J.H. de Araújo

Exchange-spring behavior in nanopowders of CoFe2O4–CoFe2

The nature of the magnetic interactions among core-shell nanoparticles of CoFe2O4–CoFe2 having an average particle size of 32 nm were investigated by δm plots. It was found that the interactions are mainly demagnetizing in nature for nanoparticles with core diameters larger than 26 nm. For smaller values of core diameters, the exchange-spring phenomenon takes place due to the exchange-coupling at the core-shell interface. The critical thickness of the shell was estimated to be 7.8 nm. The overall results are in excellent agreement with current theoretical models.

Reentrant spin glass behavior in polycrystalline La0.7Sr0.3Mn1-XFeXO 3

The magnetic and transport properties of the compound La0.7Sr0.3Mn1-xFexO 3 (0.1 < x <0.4) have been studied by means of electrical resistivity, AC magnetic susceptibility, and DC magnetization. At low concentrations (x <0.1), the system displays essentially para-to-ferromagnetic transitions as the temperature is decreased, although a decrease in the magnetic moment has been observed in previous studies at temperatures a little below TC. This ferromagnetism is explained by double exchange theory in terms of the formation of Mn+3/Mn+4 ions pairs in the system. At concentrations in the range 0.1 < x <0.4 the system is more complex. Increased Fe doping not only weakens the ferromagnetic (FM) order and augments the resistivity of the samples, but also induces the appearance of a reentrant spin glass phase at low temperatures (T < 60 K). Irreversibility of the magnetization measured with zero field cooling and with field cooling has been observed. In addition, the AC susceptibility peak position varies with frequency. All these effects are characteristic of spin glass behavior. The results have been interpreted based in an increase of frustration due to increasing competition between FM Mn+3/Mn+4 interactions and antiferromagnetic interactions between ions at the boundaries of Fe clusters.

Giant magnetoimpedance in FeAg granular alloys

We have observed giant magnetoimpedance (GMI) in an FeAg granular alloy. Impedance and transverse susceptibility (TS) measurements as a function of the external dc magnetic field were made at room temperature. The variation of the magnetoimpedance ratio with magnetic field has been related to a corresponding TS ratio change as a function of the magnetic field. The peaks in the GMI and TS curves are in the same position and have been associated in both cases to effective anisotropy fields.

Origin of spin-glass and exchange bias in La1∕3Sr2∕3FeO3−γ nanoparticles

The structure and the magnetic properties of nanopowdered samples of La1∕3Sr2∕3FeO3−γ with average particles size d in the range of 67-367 nm prepared by a sol-gel method were investigated in detail. The samples were characterized by X-ray diffraction, scanning electron microscopy, specific heat, Mossbauer spectroscopy, ac susceptibility, and magnetization measurements. Exchange bias with vertical magnetization shift was found in all samples. Charge ordering and antiferromagnetism were observed close to 200 K for large particles (d ≥ 304 nm) samples, while for particles with intermediated and smaller values (d ≤ 156 nm) a cluster-glass like behaviour and a short range charge ordering were seen near 115 K and 200 K, respectively. The spin-glass like and exchange bias behaviour in nanopowdered samples of La1∕3Sr2∕3FeO3−γ are associated to compact Fe3+ antiferromagnetic (AF) clusters caused by an oxygen deficiency, which was found to be higher in the samples with the smallest average particles sizes. The eff...

Atomic hopping in AlCuFe quasicrystal

Abstract High temperature 57Fe Mossbauer effect measurements in annealed icosahedral AlCuFe alloy are reported. The anomalous decrease in Debye-Waller factor is qualitatively interpretated. It is suggested using consistent parameters that the isomer shift decreases linearly with temperature in agreement with a second-order Doppler shift in the Debye approximation.

Preparation and characterization of FeAg granular alloys

Fe10Ag90 granular alloys have been fabricated, using a sol-gel method, for a range of nitric acid concentrations in the start solution. The samples have been characterized by X-ray diffraction and magnetization measurements. The average Fe particle sizes derived from X-ray diffraction are in the range 24-29 nm, indicating a large variation. The coercivity obtained from the hysteresis curve is two orders of magnitude larger that of pure iron in all the samples. Moreover, the hysteresis curves do not saturate, even in fields of up to 1 T. These observations indicate that the samples contain both superparamagnetic and blocked particles. A comparison between the coercive field and the average particle diameter, determined by the Sherrers formula, is displayed in all acid concentrations.

Effect of High Energy Milling on the Magnetic Properties of the WC-10wt.%Co Cemented Carbides

Cemented tungsten carbides were produced by liquid-phase sintering. In these work high energy milling (HEM) was used to produce homogeneous and finely grained powder mixtures. The milling effect on the magnetic properties of sintered samples is studied. Different mixtures in same composition (WC-10wt.%Co) were prepared by conventional mixture technique and wet HEM up to 300 hs in Planetary Mill. Magnetic hysteresis measurements on the sintered samples detected a significant increase in the coercitive field and a decrease on the saturation magnetization with milling time increasing. X-ray diffractogram show phase transformations with milling time. The Magnetic properties are correlated with phase relations and microstructural properties of the sintered samples.