J. P. Shrivastava

Similarities in the mineralogical and geochemical attributes of detrital clays of Maastrichtian Lameta Beds and weathered Deccan basalt, Central India

Abstract Mineralo-chemical attributes of the Maastrichtian (Late Cretaceous) Lameta sediments, intimately associated with the Deccan Traps in Central India, provide insight into the initiation of Deccan volcanism. X-ray diffraction studies on the detrital clays of the Lametas and weathered Deccan basalt show identical mineral assemblages with the dominance of smectite and subordinate kaolinite, illite. IR spectra are also indicative of their common mineralogical attributes. Structural formulae of the smectites in Lameta exhibit high octahedral Mg and Fe. The immobile trace-element concentrations in Lameta clays resemble those in weathered Deccan basalt. REE plots of the Lametas are subparellel with that of weathered Deccan basalt and show negative Ce anomalies documented in basalt weathering.These findings suggest that smectite-rich clays of the Lametas are derivatives of the Deccan basalt, implying early activities of Deccan volcanism either during or just prior to the Maastrichtian Lameta sedimentation.

Basalts of the Eastern Deccan Volcanic Province, India

Abstract The Mandla lobe in the eastern part of the Deccan volcanic province represents an isolated lava pile having a thickness of ∼900 m. The large thickness of this lava pile and its spatial detachment from the western Deccan outcrop points to a plausible second source. The stratigraphic configuration of the central and eastern Deccan lava sequences and their possible stratigraphic correlation are primarily based on geology and chemical signatures of the lava flows. Based on variations in the incompatible element ratios, the lava sequences of Chindwara, Jabalpur-Seoni and Jabalpur-Piparia sections were classified into four informal formations showing similarity with the southwestern formations. Major and trace element abundances in fifteen lava flows of Jabalpur area are similar to that of the southwestern Deccan lava flows. It has been found that the Ambenali Fm. and a few Khandala and Bushe Fm. flows are present in the northeastern Deccan. The regional mapping and detailed petrographic studies coupled with the lateral tracing have enabled the recognition of thirty-seven physically distinct lava flows and is justified by their major-elemental chemistry. The ‘intraflow variations’ studied in some of the flows is very low for most of the major oxides. These thirty-seven lava flows are grouped into eight chemical types. The order of superposition in this sequence reflects that the older flows occur in the west of the outlier at the Seoni-Jabalpur-Sahapura sector whereas, the younger flows are confined to the Dindori-Amarkantak sector in the east. The spatial disposition of the lava flows suggests that the structural complexity in the lava flow sequence in the Mandla lobe lies between Jabalpur and Dindori. The juxtaposition of distinct groups of lava flows are observed near Deori (flows 1 to 4 abeted aginst flows 5 to 14) and Dindori areas. At Dindori and towards its south the distinct lava packages (flows 15 to 27 and flows 28 to 37) are juxtaposed along the course of Narmada river. The possible explanation for this could be the presence of four post-Deccan faults at Nagapahar, Kundam, Deori and Dindori areas. The vertical shift of chemically distinct lava packages at different sectors in the outlier contravenes the idea of small regional dip and favours the presence of four NE-SW trending post-Deccan faults. Major geochemical breaks, when traced out from section to section, exhibit shifting in heights by approximately 150 m near Nagapahar and 300 m near Deori and Dindori areas. The field, petrographic and major-oxide data sets considered in conjuction with the magnetic chron reversal heights, support the inference that four faults trending NE-SW are present in the Mandla lobe. A commonality in the mineralo-chemical attributes of the infra (Lametas)-/inter-trappean as well as weathered Deccan basalt further favours their derivation from Deccan basalt, implying the availability of Deccan basalt during the Maastrichtian Lameta sedimentation. This observation does not match with the models suggesting an extremely short duration of Deccan volcanism (

Clay mineralogical studies on Bijawars of the Sonrai basin: Palaeoenvironmental implications and inferences on the uranium mineralization

Clays associated with the Precambrian unconformity-related (sensu lato) uranium mineralization that occur along fractures of Rohini carbonate, Bandai sandstone and clay-organic rich black carbonaceous Gorakalan shale of the Sonrai Formation from Bijawar Group is significant. Nature and structural complexity of these clays have been studied to understand depositional mechanism and palaeoenvironmental conditions responsible for the restricted enrichment of uranium in the Sonrai basin. Clays (<2 μm fraction) separated from indurate sedimentary rocks by disaggregation, chemical treatment and centrifugation were examined using X-ray Diffraction (XRD) and Scanning Electron Microscopy (SEM). Presence of tv-1M type illite is inferred from the Rohini and Bandai Members of the Sonrai Formation, indicative of high fluid/rock interaction and super-saturation state of the fluids available in proximity with the uranium mineralization. It is observed that the Sonrai Formation is characterized by kaolinite > chlorite > illite > smectite mineral assemblages, whereas, Solda Formation contains kaolinite > illite > chlorite clays. It has been found that the former mineral assemblage resulted from the alteration process is associated with the uranium mineralization and follow progressive reaction series, indicating palaeoenvironmental (cycles of tropical humid to semi-arid/arid) changes prevailed during maturation of the Sonrai basin. The hydrothermal activity possibly associated with Kurrat volcanics is accountable for the clay mineral alterations.