Fuzzy Logic Control

Many uncertain factors affect the operation of Wastewater Treatment Plants. Due to the complexity of biological wastewater treatment processes, classical methods show significant difficulties when trying to control them automatically. Consequently soft computing techniques and, specifically, fuzzy logic appears to be a good candidate for controlling these ill-defined, time-varying and non-linear systems. This paper describes the development and implementation of a Fuzzy Logic Controller to regulate the aeration in the Taradell Wastewater Treatment Plant. The main goal of this control process is to save energy without decreasing the quality of the effluent discharged. The fuzzy controller integrates the information coming from two different signals: the Dissolved Oxygen and Oxidation-Reduction Potential values. The simulation results proved that fuzzy logic is a good tool for controlling the aeration of the wastewater treatment plant. The results obtained show that energy savings of more than 10% can be achieved using aeration fuzzy control and at the same time still keeping the good removal levels.

Instrumentation, control and automation in wastewater - From London 1973 to Narbonne 2013

Key developments of instrumentation, control and automation (ICA) applications in wastewater systems during the past 40 years are highlighted in this paper. From the first ICA conference in 1973 through to today there has been a tremendous increase in the understanding of the processes, instrumentation, computer systems and control theory. However, many developments have not been addressed here, such as sewer control, drinking water treatment and water distribution control. It is hoped that this review can stimulate new attempts to more effectively apply control and automation in water systems in the coming years.

Towards integrated operation of membrane bioreactors: effects of aeration on biological and filtration performance.

Two experimental studies evaluated the effect of aerobic and membrane aeration changes on sludge properties, biological nutrient removal and filtration processes in a pilot plant membrane bioreactor. The optimal operating conditions were found at an aerobic dissolved oxygen set-point (DO) of 0.5 mg O2 L(-1) and a membrane specific aeration demand (SADm) of 1 m h(-1), where membrane aeration can be used for nitrification. Under these conditions, a total flow reduction of 42% was achieved (75% energy reduction) without compromising nutrient removal efficiencies, maintaining sludge characteristics and controlled filtration. Below these optimal operating conditions, the nutrient removal efficiency was reduced, increasing 20% for soluble microbial products, 14% for capillarity suction time and reducing a 15% for filterability. Below this DO set-point, fouling increased with a transmembrane pressure 75% higher. SADm below 1 m h(-1) doubled the values of transmembrane pressure, without recovery after achieving the initial conditions.

Development of a case-based system for the supervision of an activated sludge process.

The development of a case-based reasoning system for the supervision of an activated sludge process is presented here. The methodology proposed permits the use of past experiences to solve new problems that arise in the process. These experiences are classified as cases or situations. The adaptation of cases and the generation of new cases are used to tune the response of the system and to learn from the new information generated by the process. The case and the case library definition, the initial seed, the search and retrieval process, the adaptation, the action, the evaluation and the learning steps are presented and outlined. The process studied is the wastewater treatment plant of Girona, Spain. Two examples of the response of the system to two different operational situations are presented. The paper also outlines the integration of different fields in a multidisciplinary approach as the most optimal solution to ensure the successful control and supervision of complex processes like the activated sludge process. With this aim the integration of an array of specific supervisory intelligent systems (for the logical analysis and reasoning) and numerical computations for detailed engineering is suggested.

Assessment of energy-saving strategies and operational costs in full-scale membrane bioreactors

The energy-saving strategies and operational costs of stand-alone, hybrid, and dual stream full-scale membrane bioreactors (MBRs) with capacities ranging from 1100 to 35,000xa0m(3)xa0day(-1) have been assessed for seven municipal facilities located in Northeast Spain. Although hydraulic load was found to be the main determinant factor for the energy consumption rates, several optimisation strategies have shown to be effective in terms of energy reduction as well as fouling phenomenon minimization or preservation. Specifically, modifications of the biological process (installation of control systems for biological aeration) and of the filtration process (reduction of the flux or mixed liquor suspended solids concentration and installation of control systems for membrane air scouring) were applied in two stand-alone MBRs. After implementing these strategies, the yearly specific energy demand (SED) in flat-sheet (FS) and hollow-fibre (HF) stand-alone MBRs was reduced from 1.12 to 0.71 and from 1.54 to 1.12xa0kWxa0h(-1)xa0m(-3), respectively, regardless of their similar yearly averaged hydraulic loads. The strategies applied in the hybrid MBR, namely, buffering the influent flow and optimisation of both biological aeration and membrane air-scouring, reduced the SED values by 14%. These results illustrate that it is possible to apply energy-saving strategies to significantly reduce MBR operational costs, highlighting the need to optimise MBR facilities to reconsider them as an energy-competitive option.