J.E.M. Haverkort

Large redshift in photoluminescence of p-doped InP nanowires induced by Fermi-level pinning

We have studied the effect of impurity doping on the optical properties of indium phosphide (InP) nanowires. Photoluminescence measurements have been performed on individual nanowires at low temperatures (5–70 K) and at low excitation intensities (0.5–10W∕cm2). We show that the observed redshift (200 meV) and the linewidth (70 meV) of the emission of p-type InP wires are a result of a built-in electric field in the nanowires. This bandbending is induced by Fermi-level pinning at the nanowire surface. Upon increasing the excitation intensity, the typical emission from these p-InP wires blueshifts with 70meV∕decade, due to a reduction of the bandbending induced by an increase in the carrier concentration. For intrinsic and n-type nanowires, we found several impurity-related emission lines.

Carrier‐carrier scattering induced capture in quantum well lasers

We present calculations of the carrier capture efficiency into various types of quantum well lasers. The carrier capture into a quantum well can be due to either optical phonon emission or carrier‐carrier scattering. Both capture mechanisms have been calculated and show oscillations as a function of the quantum well thickness. By optimizing the carrier capture efficiency the carrier accumulation in the barrier layers can be reduced, resulting in an improved modulation response and threshold current.

Position-controlled [100] InP nanowire arrays

We investigate the growth of vertically standing [100] zincblende InP nanowire (NW) arrays on InP (100) substrates in the vapor-liquid-solid growth mode using low-pressure metal-organic vapor-phase epitaxy. Precise positioning of these NWs is demonstrated by electron beam lithography. The vertical NW yield can be controlled by different parameters. A maximum yield of 56% is obtained and the tapering caused by lateral growth can be prevented by in situ HCl etching. Scanning electron microscopy, high-resolution transmission electron microscopy, and micro-photoluminescence have been used to investigate the NW properties.

High-Efficiency Nanowire Solar Cells with Omnidirectionally Enhanced Absorption Due to Self-Aligned Indium–Tin–Oxide Mie Scatterers

Photovoltaic cells based on arrays of semiconductor nanowires promise efficiencies comparable or even better than their planar counterparts with much less material. One reason for the high efficiencies is their large absorption cross section, but until recently the photocurrent has been limited to less than 70% of the theoretical maximum. Here we enhance the absorption in indium phosphide (InP) nanowire solar cells by employing broadband forward scattering of self-aligned nanoparticles on top of the transparent top contact layer. This results in a nanowire solar cell with a photovoltaic conversion efficiency of 17.8% and a short-circuit current of 29.3 mA/cm2 under 1 sun illumination, which is the highest reported so far for nanowire solar cells and among the highest reported for III-V solar cells. We also measure the angle-dependent photocurrent, using time-reversed Fourier microscopy, and demonstrate a broadband and omnidirectional absorption enhancement for unpolarized light up to 60° with a wavelength average of 12% due to Mie scattering. These results unambiguously demonstrate the potential of semiconductor nanowires as nanostructures for the next generation of photovoltaic devices.

Directional and Polarized Emission from Nanowire Arrays

Lighting applications require directional and polarization control of the emitted light, which is currently achieved by bulky optical components such as lenses, parabolic mirrors, and polarizers. Ideally, this control would be achieved without any external optics, but at the nanoscale, during the generation of light. Semiconductor nanowires are promising candidates for lighting devices due to their efficient light outcoupling and synthesis flexibility. In this work, we demonstrate a precise control of both the directionality and the polarization of the nanowire array emission by changing the nanowire diameter. We change the angular emission pattern from a large-angle doughnut shape to a narrow-angle beaming along the nanowire axis. In addition, we tune the polarization from unpolarized to either p- or s-polarized. Both the far-field emission pattern and its polarization are controlled by the number and type of guided or leaky modes supported by the nanowire, which are determined by the nanowire diameter.

Analysis of 6-nm AlGaAs SQW low-confinement laser structures for very high-power operation

This paper reports experimental results on single quantum-well separate confinement heterostructures (SQW SCH) with low-confinement factor, designed for very high-power operation. The maximum power output for AR/HR coated 3-mm-long devices, measured in very short pulsed conditions (100 ns/1 kHz), from 10-/spl mu/m-wide stripes was as high as 6.4 W before catastrophic optical degradation. If scaled to continuous-wave (CW) conditions, this value would be 800-1100 MW, which would mean a factor of 22.7 times more than reported for the best devices with normal design for threshold minimization. The absorption coefficient for the symmetrical structure is as low as 1.1 cm/sup -1/, in spite of the low trapping efficiency of carriers in the quantum well (QW). The maximum differential efficiency is 40% (both faces, uncoated devices) for symmetrical structure and 33% for the asymmetrical one (all measurements in pulsed conditions). Threshold current densities were 800 A/cm/sup 2/ for 5-mm-long devices in the symmetrical case and 2200 A/cm/sup 2/ in the asymmetrical one. The effects of inefficient carrier trapping in the QW on the threshold current densities and differential efficiency are discussed.

Growth and Optical Properties of Direct Band Gap Ge/Ge0.87Sn0.13 Core/Shell Nanowire Arrays

Group IV semiconductor optoelectronic devices are now possible by using strain-free direct band gap GeSn alloys grown on a Ge/Si virtual substrate with Sn contents above 9%. Here, we demonstrate the growth of Ge/GeSn core/shell nanowire arrays with Sn incorporation up to 13% and without the formation of Sn clusters. The nanowire geometry promotes strain relaxation in the Ge0.87Sn0.13 shell and limits the formation of structural defects. This results in room-temperature photoluminescence centered at 0.465 eV and enhanced absorption above 98%. Therefore, direct band gap GeSn grown in a nanowire geometry holds promise as a low-cost and high-efficiency material for photodetectors operating in the short-wave infrared and thermal imaging devices.

MEASUREMENT OF THE AMBIPOLAR CARRIER CAPTURE TIME IN A GaAs/AlxGa1-xAs SEPARATE CONFINEMENT HETEROSTRUCTURE QUANTUM WELL

The carrier capture in a separate confinement heterostructure quantum well has been studied both experimentally and theoretically. Our calculations show that the electron and hole capture time vary strongly as a function of the excess energy. At an excess energy of 40 meV, both capture times are equal resulting in an ambipolar capture process which allows a direct comparison between theory and experiment. We carried out subpicosecond luminescence spectroscopy experiments and deduce an ambipolar overall capture time of 20 ps, a number which for the first time is in agreement with theoretical predictions. The quantum mechanical overall capture time of 20 ps gives rise to a classical local capture time of 3 ps which is determined from a diffusion model.

Optical investigation of the two-dimensional hole energy spectrum in GaAs/AlxGa1-xAs heterojunctions

We present the results of optical studies on the energy spectrum of a two‐dimensional hole gas (2DHG) in a GaAs/AlxGa1−xAs structure. The photoluminescence (PL) line shape in the 2DHG is investigated as a function of temperature by heating the holes by a current flow through the 2D hole channel. The line shape of the PL from the 2DHG as a function of temperature is calculated by taking into account the real band structure and the hole–hole final‐state interaction. By comparing experiment and theory, it is found that the special features of the band structure predicted theoretically explain the experimental data.

Optical study of the band structure of wurtzite GaP nanowires

We investigated the optical properties of wurtzite (WZ) GaP nanowires by performing photoluminescence (PL) and time-resolved PL measurements in the temperature range from 4 K to 300 K, together with atom probe tomography to identify residual impurities in the nanowires. At low temperature, the WZ GaP luminescence shows donor-acceptor pair emission at 2.115 eV and 2.088 eV, and Burstein-Moss band-filling continuum between 2.180 and 2.253 eV, resulting in a direct band gap above 2.170 eV. Sharp exciton α-β-γ lines are observed at 2.140–2.164–2.252 eV, respectively, showing clear differences in lifetime, presence of phonon replicas, and temperature-dependence. The excitonic nature of those peaks is critically discussed, leading to a direct band gap of ∼2.190 eV and to a resonant state associated with the γ-line ∼80 meV above the Γ8C conduction band edge.