J.F. Ortuño

Nutrient removal and sludge production in the coagulation-flocculation process.

Nutrient removal and sludge production in the coagulation-flocculation process, applied to a slaughterhouse effluent, have been studied. Fe2(SO4)3, Al2(SO4)3 and polyaluminium chloride were used as coagulants. Inorganic products were used as coagulant aids: activated silica, powdered activated carbon and precipitated calcium carbonate and synthetic polyelectrolytes: cationic polyacrylamide, polyacrilic acid, anionic polyacrylamide and polyvinyl alcohol. Performances were measured under optimum conditions for the products used. They were found after studying the different variables which influence the process. Phosphorus removal is very high (approximately 100% for the orthophosphate and between 98.93% and 99.90% for the total phosphorus). Ammonia nitrogen removal is very low although appreciable performances are observed for albuminoid nitrogen (73.9-88.77%). The use of coagulant aids reduces the volume of the sludge produced up to 41.6%.

Microscopic observation of particle reduction in slaughterhouse wastewater by coagulation-flocculation using ferric sulphate as coagulant and different coagulant aids.

A coagulation-flocculation treatment has been applied to a slaughterhouse liquid effluent, using ferric sulphate as coagulant and activated silica, powdered activated carbon, cationic polyacrylamide, polyvinyl alcohol, polyacrylic acid and anionic polyacrylamide as coagulant aids in order to improve the settling time. Once the optimal conditions had been established (speed and time of stirring during flocculation step, pH, coagulant and coagulant aid doses), the efficiency of the coagulation-flocculation process was studied by comparing the particle size distribution before and after the addition of the coagulant. When ferric sulphate was used without the coagulant aids, particle removal efficiency varied with size, although overall efficiency was quite substantial (87%). The use of coagulant aids improved the removal efficiency, except in the case of activated silica, when it fell to 78%. In all other cases removal efficiency values between 93% (for polyvinyl alcohol) and 99% (for anionic polyacrylamide) were reached.

Hydraulic performance of a deep wastewater stabilization pond

Abstract The hydraulic performance of a deep wastewater stabilization pond located in the Espinardo Campus of the University of Murcia was studied. The pond has a maximum capacity of 15,000 m3, with a maximum depth of 8 m. Sulforhodamine B dye is used as a tracer in the experimental study, which was carried out in two different climatic periods, winter and summer, so that the influence of temperature on the internal hydrodynamic of the lagoon could be ascertained. Two types of sample were obtained. One was taken from the mass of water within the pond and the other at the outlet. The mean real residence time ( t ) was calculated and it was below the spatial time (τ) both in summer and winter. Sampling carried out in the outlet flow along the time allowed the application of population balance models and to analyze the existence of short circuits and dead spaces. The pond active volume was calculated, being 70 and 22% of total volume in winter and summer, respectively. In both seasons, the active zone showed a hydrodynamic behaviour similar to the completely mixed continuous tank reactor (observed in the curves C and in the fitting of the experimental data at outlet and the use of the combined model of Cholette and Cloutier). From the experimental data of the remaining BOD5 it was possible to calculate the global kinetic constants for organic matter degradation and, from this, the constants at 20°C obtained at the most unfavourable (higher) water temperature observed. Both in winter and summer constants values (k20 = 0.46 and 0.32 d−1) seemed to point to the active zone of the system, showing a fundamentally aerobic behaviour.

Determination of low concentration of sulphorhodamine B in wastewaters and stabilization ponds

Abstract The use of sulphorhodamine B, a known red fluorescent dye as a quantitative tracer in hydrological studies related to wastewaters has been proved experimentally. The interference in the accuracy of fluorescence readings owing to dissolved or suspended contaminants in wastewaters, especially at low concentrations of dye, was solved by successive filtering and eluting of the sample through a sep-pack C-18. The sulphorhodamine B, which is concentrated by displacement with small volumes of methanol, was thus retained. Volumes were then read with an fluorescence spectrophotometer. The procedure was demonstrated to be valid for use with sewers, stabilization ponds and wastewaters for concentrations as low as 5 × 10 −7 g litre −1 .

Sewage Treatment with a Hybrid Constructed Soil Filter

Abstract The overall aim of this research was to apply a hybrid constructed soil filter for sewage treatment. A hybrid constructed soil filter is an ecological process used for decentralized sewage treatment in villages, small towns or scattered residential areas. Sewage is firstly treated by conventional physicochemical or biological treatment and then allowed to infiltrate through aerated unsaturated zone wherein it gets purified through processes such as filtration, adsorption, chemical reaction and biodegradation. This system has demonstrated a consistent capacity to remove organic matter and nitrogen. Experimental results have shown that under hydraulic load rates of 0.22 m3/m2 · h and organic load rates ranging from 47 to 156 g COD/m2 · h, mean removal efficiencies of 89% for COD, 99% for BOD5, 86% for suspended solids and 52% for total nitrogen can be achieved using an hybrid constructed soil filter. Compared to the conventional activated sludge process, this technology has many advantages, such as simple construction, low operation and maintenance costs, as well as a simple operation.