J. Margerie

Experimental and theoretical investigation of the 4fn↔4fn-15d transitions in YPO4:Pr3+ and YPO4:Pr3+, Ce3+

Excited state absorption spectra from the 4f2 levels of Pr3+ in YPO4 to 4f5d were measured at 293 and 77 K using a pulsed pump-probe technique. The spectra from the 1D2 manifold were recorded by employing a continuous wave probe, whilst those from the 3PJ-1I6 states were recorded by using for the first time a pulsed probe. These experimental results are compared with the numerical predictions of a full calculation of the 4f5d levels and the agreement is found to be good. A detailed study of the UV luminescence properties of the Pr3+ and the Ce3+ ions in the YPO4 host crystal, including the energy transfer between these two ions, is also reported. Fluorescence spectra and decay curves from the lower excited-state levels of the 4f5d and 5d electronic configurations of the Pr3+ and Ce3+ ions, respectively, were measured both at 293 and 77 K. The Pr3+→Ce3+ energy transfer efficiency was evaluated. Further considerations about the possibility to obtain laser emission based on the 5d→4f optical transition seem to indicate that this material is probably not a very good candidate to build a UV tunable laser because of a relatively short lifetime of the emitting level corresponding to a reduced quantum efficiency.

Energy levels of the laser active Er3+ ion in each of the two crystallographic sites of yttrium orthosilicate

There are two non-equivalent sites of yttrium in the lattice of Y2SiO5. Both of them may be occupied substitutionally by Er3+, resulting in a laser active material. We measured absorption spectra of Y2SiO5:Er3+ at several low temperatures and we studied its emission spectrum at 4.2 K following selective excitation of individual Stark components of the 4I13/2 to 4 I15/2 transition by the light of a tunable colour centre laser. The results of these two experiments allow classification of the absorption and emission lines into two independent systems, thus yielding two energy level schemes 1 and 2. Moreover, simple crystal field calculations strongly suggest from which Y2SiO5 crystallographic site spectrum 1 arises, and from which one spectrum 2.